• Journal of the Korean Ceramic Society
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• v.39 no.1
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• pp.74-78
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• 2002

In this study, the solution combustion method was employed to synthesize perovskite PZT ceramics. Multicomponent oxides can be prepared by the solution combustion synthesis using redox exothermic reaction of precursor solutions. The results of DTA/TG showed exothermic peaks in 214$^{\circ}C$ and 350$^{\circ}C$. Those were caused by the differences of the thermal decomposition behavior of oxidizer and fuel. The combustion reaction was completed at 370$^{\circ}C$ during heating procedure, but the product was not transformed into perovskite. The thermal decomposition behavior of both oxidizer and fuel were considered during solution combustion process at 600$^{\circ}C$, which showed tetragonal single phase PZT ceramics with 50 nm crystalline size. The lattice constant a was 3.997 ${\pm}$ 0.001 ${\AA}$ and the lattice constant c was 4.147${\pm}$0.001 ${\AA}$.

• Journal of Energy Engineering
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• v.19 no.3
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• pp.182-187
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• 2010

This study was the effect of inserting CO tube on $NO_x$ and CO emission characteristics in a compact combustion chamber. In detail, $NO_x$ and CO emission characteristics with changing of distance due to inserting CO tube between a burner and a main heat exchanger were investigated. For this study, the commercial program, FLUENT with GRI 2.11 detail reaction mechanism, was used for the numerical study and a commercial heat exchanger was tested for the experimental study. As results, when the CO tube was inserted between a burner and a main heat exchanger, it was verified that $NO_x$ and CO emissions was decreased simultaneously as CO tube was closed to a burner and the distance between CO tube and a main heat exchanger was increased.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.12
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• pp.1111-1118
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• 2010

Combustion measurements based on optical techniques have recently become of major interest as tools not only for clarifying the combustion mechanism but also for validating the computational results for the combustion fields. In this study, the particle behavior in turbulent pulverized coal flame are investigated using advanced optical diagnostics. A laboratory-scale pulverized coal combustion burner is specially fabricated as open type in order to apply various optical measurement techniques. The detailed particle behavior is performed by LDV (laser Doppler velocimetry) and SDPA (shadow Doppler particle analyzer). It is observed that the particle mean diameter increase as the distance from burner increases, and this is found to be caused by the decrease of small particles' diameter and increase of large particles' diameter. This is because of result in the char reaction and the particle swelling due to devolatilization, respectively. The size-classified streamwise velocities of pulverized coal particles in the central region of the jet show the same magnitude, whereas those in the outer region are different depending on the particle size. The results show that the velocity and size-classified diameter of the pulverized coal particles in the flame can be measured well by SDPA.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.608-611
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• 2011

Laser-induced combustions and explosions generated by high laser irradiances were explored by Laser-Induced Breakdown Spectroscopy (LIBS) in rich, and stoichiometric conditions. The laser used for target ablation is a Q-switched Nd:YAG laser with 7 ns pulse duration at wavelength of 1064 nm laser energies from 40 mJ to 2500 mJ ($6.88{\times}10^{10}-6.53{\times}10^{11}\;W/cm^2$). The plasma light source from aluminum detected by the echelle grating spectrometer and coupled to the gated ICCD(a resolution (${\lambda}/{\Delta}{\lambda}$) of 5000). This spectroscopic study has been investigated for obtaining both the atomic signals of aluminum (fuel) - oxygen (oxidizer) and the calculated ambient condition (plasma temperature and electron density). The essence of the paper is observing specific electron density ratio which can support the processes of combustion and explosion between ablated aluminum plume and oxygen from air by inducing high power laser.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.575-580
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• 2010

Forest fires in Korea, having forest coverage of 70%, have kept increasing in number and scale since the middle of 1990's. Although deposited fallen leaves in forests such as herbaceous plants, conifers, and broadleaf trees are used as a medium for forest fires, the pyrolysis and combustion characteristics of the various species of trees are hardly studied. Oriental oak is the representative broadleaf tree in domestic forests, and pyrolysis and combustion of oriental oak leaf were carried out by thermogravimetic analysis (TGA). The leaf of oriental oak was ignited at $239^{\circ}C$ whereas pyrolysis started at $250^{\circ}C$. The corresponding kinetic parameters including activation energy and pre-exponential factor were determined by differential method over the degree of conversions. The values of activation energies for pyrolysis were increased as the conversion increases from 10% to 80%, whereas those of values were decreased during combustion.

• Journal of the Korean Wood Science and Technology
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• v.43 no.1
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• pp.96-103
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• 2015

The aim of this paper is to analyze combustion characteristics of treated woods by fire retardants which are prepared by several borate and phosphate compound solutions. The combustion characteristics for flame retardant treated wood were carried out using thermogravimetric analysis (TGA) to measure their combustion heat and flame retardant test using cone-calorimeter. The result of TGA and flame retardant test showed that single chemical solution affected the char forming and flame delay. The mixed retardants solutions was believed to be related to the efficacy and property of single chemical. The retention value and concentration of the retardants also affected the performance of fire retardant treated woods. The fire retardants FR1 and FR2 satisfied the requirement of The 3 Grade of Korean building codes.

• Fire Science and Engineering
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• v.17 no.4
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• pp.36-41
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• 2003

This experimental study shows the combustion characteristics for each coating thickness of water and oil paint which are used as fire retardant paints that prevent fire propagation through cables in underground culverts and trays. To evaluate combustion characteristics, smoke density(ASTM E 662) and Limited Oxygen Index(ASTM D 2863) experiment method was used. As the results of this study, the combustion characteristics of fire retardant paints produced the following : (a) The molt suitable coating thickness of fire retardant paint was 1.5∼2.0 mm in water paint and 0.2 mm in oil paint. (b) Flaming method in experiments of smoke density were found to be higher than Non-flaming method. (c) Water paint has the fire retardant effect and characteristics better than oil paint in measurement results of smoke density and oxygen index. (d) The oxygen index of water and oil fire retardant was able to know that it was satisfied a standard (30 or above).

• Journal of the Korean Vacuum Society
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• v.17 no.3
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• pp.189-194
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• 2008

Measurements with a Langmuir probe, which are the most often used procedures of plasma diagnostics, can disturb plasma flows and change its characteristics quite a little because the probe should be inserted into thermal flowing plasmas. In this study, we calculated the characteristics of thermal plasmas with and without the probe into an atmospheric argon free-burning arc numerically, and investigated aerodynamic and thermal disturbances with temperature and axial velocity distributions. For the modelling of thermal plasmas, we have made two governing equations, which are on the thermal-flow and electromagnetic fields, coupled together with a commercial CFD package and user-coded subroutines. It was found that thermal disturbances happened to both sides of the probe, before and behind, seriously. Due to the aerodynamic disturbance, we could find that there were the stagnation point in front of the probe and the wake behind it. Therefore, aerodynamic and thermal disturbances caused by the probe insertion should be considered to increase the reliability of the probe diagnostics.

• Nuclear Engineering and Technology
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• v.16 no.4
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• pp.181-194
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• 1984

The in-core fuel management problem was studied by use of the calculus of variations. Two functions of interest to a public power utility, the profit function and the cost function, were subjected to the constraints of criticality, the reactor turnup equations and an inequality constraint on the maximum allowable power density. The variational solution of the initial profit rate demonstrated that there are two distinct regions of the reactor, a constant power region and a minimum inventory or flat thermal flux region. The transition point between these regions is dependent on the relative importance of the profit for generating power and the interest charges for the fuel. The fuel cycle cost function was then used to optimize a three equal volume region reactor with a constant fuel enrichment. The inequality constraint on the maximum allowable power density requires that the inequality become an equality constraint at some points in the reactor. and at all times throughout the core cycle. The finite difference equations for reactor criticality and fuel burnup in conjunction with the equality constraint on power density were solved, and the method of gradients was used to locate an optimum enrichment. The results of this calculation showed that standard non-linear optimization techniques can be used to optimize a reactor when the inequality constraints are properly applied.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1517-1519
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• 1999

FED용 형광체로 사용되는 $ZnGa_2O_4$를 Glycine Nitrate Process로 합성하여 고상 반응법으로 합성한 $ZnGa_2O_4$ 분말과 비교 분석하였다. 또한 Glycine Nitrate Process로 제조시 Mn의 doping 농도를 변화시키면서 각각의 조성비에 따른 발광특성을 알아보았다. TGA 측정 결과 GNP법으로 합성된 $ZnGa_2O_4$의 경우약 $300^{\circ}C$이상에서 무게감량이 없으며, XRD 상분석 결과 연소반응 후 이미 상형성이 이루어짐을 알 수 있었다. PL측정을 결과 GP(Glycine Nitrate Process)로 제조된 $ZnGa_2O_4$ 분말의 발광효율이 고상 반응법으로 제조된 분말보다 우수하였으며, 균일하고 비표면적이 큰 단일상임이 관찰되었고, 더 작은 에너지와 시간으로 제조할 수 있는 장점이 있었다.