• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.361-364
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• 2009

KEPRI has studied planar type SOFC stacks using anode-supported single cells and kW class co-generation systems for residential power generation. A 1kW class SOFC system consisted of a hot box part, a cold BOP part and a water reservoir. A hot box part contains a SOFC stack made up of 48 cells with $10{\times}10cm^2$ area and ferritic stainless steel interconnectors, a fuel reformer, a catalytic combustor and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation. A cold BOP part was composed of blowers, pumps, a water trap and system control units. When a 1kW class SOFC system was operated at $750^{\circ}C$ with hydrogen, the stack power was 1.2kW at 30 A and 1.6kW at 50A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about 1.3kW with hydrogen and 1.2kW with city gas respectively. The system also recuperated heat of about 1.1kW by making hot water. Recently KEPRI developed stacks using $15{\times}15cm^2$ cells and tested them. KEPRI will develop a 5 kW class CHP system using $15{\times}15cm^2$ stacks by 2010.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.100.1-100.1
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• 2011

Electrochemical impedance spectroscopy(EIS) are using widely as a useful technique mainly in the field of electrochemical for the analysis of electrode reactions or characteristics of the composites. The response analysis of the systems technique provides comprehensive informations about the characteristic and structure of complex and internal reaction. The EIS is the method to measure impedance of the measurement target classified by the frequency, it select the equivalent impedance model to give same response from the result and it calculate the parameter. Therefore, the chemical reaction inside the fuel cell is to modeling to electrical impedance. And as repeating the same experiment in each of the operating point, we can get each different parameter. As a result, we can establish the equivalent impedance model in each operating point. Therefore, if we use these models, we can evaluate the fuel cell without the internal design parameter of the fuel cell as required in existing modeling. The EIS is used typically technique for distinguish status of fuel cell called SOH(State Of Health). When the fuel cell is degradation, Efficiency and health of the fuel cell is reduced because internal impedance is increase. As usage of these principles, we can evaluate state of fuel cell through the impedance analysis of fuel cells. In this study, we are presents EIS distinction system and algorithm for residential fuel cell systems. At the time of the fuel cell installation in the fields, the EIS system and proposed algorithm will be able to apply as technique for efficiency and performance evaluation about fuel cell system.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.8
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• pp.325-330
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• 2016

This study was conducted to develop a heating system for a fuel cell-driven electric vehicle. The system consists of a compressor, an expansion device and three heat exchangers. A conventional air source heat exchanger is used as primary heat exchanger of the system, and an additional water source heat exchanger is used as a pre-heater to supply heat to the upstream air of the primary heat exchanger. On the other hand, the third heat exchanger consists of a water-to-refrigerant heat exchanger. The heat source of the pre-heater and the water-refrigerant heat exchanger is the waste heat from the fuel cell's stack. In the experiment, the indoor and the outdoor air temperature were fixed, and the compressor speed, EEV opening and waste heat temperature were varied. The results indicate that the $COP_h$ of the proposed system is 3.01 when the system is operating at a 1,200 rpm compressor speed, 50% EEV opening, and $50^{\circ}C$ waste heat source temperature in air pre-heater operation. However, when the system uses a water-refrigerant heat exchanger, the $COP_h$ increases to up to 9.42 at the same compressor speed and waste heat source temperature with 75% EEV openings.

• Applied Chemistry for Engineering
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• v.30 no.1
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• pp.62-67
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• 2019

This study was focused on the design and the performance analysis of integral Hot BoP for recovering waste heat from high-temperature exhaust gas in 2 kW class solid oxide fuel cell (SOFC). The hot BoP system was consisted of a catalytic combustor, air preheater and steam generator for burning the stack exhaust gas and for recovering waste heat. In the design of the system, the maximum possible heat transfer was calculated to analyze the heat distribution processes. The detail design of the air preheater and steam generator was carried out by solving the heat transfer equation. The hot BoP was fabricated as a single unit to reduce the heat loss. The simulated stack exhaust gas which considered SOFC operation was used to the performance test. In the hot BoP performance test, the heat transfer rate and system efficiency were measured under various heat loads. The combustibility with the equivalent ratio was analyzed by measuring CO emission of the exhaust gas. As a result, the thermal efficiency of the hot BoP was about 60% based on the standard heat load of 2 kW SOFC. CO emission of the exhaust gas rapidly decreased at an equivalent ratio of 0.25 or more.

• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.11-15
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• 2016

Proton Exchange Membrane Fuel Cells (PEMFC) instead of batteries is appropriate for long time flight of unmanned aero vehicles (UAV). In this work, $NaBH_4$ hydrolysis system supplying hydrogen to PEMFC was studied. In order to decrease weight of $NaBH_4$ hydrolysis system, enhancement of hydrogen yield, recovery of condensing water and maintenance of stable hydrogen yield were studied. The hydrogen yield of 3.4% was increased by controlling of hydrogen pressure in hydrolysis reactor. Condensing water formed during air cooling of hydrogen was recovered into storage tank of $NaBH_4$ solution. In this process the condensing water dissolved $NaBH_4$ powder and then addition of $NaBH_4$ solution decreased system weight of 14%. $NaBH_4$ hydrolysis system was stably operated with hydrogen yield of 96% by 2.0g Co-P-B catalyst for 10 hours at 2.0L/min hydrogen evolution rate.

• Journal of the Korean Ceramic Society
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• v.43 no.12 s.295
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• pp.812-822
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• 2006

This study amis to investigate the functional analysis of anode and cathode materials in Anode supported Solid Oxide Fuel Cell. The concentration polarization of single cell was investigated with CFD (Computational Fluid Dynamics) method for the case of the different morphology by using four types of unit cell and discussed to reduce the concentration polarization. The concentration polarization at anode side effected the voltage loss in Anode supported Solid Oxide Fuel Cell and increased contact areas between fuel gas and anode side could reduce the concentration polarization. For intermediate temperature operation, Anode-supported single cells with thin electrolyte layer of YSZ (Yttria-Stabilized Zirconia) were fabricated and short stacks were built and evaluated. We also developed diesel and methane autothermal reforming (ATR) reactors in order to provide fuels to SOFC stacks. Influences of the $H_2O/C$ (steam to carbon ratio), $O_2/C$ (oxygen to carbon ratio) and GHSV (Gas Hourly Space Velocity) on performances of stacks have been investigated. Performance of the stack operated with a diesel reformer was lower than with using hydrogen as a fuel due to lower Nernst voltage and carbon formation at anode side. The stack operated with a natural gas reformer showed similar performances as with using hydrogen. Effects of various reformer parameters such as $H_2O/C$ and $O_2/C$ were carefully investigated. It is found that $O_2/C$ is a sensitive parameter to control stack performance.