• Title/Summary/Keyword: 연소법

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A Study on change in thermal properties and chemical structure of Zr-Ni delay system by aging (노화에 따른 Zr-Ni계 지연관의 열 특성 및 화학적 구조 변화에 관한 연구)

  • Park, Byung Chan;Chang, Il Ho;Kim, Sun Tae;Hwang, Taek Sung;Lee, Seungho
    • Analytical Science and Technology
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    • v.22 no.4
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    • pp.285-292
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    • 2009
  • It has been observed that, after long term storage, some ammunitions are misfired by tamping (combustionstopping) due to aging of the chemicals loaded in the ammunitions. Used in ammunitions are percussion powder which provides the initial energy, igniter which ignites the percussion powder, and a delay system that delays the combustion for a period of time. The percussion powder is loaded first, followed by the igniter and then the delay system, and the ammunitions explode by the energy being transferred in the same order. Tamping occurs by combustion-stopping of the igniter or insufficient energy transfer from the igniter to the delay system or the combustion-stopping of the delay system, which are suspected to be caused by low purity of the components, inappropriate mixing ratio, size distribution of particulate components, type of the binder, blending method, hydrolysis by the humidity penetrated during the long term storage, and chemical changes of the components by high temperature. Goal of this study is to find the causes of the combustion-stopping of the igniter and the delay system of the ammunitions after long term storage. In this study, a method was developed for testing of the combustion-stopping, and the size distributions of the particulate components were analyzed with field-flow fractionation (FFF), and then the mechanism of chemical change during long term storage was investigated by thermal analysis (differential scanning calorimetry), XRD (X-ray diffractometry), and XPS (X-ray photoelectron spectroscopy). For the ignition system, M (metal)-O (oxygen) and M-OH peaks were observed at the oxygen's 1s position in the XPS spectrum. It was also found by XRD that $Fe_3O_4$ was produced. Thus it can be concluded that the combustion-stopping is caused by reduction in energy due to oxidation of the igniter.

Discussions on Carbon Account in Harvested Wood Products and Effects on Korean Carbon Emissions under the UNFCCC (기후변화협약 하에서 목제품 탄소계정 논의 동향 및 국내 탄소배출량에 미치는 영향 분석)

  • Choi, Soo Im;Bae, Jae Soo;Jung, Byung Heon
    • Journal of Korean Society of Forest Science
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    • v.95 no.4
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    • pp.405-414
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    • 2006
  • Korea is expected to be included in the countries of compulsory reduction of greenhouse gas emissions from the 2nd commitment period (2013~2017). For the negotiations in the future, this study was designed to review the tendency of discussions about carbon account in harvested wood products (HWP), which is currently underway around the globe and approach-specific characteristics, and analyze effects on carbon emissions in our country. As a result, most importantly, except the current IPC default approach there is no big difference among the 3 approaches of carbon account in HWP, which were newly suggested on the basis importers because all the HWP circulated at home are accounted for by carbon-stock changes. Under production approach, those HWP produced at home only are evaluated according to carbon-stock changes with the exception of imported HWP. Atmospheric-flow approach is favorable to net wood exporters, because the spot where ultimate decomposition and combustion arising out of the use of HWP occur is regarded as the place of carbon emission. Meanwhile, the estimation of korean carbon-stock change in HWP showed that as of 2004, stock-change approach was 1.567 Tg C, with production approach being 0.581 Tg C and atmospheric-flow approach being -1.425 Tg C, which means stock-change approach is most favorable to Korea as a net wood importer, while atmospheric-flow approach is the least favorable one, in terms of carbon emissions reduction in Korea.

Fabrication of Fiber-Reinforced Composites by High Pressure Self-Combustion Sintering Method (고압 자전연소 소결법을 이용한 섬유강화 복합체의 제조)

  • 방환철;고철호;임동원;김봉섭;최태현;윤존도
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.444-452
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    • 2000
  • Dense composites of titanium matrix and Al2O3 matrix with reinforcements of carbon or titanium carbide fibers were successfully fabricated by high-pressure self-combustion sintering method or combustion reacton under 30 MPa of uniaxial pressure with an aid of external heating in vaccum. It was found that the fibers were uniformly distributed in the matrix, and aligned in a phase perpendicular to the pressure axis. As a moel ratio of Ti/C or reaction time increased, the density of Ti-matrix composite increased Micro pores around fibers could be removed by using clean carbon fibers without sizing agent on their surface. The evolution of carbide fibers from carbon fibers was observed. The composition of the various phases around fibers were analyzed.

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Heat Dissipation of Cylinder Head of Reciprocating Internal Combustion Engine (왕복동 내연기관 실린더 헤등의 방열에 관한 연구)

  • Kim, K. C.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.8 no.1
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    • pp.71-78
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    • 1984
  • 본 논문은 왕복동 내연기관의 방열에 관한 연구의 하나로서 디이젤 기관 실린더 헤드와 흡 배기 밸브의 온도 분포와 열유속의 분포를 구한 것이다. 방열 해석은 기관의 정상 작동된 다음의 실린 더 헤드의 열부하가 일정하다고 생각하여 실린더 헤드의 밸드 시이트 양단의 온도와 연소 가스 배출 온도, 흡기 및 냉각수 온도를 측정하고 온도분포 및 열유속을 유한요소법을 적용하여 구하 였다. 본 연구의 결과 실린더 헤드 및 밸브의 과부하는 밸브의 경우에는 밸브 헤드 중심과 밸브 헤드 중심 부근에서 일어나며, 실린더 헤드의 경우에는 헤드 중심부 표면에서 발생하였다. 흡 배 기 밸브 및 물재킷부의 온도 분포 및 열유속의 분포를 주어진 냉각수 온도 조건에 대하여 구한 후 이들을 비교 검토 하였다.

Flow Measurement of a Triple Hot-Wire Probe (三軸 熱線 프로브에 의한 流動計測法)

  • 김경훈
    • Journal of the KSME
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    • v.34 no.9
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    • pp.705-710
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    • 1994
  • 열.유체유동 중 난류에 대한 유동현상은 매우 광범위한 영역에서 나타나기 때문에 그 응용성이 매우 크게 작용되어 상업용 설비, 항공기, 자동차, 연소기 및 각종 스포츠 등에 이르기까지 넓게 적용되고 있다. 본 계측법은 특히 기하학적 형상에 좌우되지 않는 범용데이터 처리와 결부시켜 이용하는 것으로 최근 컴퓨터의 보급이 활발히 정착됨에 따라 보다 정확한 방법으로 난류의 정량적인 자료와 정성적인 난류구조를 계측하기 위하여 컴퓨터와 온라인으로 연결한 열선한 열 선유속계의출력을 통계해석에 의해 분석하는 방법이 시도되고 있는 것이다. 끝으로 이 글에서 언급한 삼축 열선 프로브는 프로브의 제작에 대한 고도의 기술과 프로브의 겁사체적을 되도록 작게 해야 하는 과제를 안고 있으며, 이러한 문제들은 제작기술의 발달로 점차 해결되고 있으며 적용대상이 크기 때문에 앞으로 많이 이용 될 것으로 기대되는 바이다.

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Preparation of High Purity Si Powder by SHS (자전 연소 합성법에 의한 고순도 실리콘 분말제조)

  • Shin, Chang-Yun;Min, Hyun-Hong;Yun, Ki-Seok;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.44 no.2 s.297
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    • pp.93-97
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    • 2007
  • High purity Si powder was prepared in the system of $SiO_2-Mg$ combustion reaction. Various conditions of combustion reaction and leaching were investigated. As the particle size of Mg decreased and the compaction pressure increased the quantity of the unreacted power was decreased. In the acid leaching of MgO, increasing particle size, reaction temperature, rotating speed and reaction time made leaching effect low. Final Si powder produced by combustion and leaching reaction, has a high purity of 99.9% with irregular shape.

Preparation of WC Powders by SHS Process in the Presence of Alkali Salts (자전연소합성법에서의 알칼리염을 이용한 WC 분말의 제조)

  • Won, Hyung-Il;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.152-156
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    • 2007
  • Tungsten carbide powder was synthesized by SHS (self-propagating high-temperature synthesis). Except $WO_{3}$, each concentration of raw material ($WO_{3},\;Mg,\;NaCl,\;Na_{2}CO_{3},\;C$) was investigated. Final product was characterized by XRD and SEM. X-ray data demonstrated that the $NaCl+Na_{2}CO_{3}$ combined mixture has superiority in the WC formation process. Single phase and submicrometer WC powder was synthesized at the temperature below $1600^{\circ}C$. The role of sodium salts in combustion process was discussed, and chemical mechanism of WC formation was proposed. WC powder prepared by salt-assisted combustion synthesis has a size $0.2{\sim}3\;{\mu}m$ and low agglomeration degree.

Use of Ultrasonic to Atomizing a Highly Viscous Bio-oil (고점성 바이오유의 분무미립화를 위한 초음파 이용)

  • 주은선;나우정;김종천
    • Journal of Biosystems Engineering
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    • v.21 no.4
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    • pp.467-473
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    • 1996
  • Ultrasonic energy was applied for atomizing rice-bran oil which is a highly viscous bio fuel. Six different nozzles, an injection simulator, and an ultrasonic generator system were designed and constructed for the experiment. An immersion liquid method was used for the measurement of injection droplet sizes. The characteristics of injection droplets was investigated with respect to the numbers of the droplets with diameters ranging from 5$\mu$m 50$\mu$m and to the Sauter mean diameter. The results showed that the ultrasonic energy was effective for the improvement of the atomization of the injection droplets for all the factors such as type of nozzles, nozzle opening pressures, and collection distances.

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Simulation of Natural Gas Injected Dual-Fuel DI 2-Stroke Diesel Engine (천연가스를 파이럿오일과 이원공급하는 직접분사식 2행정 디이젤기관의 시뮬레이션)

  • Choi, In Su
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.3
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    • pp.9-18
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    • 1995
  • The substitution of conventional fuel oil by alternative fuels is of immense interest due to liquid oil shortage and requirements of emission control standard. Among the alternative fuels, natural gas may be the most rational fuel, because of its widespread resource and clean est burning. Meanwhile, engine simulation is of great importance in engine development. Hence a zero-dimensional combustion model was developed for dual-fuel system. Natural gas was injected directly into the cylinder and small amount of distillate was used to provide the ignition kernel for natural gas burning. The intake air and exhaust gas flow was modeled by filling and emptying method. Although the single zone approach has an inherent limitation, the model showed promise as a predictive tool for engine performance. Its simulation was also made to see how the engine performance was influenced by the fuel injection timings and amount of each fuel.

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Synthesis of nanometric tungsten powders by solid state combustion method (고상연소반응법에 의한 나노텅스텐분말의 합성)

  • H.H. Nersisyan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.93-93
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    • 2003
  • Tungsten and tungsten heavy alloys have widespread application as radiation shielding devices and heavy duty electrical contacts. High density and good room temperature mechanical properties have generated interest in evaluating tungsten and tungsten alloys as kinetic energy penetrators against armor. Nowdays ultra fine-grained tungsten powders are in great interest because higly dense structures can be obtained at low temperature, pressure and lower sintering time. Several physical md chemical methods are available for the synthesis of nanometric metal Powders: ball milling, laser abalation, vapor condensation, chemical precipitation, metallic wire explosion i.e. However production rates of the above mentioned methods are low and further efforts are needed to find out large-scale synthesis methods. From this point of view solid state combustion method ( known as SHS) represents undoubted interest.

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