• Title/Summary/Keyword: 에틸렌 함량

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Phase Behavior of Ternary Mixture of Poly(ethylene-co-octene) - Ethylene - 1-Octene (Poly(ethylene-co-octene) - Ethylene - 1-Octene 3성분계 혼합물의 상거동)

  • Lee, Sang-Ho;Sohn, Jin-Eun;Chung, Sung-Yoon;Han, Sang-Hoon
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.116-124
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    • 2006
  • Cloud-point data to $160^{\circ}C$ and 1,000 bar are presented with poly(ethylene-co-15.3 mole% octene) copolymers ($PEO_{15}$) in pure 1-octene and mixtures of ethylene - 1-octene. The cloud-point curves for $PEO_{15}$ - ethylene - 1-octene mixture dramatically increase in pressure to as high as 1,000 bar with an increasing ethylene concentration. At ethylene concentrations less than 18 wt%, the ternary mixture has bubble- and cloud-point curves. As the ethylene concentration of the ternary mixture increases, the bubble-point curve and the single-phase region reduce. The reduction in the single phase region with increasing ethylene concentrations is the result of reduced dispersion interactions between $PEO_{15}$ and the mixed solvent. The single-phase region decreases with increasing temperatures when ethylene concentrations are lower than 36 wt%, whereas the single-phase region increases with temperatures at ethylene concentrations greater than 50 wt%. At ethylene concentrations greater than 50 wt% the effect of the polar interactions of the mixed solvent, which is unfavorable to dissolve PEO, is greater than the effect of the density of the mixed solvent. Therefore, the cloud-point pressures increase with a decreasing temperature. However, at ethylene concentrations less than 50 wt%, the cloud-point pressures decrease with temperature, because the effect of the polar interactions is less than the density effect.

Effect of Ethylene Adsorbent on Apple Fruit Quality during Storage (사과과실 저장성에 미치는 에틸렌흡착제의 효과)

  • Ahn, Young-Jik;Choi, Jong-Seung;Min, Byung-Hoon;Yi, Kyoung-UK
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.169-173
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    • 1996
  • This experiment was conducted to investigate the effect of ethylene adsorbent removing ethylene gas produced from apple fruits in poly ethylene film bag storage. The treatment of ethylene adsorbent was not effected the change in soluble solids and organic acid content of fruits. The fruit softening was remarkably delayed by the absorbent treatment, and the more amount of it was the more effective. The ethylene evolution and respiration of fruits reduced or decreased by this treatment during storage. The ethylene adsorbent for 'Fuji' apple fruit was effective more than 30g per 10kg fruits.

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Effects of high carbon dioxide and ethylene treatment on postharvest ripening regulation of red kiwifruit (Actinidia melanandra Franch) during cold storage (고농도 이산화탄소와 에틸렌처리가 레드키위의 수확 후 저온저장 중 숙성조절에 미치는 효과)

  • Yang, Yong-Joon;Lim, Byung-Seon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.6
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    • pp.478-485
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    • 2017
  • The effect of high carbon dioxide and ethylene treatment on postharvest ripening regulation of red kiwifruit (Actinidia melanandra) was investigated during cold storage. Physio-chemical properties such as weight loss, firmness, SSC, acidity, and market quality were analysed in red kiwifruit held at $10^{\circ}C$ compared to the fruit treated with carbon dioxide and ethylene during 75 days of storage. No significant weight loss was detected in red kiwifruit treated with carbon dioxide until 75 days of storage while the most rapid loss was found in fruit treated with ethylene. In ethylene-treated fruit, the firmness was dramatically reduced from 4.2kg on the first day to 1.2 kg after 27 days of storage at $10^{\circ}C$. However, the firmness of the carbon dioxide-treated fruit was 1.8kg after 54 days of storage. The highest level of SSC(%) was investigated within the 27 storage days at $10^{\circ}C$ for fresh red kiwifruit treated with exogenous ethylene, whereas the carbon dioxide-treated fruit exhibited a greatly increased SSC after 64 days. The carbon dioxide-treated red kiwifruit maintained statistically(p<.01) higher levels of acidity compared to the control and the exogenous ethylene-treated ones during 41 days of storage at $10^{\circ}C$. The SSC/Acid ratio of fruit treated with carbon dioxide was significantly lower (p<.01) maintained than the other two treatments (ethylene-treated and control fruit)throughout the 75-day experiment. Based on the quality characteristics of postharvest red kiwifruit, it could be concluded that the carbon dioxide treatment significantly delayed the ripening process and maintained the market quality of harvested red kiwifruit, which can be a potential application for commercial use in the kiwi industry.

Effects of Methylglyoxal-bis (Guanylhydrazone) and Ethylene Synthesis Inhibitor on Adventitious Root formation from Soybean Cotyledon (Methylglyoxal-bis (Guanylhydrazone)와 에틸렌 생합성 저해제가 대두 자엽 부정근 형성에 미치는 영향)

  • 조형일;한태진;하건수;이순희;김응식
    • Korean Journal of Plant Tissue Culture
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    • v.21 no.6
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    • pp.327-332
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    • 1994
  • The effect of methylglyoxal-bis (guanylhydrazone) (MGBG) and ethylene synthesis inhibitors on adventitious root formation from soybean cotyledon in relation to ethylene production and endogenous polyamine content was investigated. Cotyledon explants cultured on rooting medium formed numerous adventitious rook on the cut surfaces after 2 weeks of culture. However when cultured on rooting medium supplemented with MGBG, the root formation was strongly inhibited, its inhibitory effect was reserved when cultured on medium with MGBG + spermine, MGBG + CoCl$_2$ and MGBG + spermine+CoC1$_2$. A slight reversion of the rooting inhibition was observed in 10$^{-3}$ M MGBG +10$^{-5}$ M spermine treatment, whereas it caused a significant effect in 10$^{-3}$ M MGBG +10$^{-4}$ M treatment .Ethylene production and endogenous polymine content was investgated in 10$^{-3}$ M MGBG , 10$^{-3}$ M MGBG +10$^{-5}$ Mspermine, 10$^{-3}$ M MGBG +10$^{-4}$ M CoCl$_2$and 10$^{-3}$ M MGBG +10$^{-5}$ M spermine +10$^{-4}$ M CoCl$_2$treatments. Ethylene production highest in 10$^{-3}$ M MGBG +10$^{-5}$ M spermine treatment was higher than control. In 10$^{-3}$ M MGBG +10$^{-5}$ M spermine + 10$^{-4}$ M CoCl$_2$ treatment, ethilene production was lowest, whereas polyamine level was highest.

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Crystallization Characteristics of Metallocene Low Density Polyethylene (메탈로센 선형 저밀도 폴티에틸렌의 결정화 거동)

  • 김경룡;한정우;조봉규;강호종
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.833-839
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    • 2001
  • The crystallization characteristics of metallocene linear low density polyethylene was investigated by small angle light scattering and comparison was made with Ziegler-Natta linear low density polyethylene. The special efforts were made to find out the effects of branching number, length of branching and co-monomer content of m-LLDPE on the crystallization behavior of m-LLDPE. It was found that m-LLDPE has longer induction time to start crystallization from the amorphous state than that of conventional LLDPE with similar branching number, but the rate of crystallization seems not change much in both LLDPEs. Lowering of branching number in m-LLDPE resulted in both increasing of rate of crystallization and reducing induction time to crystallize. In general, the maximum size of spherulites of m-LLDPE is bigger than that of conventional LLDPE.

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Study on the Thermal Properties and Adhesion Strength of Amorphous Polyalphaolefins/Petroleum Resin Blonds as a Hot Melt Adhesive (핫 멜트 접착제로 사용되는 비 결정성 올레핀 수지/석유수지 블렌드의 열적 성질 및 접착성에 관한 연구)

  • 홍인오;김환기;강호종
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.513-519
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    • 2000
  • The effect of petroleum resin as a tackifier for polyalphaolefin (APAO) hot melt adhesive on thermal properties, crystallinity and adhesion strength was investigated. The presence of petroleum resin resulted in the melting temperature decrease in APAO/petroleum blend, especially, in APAO with low ethylene content/C$_{5}$ petroleum blend. It was also found that petroleum resin caused the decrease of crystallinity regardless of ethylene content in APAO. The maximum adhesion strength was found to be at 50/50 (APAO/petroleum) composition. $C_{5}$ resin was more effective to increase adhesion strength than $C_{9}$ for APAO with high ethylene content. In addition, it was found that the adhesion strength was improved with the decrease of crystallinity in APAO/petroleum resin hot melts.

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MA Strotage Response of Fresh Lemongrass Depending upon Film Source and Storage Temperature (필름종류와 저장온도에 따른 Lemongrass의 MA 저장성 비교)

  • Park, Kuen-Woo;Kang, Ho-Min;Kim, Chung-Ho
    • Horticultural Science & Technology
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    • v.18 no.1
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    • pp.18-21
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    • 2000
  • This study was carried out to investigate the MA response of fresh lemongrass (Cymbopogon citratus) depending upon film sources and storage temperatures. The fresh weight loss was significantly lower at 5 and $0^{\circ}C$ than those of higher temperatures. And ceramic $80{\mu}m$ film (CE 80) was more effective in preventing weight loss than CE40. The contents of $CO_2$ and ethylene were much higher in CE 80 wrapping than those in CE 40 ones. Rapid accumulation of $CO_2$ was observed at high storage temperature. However, the ethylene content during whole storage period was higher at $0^{\circ}C$ than those at $5^{\circ}C$, but the level of ethylene was remained below 1ppm and did not adversely affected to lemongrass quality. The treatment of CE 80 at $5^{\circ}C$ was most effective on keeping visual quality and chlorophyll content. The storage durations were up to 48 days at $5^{\circ}C$ and 35 days at $0^{\circ}C$, respectively. Results indicated that CE 80 at $5^{\circ}C$ is an optimal condition for MA storage of lemongrass.

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Physical Properties of the Melt Spun Fibers of the High Density Polyethylene and Polypropylen Blends (용융방사한 고밀도 폴리에틸렌 폴리프로필렌 블렌드 섬유의 물리적 성질)

  • 조준한;최경식;김상용
    • The Korean Journal of Rheology
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    • v.1 no.1
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    • pp.63-70
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    • 1989
  • 고밀도 폴리에틸렌과 폴리프로필렌을 용융혼합하여 블렌드를 만들었다. 압출물의 morphology 와 유변학적 성질을 측정하고 그 용융하고 섬유의 X-선 회절, 인장 성질, 복굴 절률등과 관련하여 고찰하였다. 파단면의 SEM 사진으로부터 폴리에티렌 성분비가 25%, 50% 에서는 폴리프로필렌이, 75%에서는 폴리에틸렌이 연속상을 이루며 분산상은 고르게 분포함을 알았다 점도와 용융탄성은 모두 폴리에틸렌이 폴리프로필렌보다 크며 블렌드에서 는 그중간에 위치 하였다. 폴리에틸렌의 함량의 증가에 따라 압풀물의 제 1법선 응력차는 증가하였고따라서 방사 섬유의 복굴절률도 증가하였으며 초기 탄성률도 증가하는 경향을 보 였으나 결정 배향도는 조성 의존성을 갖지 않는다. 두 고분자의 비상용성으로 인해 강도는 짓선성에서 벗어나는 거동을 나타내었다.

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Study on crystallization behavior of an ethylene-polypropylene copolymer based encapsulant for photovoltaic application (태양전지 봉지재용 에틸렌-프로펠렌 공중합체의 결정화 거동에 관한 연구)

  • Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.12
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    • pp.737-742
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    • 2016
  • We prepared five different ethylene-propylene copolymers (EPCs) for use as the encapsulant of a photovoltaic module. All of the polymers were of commercial grade from ExxonMobile company and had different ethylene/propylene compositions. The crystallization behaviors and crystal structures of the polymers were analyzed by differential scanning calorimetry and wide angle X-ray scattering diffractometry, respectively. We observed the general trend that the degree of crystallization, density and glass transition temperature of the EPCs decreased with increasing ethylene content. However, an unexpected result was also observed: the EPC with the highest ethylene content (22.2 mol. %) showed the highest melting temperature. As a result, the EPC with 22.2 mol. % of ethylene shows the highest light transmittance, due to its having the lowest degree of crystallization and highest thermal creep resistance. This abnormal result is attributed to the blocky structure prepared by ExxonMobile's special catalyst technology. It was also observed that new additional melting peaks appeared as the crystallization time increased. Using wide angle X-ray scattering diffractometry, it was confirmed that these additional peaks originated from the formation of a new crystal structure caused by annealing.

Arabidopsis thaliana의 Ethylene Triple Response Mutant에서 에틸렌 생합성 과정의 생리 생화학적 특성

  • 이준승
    • Journal of Plant Biology
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    • v.39 no.1
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    • pp.31-40
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    • 1996
  • The physiological and biochemical characterizations of the ethylene-related mutants in Arabidopsis thaliana - ethylene overproducing mutant (eto1-l) and ethylene insensitive mutants (etrl-3, ein2-l) - were detailed in this studies. Two or three week.old mature rosette leaves (before bolting) were used as the plant materials. Ethylene productions of eto1-l, etrl-3, and ein2-l mutants were about 200%, 400%, and 450% compared to that of wild type, respectively. ACC synthase and ACC oxidase activities of eto1-l mutant were similar to those of wild type. ACC content and ACC N-malonyltransferase activity, however, were 4.5 times and 3 times higher than those of wild type, respectively. SAM synthetase activity increased by 50% in eto1-l mutant plant. These results indicated that the alteration in the eto1-l mutant occured before the step of the conversion of SAM to ACe. In etrl-3 and ein2-l mutants, ACC synthase activities increased, but ACC oxidase activities decreased. ACC content and ACC N-malonyltransfcrase activity were 2 times higher than those of wild type. SAM synthetase activity in etrl-3 is similar to those of wild type, while it increased by 73% in ein2-l. These results showed that the block in ethylene action affected the autoregulation of ethylene biosynthesis, so that ACC synthase activity was not autoinhibited and ACC oxidase activity was not auto stimulated by ethylene. When the leaf tissues were used for in vitro kinase assay, a cytosolic protein (approximately 36 kDa) was phosphorylated only in eto1-l and ein2-l mutants.utants.

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