• Prospectives of Industrial Chemistry
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• v.22 no.5
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• pp.1-13
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• 2019

국제해사기구(IMO, international maritime organization)는 2015년부터 배출규제해역(ECA, emission control area)을 운항하는 선박은 황 함유량이 0.1%(m/m) 이하로 강화된 기준을 만족하는 연료를 사용해야 하며, 2020년부터는 모든 선박에 대해 황 함유량이 0.5%(m/m) 이하인 연료를 사용하거나 동등 이상의 성능을 갖는 배출가스 후처리 장치의 설치를 의무화하였다. 이에 따라, 선박에서 배출되는 오염물질을 제어할 수 있는 다양한 기술이 개발되고 있으며, 후처리 관점에서 습식 스크러버(wet scrubber)는 선박의 디젤 엔진에서 배출되는 이산화황(sulfur dioxide)을 저감시키기 위한 가장 적합한 해결책으로 알려져 있다. 습식 스크러버는 해수를 사용하는 개방형 스크러버(open loop scrubber)와 화학세정수를 사용하는 폐쇄형 스크러버(closed loop scrubber)로 구분된다. 습식 스크러버는 오염물질의 효율적인 처리가 가능하지만 유지보수비가 비싸고, 폐수 발생으로 인한 2차 오염발생 및 부식에 매우 취약한 단점이 있다. 따라서 최근에는 스크러버 내부의 부식을 방지하기 위한 내부식성 재질에 관한 연구와 흡수제(absorbent)의 고도화 연구가 활발히 진행되고 있다. 또한, 하이브리드형 스크러버(hybrid scrubber)는 개방형과 폐쇄형 스크러버의 장점을 결합한 기술로 황산화물의 배출을 규제하는 배출규제해역에서는 폐쇄형 스크러버를 가동하고, 선박이 공해상으로 진입할 경우 개방형 스크러버로 전환함에 따라 황산화물 배출 및 반응 후 세척수의 폐수배출 기준을 동시에 만족할 수 있다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.4
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• pp.405-412
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• 2012

In the MCFC power generation system, the combustor supplies a high temperature mixture of gases to the cathode and heat to the reformer by using the off-gas from the anode; the off-gas includes high concentrations of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and avoid local heating, a catalytic combustor is usually adopted. Catalytic combustion is also generally accepted as one of the environmentally preferred alternatives for generation of heat and power from fossil fuels because of its complete combustion and low emissions of pollutants such as CO, UHC, and $NO_x$. In this study, experiments were conducted on catalytic combustion behavior in the presence of Pd-based catalysts for the BOP (Balance Of Plant) of 5 kW MCFC (Molten Carbonate Fuel Cell) power generation systems. Extensive investigations were carried out on the catalyst performance with the gaseous $CH_4$ fuel by changing such various parameters as $H_2$ addition, inlet temperature, excess air ratio, space velocity, catalyst type, and start-up schedule of the pilot system adopted in the BOP.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.8
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• pp.755-760
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• 2010

In this study, we mainly focused on the PM (Particulate Matter) emission characteristics of a diesel engine. To analyze particle behavior in the tail-pipe, particle emission was measured on the engine-out (downstream of turbocharger), each upstream and downstream both of DOC (Diesel Oxidation Catalyst) and DPF (Diesel Particulate Filter). Moreover, particle emission contours on each sampling point were constructed. The reduction efficiency of particle number concentration and mass through the DOC and DPF was studied. Parameters such as EGR (Exhaust Gas Recirculation) and the main injection timing were varied in part load conditions and evaluated using the engine-out emissions. The DMS500 (Differential Mobility Spectrometer) was used as a particle measurement instrument that can measure particle concentrations from 5 nm to 1000 nm. Nano-particles of sizes less than 30 nm were reduced by oxidation or coagulated with solid particles in the tail-pipe and DOC. The DPF has a very high filtration efficiency over all operating conditions except during natural regeneration of DPF.

• Journal of Korea Port Economic Association
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• v.23 no.1
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• pp.95-113
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• 2007

Recently, International institution such as IMO and major maritime countries have introduced various regulations and steps to reduce port pollution. However, recognition of environmental pollution from ports is not sufficient for Korean policy makers and port communities. The purpose of this paper is to examine solutions to port pollution problems and suggests some implications to Korean ports to become a green port. To this aim, necessity of regulation on environmental pollution from port operation; literature survey on port's environmental pollution; current conditions of international port pollution; various regulations and policies governing major ports are conducted in this paper. Our main findings are as follows; first, air pollution from ship can be reduced by providing electric power at docks while at berth, Second, in case of cargo-handling equipment, retire old equipment and switch to cleaner fuel such as low-sulfur fuel and diesel emulsions. Third, offering incentives for the installation of pollution controls and minimizing idling by enforcing idling limits or by installing idle shutoff controls can be recommended for reduction of air pollution of truck and rail at ports.

• Journal of Korea Port Economic Association
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• v.27 no.1
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• pp.281-304
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• 2011

In the energy-climate era, pollution emissions from port activities have a significant issue in international shipping and port community. Thus international organization such as IMO and developed countries are seeking to develop various reduction strategies against air pollution. However Korea has recently conducted several studies concerning air pollution in port industry. The main purpose of the paper is to suggest emission reduction strategies for bulk terminal in Port of Incheon, which handles large amount bulk cargoes as a gateway for the metropolitan area. For this aim, the clean air strategies of the world major ports were considered and air pollution reduction strategies were suggested. The main findings of this paper are as follows. First, the emission reduction strategies for container terminal are should be integrated based on technologies changes, operational changes and market-based measures. Second, the emission reduction strategies for bulk terminal can be effective when use innovative measures during loading, unloading and storage process such as telescopic cascade trimming chute, snake sandwich equipment, dry fog system and dome structure. Finally, investigation on actual conditions of air pollution in Korean ports and development of environmental evaluation scheme for persisting monitoring should be conducted.

• Journal of Energy Engineering
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• v.10 no.3
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• pp.188-194
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• 2001

The process simulations are made on the IGCC power plant using heavy residue oil from refinery process. In order to model combined power block of IGCC, the present study employs the gas turbine of MS7001FA model integrated with ASU (Air Separation Unit), and considers the air extraction from gas turbine and the combustor dilution by returned nitrogen from ASU. The exhaust gas energy of gas turbine is recovered through the bottoming cycle with triple pressure HRSG (Heat Recovery Steam Generator). Clean syngas fuel of the gas turbine is assumed to be produced through Shell gasification of Visbreaker residue oil and Sulfinol-SCOT-Claus gas cleanup processes. The process optimization results show that the best efficiency of IGCC plant is achieved at 20% air extraction condition in the case without nitrogen dilution of gas turbine combustor find at the 40% with nitrogen dilution. Nitrogen dilution of combustor has very favorable and remarkable effect in reducing NOx emission level, while shifting the operation point of gas turbine to near surge point.

• Journal of Korea Society of Industrial Information Systems
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• v.21 no.3
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• pp.29-33
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• 2016

Development of the distributed energy resources such as photovoltaic, wind, and fuel cell has increased rapidly due to the rising demand for clean energy utilization. On the other hand, the distribution system became complex and has problems such as degradation of power factor and current unbalance caused by power converters, reactive power and unbalanced loads. To solve these problems, this paper proposes a 3-phase 4-leg type power conditioning system with compensation control algorithm for the reactive power and unbalance current in distribution system using photovoltaic resource. It is simulated in PSCAD/EMTDC and the effectiveness is confirmed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.112-118
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• 2018

In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.11
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• pp.636-641
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• 2015

Waste energy conversion to SRF (Solid Refuse Fuel) has the effects not alternative fossil fuel usage but also the reduction of greenhouse gas. But the direct burning of the SRF including a plastic waste generates air pollution problem like soot, dioxin, etc. so that an application of pyrolysis and gasification treatment should be needed. The purpose of this study is to supply a basic thermal data of the pyrolysis gasification characteristics in the plastic-rich SRF which are needed for developing the novel pyrolyser or gasifier. To do so, a bench-scale test rig was newly engineered, and then experiments were achieved for the production characteristics of gas, tar, and char. While SRF sample, gasification air ratio, holding time changed as 2 g, 0.691, 32 min respectively, the $H_2$ 1.36%, $CH_4$ 2.18%, CO 1.88%, $Cl_2$ 15.9 ppm, HCl 6.4 ppm were composed. Also light tar benzene $4.03g/m^3$, naphthalene $0.39g/m^3$, anthracene $0.11g/m^3$, pyrene $0.06g/m^3$, gravimetric tar $18g/m^3$, and char 0.29 g was formed.

• Resources Recycling
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• v.15 no.1 s.69
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• pp.46-57
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• 2006

For the development of combustion technology of RDF(refuse derived fuel), combustion characteristics are examined in bubbling fluidized bed, circulating fluidized bed, continuos combustor and batch type combustor. The characteristics of combustion and exhaust gas has been compared and analyzed in many type of combustion facilities, which has been utilized as basic data for the advanced research of specified RDF combustion facility. Stable combustion has been observed in bubbling and circulating fluidized bed from controled operating condition like the proper feeding rate and superficial gas velocity. In circulating fluidized bed, concentration of NOx has been increased with the operating condition by the fuel-NO and oxygen reaction and $SO_2$ can be considered not to be produced in RDF fluidized bed from very low concentration in flue gas. HCl concentration is 36.4 ppm as average value and lower than standard emission value, but the counter plan is needed. Shaped RDF and fluff RDF have been compared in continuos combustor and batch type combustor and shaped RDF shows benefit for the stable heat recovery and gas emission shows similar value and characteristics.