• Title/Summary/Keyword: 에틸렌글리콜

Search Result 167, Processing Time 0.028 seconds

Effect of Introducing EG on Foamed Cellular Structure and Properties in the Foaming Process of Rigid PU (경질 PU발포공정에 있어서 EG의 첨가가 발포체의 구조와 물성에 미치는 영향)

  • Baek, Woon-Seon;Lee, Kee-Yoon
    • Polymer(Korea)
    • /
    • v.25 no.4
    • /
    • pp.528-535
    • /
    • 2001
  • Polyurethane specimens were mainly composed of polyol, MDI, silicone surfactant, and water. The effects of ethylene glycol on the cell size, forming magnification, cream time, gel time, take free time, final free rising height, and reactive temperature were investigated. The cyclopentane was used for PU foam as a physical blowing agent. The components were hand-mixed at about 5000 rpm within 4 seconds at room temperature. The mixtures with various ethylene glycol contents were foamed in the wood mold. When the index of isocyanate was fixed, as the amount of ethylene glycol increased, cell size and thermal conductivity were decreased by about 5.1% and 14%, respectively.

  • PDF

Preparation and Release Behavior of Methoxy poly(ethylene glycol)- poly(L-lactide-co-glycolide) Wafer Containing Albumin (알부민을 함유한 메톡시 폴리(에틸렌 글리콜)- 폴리(L-락타이드-co-글리콜라이드) 웨이퍼의 제조 및 방출거동)

  • 서광수;김문석;김경자;조선행;이해방;강길선
    • Polymer(Korea)
    • /
    • v.28 no.4
    • /
    • pp.328-334
    • /
    • 2004
  • A series of methoxy poly(ethylene glycol) (MPEG)-poly(L-lactide-co-glycolide) (PLGA) diblock copolymers were synthesized by ring-opening polymerization of L-lactide and glycolide with carbitol (134 g/mole) or different molecular weights of MPEG (550, 2000, and 5000 g/mole) as an initiator in presence of Sn(Oct)$_2$. The properties of diblock copolymers were characterized by using $^1$H-NMR, GPC, and XRD. After uniform mixing of block copolymers and 1% albumin bovine-fluorescein isothiocyanate(FITC-BSA) with a freeze miller, the wafers loaded FITC-BSA were fabricated by using a mold with a dimensions of 3 mm${\times}$1mm diameter. The release profiles of FITC-BSA and the pH changes of wafer were examined using pH 7.4 PBS for 30 days at 37$^{\circ}C$. The release profiles of albumin showed fast initial burst as the molecular weights of MPEG increased. As a result of this study, the release behavior of BSA was controlled with introducing MPEG in the block copolymers.

Preparation of Polystyrene Particles Containing Poly(ethylene glycol) Groups and Their Surface Charge Characterization in Dielectric Medium (폴리(에틸렌 글리콜)기를 갖는 폴리스티렌 입자의 제조와 유전 매질내에서의 표면 전하 특성)

  • 김성훈;김배중;권대익;박기홍
    • Polymer(Korea)
    • /
    • v.28 no.6
    • /
    • pp.524-530
    • /
    • 2004
  • Polystyrene particles (PS) with poly(ethylene glycol) units on surface were formed by an emulsifier-free emulsion polymerization using styrene, poly(ethylene glycol) methacrylate (PEG-MMA) or poly(ethylene glycol) dimethacrylate (PEG-diMMA) at pH 7, and followed by freeze-drying to give the corresponding powders. The structures of PS particles were confirmed by FT-IR spectroscopy, and the particle size and distribution the PS particle were observed by scanning electron microscopy and particle analyzer. Monodisperse polymer particles were obtained at a concentration of PEG-MMA 2∼5 mol% or PEG-diMMA 1 mol% relative to styrene. The highest zeta potential of polymer surface was measured to be 183 mV at a polymer of PEG-MMA 5 mol%, which was measured in dielectric medium by means of ELS-8000 dynamic light scattering.

Effect of ethylene glycol on the nano-sized ZnO nanoparticles using polyol process (폴리올 공정을 이용한 에틸렌 글리콜이 나노 크기의 산화아연 나노입자에 미치는 영향)

  • Dae-Hwan Jang;Bo-Ram Kim;Dae-Weon Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.34 no.4
    • /
    • pp.117-124
    • /
    • 2024
  • Zinc oxide nanoparticles were synthesized using the polyol method with ethylene glycol containing hydroxyl groups (-OH). It was confirmed that the zinc compounds prepared by the polyol method were a mixture of zinc carbonate hydroxide (Zn5(OH)6(CO3)2) and zinc oxide (ZnO) crystalline structures. Calcination at 400℃, 600℃ and 800℃ was performed to examine the effects of calcination temperature on the particle size, morphology and crystallinity of zinc oxide. ZnO powders of calcination at 800 ℃ was evaluated to particle size analysis from ethylene glycol containing precursor solution compared with distilled water based solution. The zinc oxide particles obtained from the former had a particle size of approximately 404 ± 51 nm, whereas those from the latter exhibited a more uniform nanoparticles morphology with a particle size of approximately 109 ± 29 nm. This demonstrates that the addition of ethylene glycol can control the influence of water molecules, enabling the direct synthesis of zinc oxide in the form of uniform nanoparticles.

An analysis on the characteristics of regasification system for LNG-FSRU depending on the changes in performance with vaporization and temperature of the heat source (LNG-FSRU용 재기화 시스템의 열원 온도 및 기화성능의 변동에 따른 시스템 특성분석)

  • Lee, Yoon-Ho;Kim, You-Taek;Kang, Ho-Keun
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.38 no.6
    • /
    • pp.625-631
    • /
    • 2014
  • In this study, according to increase of thermoelectric power plants that use LNG, LNG-FSRU(Floating-Storage and Regasification Unit) appeared and it is installed on the Topside in order to deliver in a gaseous state to consumers who are in the shore. This study about the study on the characteristics analysis of the system depending on changes in performance with the vaporization and temperature of the heat source. For the characteristics analysis of the system, we devided vaporization method into Ethylene glycol water vaporization method and sea water as a heat source. Then the system that can vaporize 200ton per hour of LNG of $-157.9^{\circ}C$ and 10,400kPa was configured, and according to the temperature of supplied sea water, required minimum flow rate value was calculated. Also in case of using Ethylene glycol Water as a vaporization method, providing for regional and seasonal factors such as decrease of temperature of water. The system is configured by adding a steam boiler of $174.5^{\circ}C$, 775kPa as heat source. The generation amount of the steam required according to the performance of the vaporizer compared to the water temperature changes in the steam boiler and the amount of required evaporative performance due to changes in the quantity of steam and Ethylene glycol Water was confirmed.

Analysis of Thermodynamic Design Data for Heating of Double - Effect Solar Absorption System using LiBr - water and Ethylene Glycol Mixture (에틸렌글리콜 혼합액을 사용하고, 태양열을 보조열원으로 하는 이중효용 흡수식 시스템의 난방 특성해석)

  • Won, S.H.
    • Journal of the Korean Solar Energy Society
    • /
    • v.22 no.4
    • /
    • pp.51-61
    • /
    • 2002
  • Analysis of thermodynamic design data of double effect solar absorption heat pump system for heating has been done to find the property of Libr-water + ethylene Glycol mixture for working fluid by computer simulation. Derived thermodynamic design data. enthalpy based coefficient of performance and flow ratio for possible combinations of operating temperature for water - LiBr and Ethylene Glycol mixture (H2O: CHO ratio 10:1 by mole) by computer simulation. The obtained results, COP and mass flow ratio of the water-lithium bromide-ethylene glycol system, are compared with data for the water-Libr pair solution.

Experimental Investigation of Thermal Conductivities of EG-based ZnO Nanofluids Manufactured Using Pulsed Wire Evaporation Method (전기선 폭발법에 의해 제작된 에틸렌 글리콜 기반 ZnO 나노유체의 열전도도)

  • Kim, Hyun-Jin;Hwang, Kyo-Sik;Shin, Hyun-Kyo;Rhee, Chang-Kyu;Lee, Gyung-Ja;Yoon, Jong-Ho;Jang, Seok-Pil
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.36 no.2
    • /
    • pp.111-115
    • /
    • 2012
  • In this paper, the thermal conductivities of ethylene glycol. based ZnO nanofluids manufactured using the pulsed wire evaporation method are experimentally measured using the transient hot wire method at temperatures in the range of $10^{\circ}C$ to $50^{\circ}C$. For this purpose, ethylene glycol.based ZnO nanofluids with 1%, 3%, and 5.5% volume fractions were manufactured using the pulsed wire evaporation method. Transmission electron microscopy (TEM) was performed to investigate the suspension stability of the ethylene glycol.based ZnO nanofluids. Based on the experimental results, the thermal conductivities of ethylene-glycol-based ZnO nanofluids increase with increasing volume fractions of ZnO nanofluids. The maximum enhancement of the thermal conductivity is 26.5% for a volume fraction of 5.5% at $22^{\circ}C$. Finally, the experimental results are compared with conventional models such as the Maxwell and Hasselman & Johnson models.