• Title/Summary/Keyword: 연료극

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A Study on the Performance Recovery of $H_2S$ Poisoned PEMFC ($H_2S$ 피독 고분자 전해질막 연료전지의 연료극 성능 회복 연구)

  • Lee, Soo;Jin, Seok-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.102-107
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    • 2012
  • The recovery of a Pt anode in a PEMFC through 30 ppm $H_2S/H_2$ exposure was evaluated by using a cyclic voltametry(CV) scan. First, the PEMFC unit cell performanc loss was measured three times under an anode feeding with 30 ppm $H_2S/H_2$ for 1hr at $0.5A/cm^2$ of current density. The initial cell performance was $1.16A/cm^2$ at 0.6 V without $H_2S$ poisoning. After first poisoning step for 1hr the cell performance was decrease to $0.77A/cm^2$, and the further poisoning steps decreased up 0.57 V. Finally, the recovery of the cell performance of $H_2S$ poisoned PEMFC was achieved up to 90.3% by applying CV scan. Moreover, we also found out that another possible approach for over 80% recovery of the cell performance of $H_2S$ poisoned anode Pt catalyst layer was to just inject fresh hydrogen into the anode feeding stream.

Performance evaluation and cathode fabrication for solid oxide fuel cell (고체전해질형 연료전지의 공기극 제조 및 특성평가)

  • 김귀열;엄승욱;문성인
    • Electrical & Electronic Materials
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    • v.9 no.9
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    • pp.949-953
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    • 1996
  • In this paper, the cathode materials of solid oxide fuel cell were fabricated, and the analysis of TG/DTA, XRD, thermal expansion and electric conductivity were investigated. As a result, thermal expansion coefficient of LSM was not quite different from that of electrolyte. And the performance of LSM(x=0.4) was more excellent than the others.

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Development of Tubular Solid Oxide Fuel Cell (원통형 고체산화물 연료전지 기술개발)

  • Song, Rak-Hyun
    • 유체기계공업학회:학술대회논문집
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    • 2001.11a
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    • pp.373-380
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    • 2001
  • Solid Oxide Fuel Cells (SOFCs) have received considerable attention because of the advantages of high effiiciency, low pollution, cogeneration application and excellent integration with simplified reformer In this paper, we reported development of anode-tubular SOFC by wet process. For making tubular cell, Ni-cermet YSZ anode tube was fabricated using extrusion process, and YSZ electrolyte layer and LSM-YSZ composite, LSM, LSCF cathode layer were coated onto the anode supported tube using slurry dipping process and sintered by co-firing process. By using this tubular cell, we fabricated single cell consisted of the various cathode layers and 4 cell stack with an effective area of $75 cm^2$ per single cell, and evaluated their performance characteristics.

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Study on the Effect of Physical Properties of Fuels on the Anode Reaction in a DCFC System (연료의 물리적 특성과 직접탄소연료전지의 연료극 반응성에 관한 연구)

  • Ko, Tae-Wook;Ahn, Seong-Yool;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of Energy Engineering
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    • v.20 no.4
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    • pp.309-317
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    • 2011
  • The effect of physical properties of coal fuels and carbon particle on performance of DCFC (Direct Carbon Fuel Cell) was investigated. Shenhua and Adaro were selected as coal fuel and carbon particle was used for comparing with coal. The Ultimate, proximate, SEM, XRD, and BET analysis of samples were conducted. The component of char was more important than that of raw coal because the operating temperature of reactor is higher than devolatilization region of coal. The surface area and volume of pores affected significantly the performance of the system than content of fixed carbon or char rates. The performance of DCFC with carbon particle was in proportional to working temperature.