• Clean Technology
• /
• v.4 no.2
• /
• pp.23-31
• /
• 1998

Photo-sensitized oxidation of benzene in aqueous solution was conducted with persulfate, nitrate, nitrite, sulfate and chloride as sensitizers.In the photo-sensitized oxidation of benzene persulfate, nitrate and nitrite could act as sensitizers, while no detectable effects could be observed with sulfate and chloride. With increasing nitrite concentration the photo-sensitized oxidation of benzene ran through a maximum value and decreased thereafter with increasing nitrite concentration. A build-up of nitrite ions seemed to scavenge hydroxyl radicals. When nitrite was present with other ions, nitrite inhibited the photo-sensitized oxidation of benzene. Phenol and biphenyl were identified as intermediate.

• Journal of ILASS-Korea
• /
• v.8 no.4
• /
• pp.9-16
• /
• 2003

The Purpose of this study is to investigate the relationships between the local heat release rate and CH concentration have been investigated by numerical simulations of methane-air premixed flames. And simultaneous CH and OH PLIF(Planar Laser Induced Fluorescence) measurement has been also conducted for lean premixed flame as well as for laminar flames. Numerical simulations are conducted for laminar premixed flames and turbulent ones by using PREMIX in CHEMKIN and two dimensional DNS code with GRI mechanism version 2.11, respectively. In the case of laminar premixed flame, the distance between the peak of heat release rate and that of CH concentration is under $91{\mu}m$ for all equivalence ratio calculated in present work. Even for the premixed flame in high intensity turbulence, the distribution of the heat release rate coincides with that of CH mole fraction. For CH PLIF measurements in the laminar premixed flame burner, CH fluorescence intensity as a function of equivalence ratio shows a similar trend with CH mole fraction computed by GRI mechanism. Simultaneous CH and OH PLIF measurement gave us useful information of instantaneous reaction zone. In addition, CH fluorescence can be measured even for lean conditions where CH mole fraction significantly decreases compared with that of stoichiometric condition. It was found that CH PLIF measurements can be applicable to the estimation of the spatial fluctuations of heat release rate in the engine combustion.

• Journal of ILASS-Korea
• /
• v.8 no.2
• /
• pp.38-45
• /
• 2003

This study was carried on the combustion characteristics of a pure light oil and emulsified fuels at high-pressure injection in a spray combustion installation, The volume fractions of water in an emulsion were varied up to 30% and the injection pressures were 7.5, 100, 200, and $300kg_f/cm^2$. The concentrations of NOx and the average temperatures of flame were measured. And Images of OH radical using ICCD camera and instantaneous schlieren photography of flames were photographed. It was found that the temperature distribution of axial distance in the emulsified fuels was increased in the upstream and decreased in the down stream. The temperature distribution of radial distance was high at the peripheral regions of the spray in the upstream and at the central regions of spray in the downstream, The intensity of OH radical was denser at the water content 10% than at the pure light oil over the injection pressure $200kg_f/cm^2$.

• Journal of Power System Engineering
• /
• v.22 no.1
• /
• pp.56-63
• /
• 2018

After the recent fabrication of diesel vehicle exhaust gas by Volkswagen, nitrogen oxides ($NO_x$) and particulate matter (PM) are drawing attention as representative pollutants included in exhaust gas. When gasoline and diesel fuels are combusted through direct injection into a combustion chamber at high pressure, PM emission is actually increased. To find a solution to this problem, a basic study was conducted to derive an optimized variable for combustion of compressed natural gas (CNG) by applying CNG, acknowledged as a clean fuel, to direct injection system. The essence of this study is in the introduction of a radical ignition technology for compressed natural gas (RI-CNG) in a sub-chamber type engine. The direct injection system was applied to a sub-chamber to remove residual gas from previous combustion cycle. In addition, optimal mixer distribution was achieved by precisely setting ignition timing based on fuel injection timing and excess air ratio.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.23 no.1
• /
• pp.1-8
• /
• 2019

To analyze the dynamic behavior and the structure of the gaseous methane-gaseous oxygen diffusion flame formed by a swirl/shear-coaxial injector, combustion experiments were carried out under different propellant injection conditions. As a result, the OH radical emission intensity of the diffusion flame visualized through chemiluminescence was observed to increase as the propellant mass flow and the momentum flux ratio increased. And flames with swirl showed a more high radical emission intensity than those without swirl.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.2
• /
• pp.211-216
• /
• 2000

In this paper, experimental investigations were carried out to remove NOx, SOx simultaneously from a simulated combustion flue gas [$NO(0.02%)-SO_2(0.08%)-CO_2-Air-N_2$] by using a pulse corona induced plasma chemical processing. Discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was $2.5{\ell}/min$ for bubbling aqueous NaOH solution. Ammonia gas(l4.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio(MR) was determined based on [$NH_3$] and [$NO+SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration. but SOx removal rate was not significantly affected by initial concentration. The NOx, SOx removal rates decreased with increasing gas flow rate.

• Membrane Journal
• /
• v.31 no.3
• /
• pp.212-218
• /
• 2021

It is inevitable to generate incomplete combustion gases when mankind utilizes fossil fuels. From this point of view, gas separation process of combustion gas suggests the possibility of recycling CO gas. In this study, we fabricated a facilitated transport polymeric composite membrane for CO separation using AgBF₄ and HBF₄. The copolymer was synthesized via free-radical polymerization of poly(vinyl alcohol) (PVA) as a main chain and acrylic acid (AA) monomer as a side chain. The polymer synthesis was confirmed by FT-IR and the interactions of graft copolymer with AgBF₄, and HBF₄ were characterized by TEM. PVA-g-PAA graft copolymer membranes showed good channels for facilitated CO transport. In this perspective, we suggest the novel approach in CO separation membrane area via combination of grafting and facilitated transport.

• Journal of the Korean Chemical Society
• /
• v.35 no.3
• /
• pp.226-232
• /
• 1991

Adsorption and oxidation of polychlorinated phenols by suspended ${\sigma}-MnO_2$ in aqueous solution have been studied. Of the proposed mechanism, adsorption reaction of chlorophenols onto ${\sigma}-MnO_2$(s) depended upon the pH of the solution and the concentration of chlorophenol. Adsorption isotherms showed a reasonably good fit to the Langmuir isotherm. From the pH dependence of adsorption partition coefficient and the linear relationship between octanol-water partition coefficient and adsorption partiton coefficient of chlorophenol, it is estimated that adsorption is dominated by its hydrophobicity. The rate of electron transfer reaction evaluated from the rate of reductive dissolution of ${\sigma}-MnO_2$(s) depended linearly upon the concentration of chlorophenol and the pH of medium. Observed rate constants ($K_0$) of the meta-substituted chlorophenol were lower than that of the ortho-or para-chlorophenol because of resonance effect of chlorophenoxy radical. It is indicated that this radical is produced in the adsorption process and the electron transfer reaction is rate determining.

• 한국연소학회:학술대회논문집
• /
• 2000.05a
• /
• pp.57-66
• /
• 2000

OH radical and NO distributions have been measured in methane/air partially premixed counterflow flames(${\alpha}$=1.0, 0.8, 0.6) using PLIF technique. The results are discussed and compared with the numerical analysis results obtained under the same flame conditions. Measured OH and NO LIF signals agree with the computed concentration distributions. Both numerical and experimental results indicate that the structural change in a flame alters the NO formation characteristics of a partially premixed counterflow flame. The nitrogen dilution also changes flame structure, temperature and OH radical distributions and results in the decreased NO concentrations in a flame. The levels of decrease in NO concentrations, however, depends on the premixedness(${\alpha}$) of a flame. The larger change in the flame structure and NO concentrations have been observed in a premixed flame($\alpha$=1.0), which implies that the premixedness is likely to be a factor in the dilution effect on NO formation of a flame.

• Korean Chemical Engineering Research
• /
• v.50 no.6
• /
• pp.1034-1042
• /
• 2012

This study was performed by using an LFR (laminar flow reactor), which can be used to carry out different types of research on coal. In this study, an LFR was used to analyze coal flames, tar and soot yields, and structures of chars for two coals depending on their volatile content. The results show that the volatile content and oxygen concentration have a significant effect on the length and width of the soot cloud and that the length and width of the cloud under combustion conditions are less than those under a pyrolysis atmosphere. At sampling heights until 50 mm, the tar and soot yields of Berau (sub-bituminous) coal, which contains a large amount of volatile matter, are less than those of Glencore A.P. (bituminous) coal because tar is oxidized by the intrinsic oxygen component of coal and by radicals such as OH-. On the other hand, at sampling heights above 50 mm, the tar and soot yields of Berau coal are higher than those of Glencore A.P. coal by reacted residual volatile matter, tar and light gas in char and flame. With above results, it is confirmed that the volatile matter content and the intrinsic oxygen component in a coal are significant parameters for length and width of the soot cloud and yields of the soot. In addition, the B.E.T. results and the images of samples (SEM) obtained from the particle separation system of the sampling probe support the above results pertaining to the yields; the results also confirm the pore development on the char surface caused by devolatilization.