• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.691-695
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• 2017

Optimization study was carried out to improve the durability of the gas diffusion layer (GDL) in alkaline fuel cell cathode by the use of highly stable PDMS superhydrophobic coating. Two different commercial GDLs were selected as substrates. Coating temperature and viscosity of PDMS were controlled for the stability of structure in microporous layer of GDL as well as uniform coating according to thermal characteristics of GDL. Regardless of PDMS viscosity, highly stable superhydrophobicities were obtained with both GDLs at $200^{\circ}C$. After the accelerated test, however, 28BC GDL coated with 1000 CS PDMS showed the best durability with the lowest loss of superhydrophobicity.

• Journal of the Korean Ceramic Society
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• v.51 no.3
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• pp.224-230
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• 2014

Nano-sized gadolinium-doped ceria (GDC)/nickel particle-dispersed $La_ySr_{1-y}Ti_{1-x}Fe_xO_3$ (LSFTO)-based composite solid oxide fuel cell anodes were fabricated by an infiltration method and the effects of the GDC/Ni nanoparticles on the anode polarization resistance and cell performance were investigated in terms of the infiltration time and nickel content. The anodic polarization resistance of the LSFTO anode was significantly enhanced by GDC and/or Ni infiltration and it decreased with increasing infiltration time and Ni content, respectively. It is believed that the observed phenomena are associated with enhancement of the ionic conductivity and catalytic activity in the nanocomposite anodes by the addition of GDC and Ni. Power densities of cells with the LSFTO and LSFTO-GDC/Ni nanocomposite anodes were 150 and $300mW/cm^2$ at $800^{\circ}C$, respectively.

• Journal of Hydrogen and New Energy
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• v.13 no.2
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• pp.127-134
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• 2002

A Study on the application of ultrasonic with high frequency is carried out as a plan to rise the efficiency of the hydrogen fuel production in an electrolysis of water. KOH is selected as an electrolyte and concentrations are 0 %, 10 %, 20 %, and 30%. The solvent is city water. A measurable device of buoyancy by an electronic balance and a measurable device of voltage with a sensor of pressure are planned newly as a measuring device to measure the quantity of hydrogen production. An ultrasonic transducer with high frequency of 2 MHz is selected to give them the ultrasonic forcing. In results, it is clarified that ultrasonic influences the decrease of overpotential in the electrolytic solution. And basic data according to the pole interval and the temperature are obtained.

• Journal of Hydrogen and New Energy
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• v.22 no.1
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• pp.69-76
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• 2011

PEMFC (polymer electrolyte membrane fuel cell) is device that generates electricity from hydrogen. It is one of the subjects related to renewable energy and various research has been conducted on the PEMFC. PEMFC has low operating temperature and high efficiency among fuel cells, and is given attention as means for automobile and domestic use. Analysis of flow field pattern in supplying hydrogen and oxygen is part of the research to increase PEMFC efficiency. In this study, separation plate currently used in PEMFC is transformed to wave shape and mass transfer characteristics in the channel is examined through numerical and experimental analysis. Wave shape separation plate yielded 18% increase of efficiency compared to separation plate used in normal channel. And improvements in mass transfer characteristics were verified.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.30 no.3
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• pp.143-148
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• 2018

In this study the performance and humidity variation for 2 unit cells connected in series were experimentally measured. The relative flow direction of hydrogen and air was changed from parallel flow to counter flow. Internal humidity distribution was then measured by 5 embedded sensors on each channel. In all experimental conditions, the former unit cell showed a better performance and the gap is noted to be higher when counter flow is applied. The performance was noted to be higher at high humidification case in the parallel flow. However, in the counter flow, the difference of performance according to the humidification is negligible. Hydrogen and air are discharged from the PEMFC unsaturated with water vapor at parallel flow/low humidification condition, which explains lower performance of the PEMFC than other conditions. The humidities in hydrogen and air streams of counter flow were noted to increase rapidly even at low humidification condition and the consequential even hydration of membrane is the reason of higher performance.

• Korean Journal of Materials Research
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• v.10 no.12
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• pp.831-837
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• 2000

To improve the catalytic activity of platinum on polymer electrolyte fuel cell(PEFC), platinum was alloyed with cobalt and nickel at various temperature. By XRD, it was observed the crystal structure of alloy catalysts were the ordered face centered cubic(f.c.c) due to the superlattice line at $33^{\circ}$. As heat-treatment temperature was increased, the particle size of alloys also were increased and the crystalline lattice parameters were decreased. According to the results from mass activity, specific activity and Tafel slope measured by cell performance test and cyclic voltammogram, the catalyst activities of alloys are higher than that pure platinum.

• Journal of the Korean Ceramic Society
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• v.43 no.12 s.295
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• pp.788-797
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• 2006

An anode-supported SOFC single cell having $5{\mu}m$ thin electrolyte was fabricated cost-effectively by tape casting, laminating, and co-filing of anode (NiO-YSZ), cathode (LSM-YSZ), and electrolyte (YSZ) components. The optimal slurry compositions of the green tapes for SOFC components were determined by an analysis of the mean diameter, the slurry viscosity, the tensile strength/strain of the green tapes, and their green microstructures. The single cells with a dense electrolyte and porous electrodes could be co-fired successfully at $1325\sim1350^{\circ}C$ by controlling the contents of pore former and the ratio of coarse YSZ and fine YSZ in the anode and the cathode. The single cell co-fired at $1350^{\circ}C$ showed $100.2mWcm^{-2}$ of maximum power density at $800^{\circ}C$ but it was impossible to apply it to operate at low temperature because of low performance and high ASR, which were attributed to formation of the secondary phases in the cathode and the interface between the electrolyte and the cathode.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2015.10a
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• pp.205-207
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• 2015

LNG/LPG는 폭발가능성이 크기 때문에 매우 위험한 물질이다. LNG/LPG는 gas상태의 연료를 극 초저온에 고 압력 상태로 고농축한 액체 연료이다. 온도나 압력에 따라 물질의 상태가 변하기 때문에 폭발이나 화재가 일어날 수 있다. 하지만 무조건 사고가 일어나는 것은 아니며 현재까지도 화재나 폭발이 일어난 경우가 드물다. LNG/LPG선박은 충돌이나 파손 등 사고위기가 클수록 위험하다. 사고위기가 일어나는 요소로는 복잡한 항로, 많은 선박 수, 해마다 증가하는 LNG/LPG의 수요량 등이 있다. 본 연구에서는 LNG/LPG관련 해양사고 시나리오를 만들기 위해 사고 연계 고리(Accident chain)를 만들어 분석하였다. 해양사고의 연계 고리를 만들기 위해서는 story가 필요하다는 것을 알게 되었고, Risk를 통해 Peril과 Hazard를 분석 할 수 있었다. LNG/LPG의 위험성은 고압에 기인하는 위험, 화재위험, 동상위험, 화학반응의 위험, 질식 위험 등으로 분류 할 수 있었다. 아직까지는 LNG/LPG선박의 화재 및 폭발사고는 거의 일어나지 않았으나 매년 그 수요량이 증가하고 있고, 매우 위험한 물질임을 본 연구를 통해 알 수 있었다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.825-828
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• 2010

APU for aircraft is operated under severe condition as high altitude and low temperature, and demand high reliability in flight. This study is to be verified of the ignition and the combustion stability of APU under the harsh conditions. The basic data obtained in combustion rig test were directly applied to the altitude test with a engine. That start logic was obtained in ground development test. The results of altitude test show that air swirl injector has good operation and ignition performance at 20kft, hot/cold($-40^{\circ}C$) day.

• Journal of Hydrogen and New Energy
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• v.23 no.5
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• pp.476-483
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• 2012

Proper water management is crucial for the efficient operation of polymer electrolyte membrane (PEM) fuel cell. Especially, for automotive applications, A novel water management that can avoid both membrane dry-out and flooding is a very important task to achieve good performance and efficiency of PEM fuel cells. The aim of this study is to investigate the liquid water behavior on the gas diffusion layer (GDL) surface and in the cathode flow channel of a PEM unit fuel cell under flooding conditions. For this purpose, a transparent unit fuel cell is devised and fabricated by modifying the conventional PEM fuel cell design. The results of water droplet behavior under flooding conditions are mainly presented. The water distributions in the cathode flow channels with cell operating voltage are also compared and analyzed. Through this work, it is expected that the data obtained from this fundamental study can be effectively used to establish the basic water management strategy in terms of water removal from the flow channels in a PEM fuel cell stack.