• Title/Summary/Keyword: 약산

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Spectrophotometric Study of the Complex Formation of Ferric Ion with Xylenol Orange (Fe(III)와 Xylenol Orange의 착물형성에 대한 분광광도법적 연구)

  • O Tae Sub;Lee Sun Haing;Park Jung Hag
    • Journal of the Korean Chemical Society
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    • v.22 no.5
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    • pp.311-316
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    • 1978
  • The reaction between iron(III) and Xylenol Orange (XO or $H_6A$) has been investigated spectrophotometrically. It has been established that iron (III) and XO form two complexes with compositions iron(III) : XO = 2 : 1 and 1 : 1. The 2 : 1 complex is stable in acidic medium containing excess of iron, and 1 : 1 complex is stable in slightly acidic medium containing excess of XO. The absorption maxima are at 590 nm (2 : 1) and 500 nm (1 : 1), the molar absorptivities being $3.18{\pm}0.04{\times}10^4,\;1.32{\pm}0.03{\times}10^4$respectively. The stability constants of two complexes studied by varying pH are $loglog{\beta}_{21}=18.69{\pm}0.03,\;log{\beta}_{212}=42.08{\pm}0.09,\;log{\beta}_{11}=4.17{\pm}0.04,\;and\;log{\beta}_{113}=34.47{\pm}0.07.$

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Interpretation of heavy metal elements from the road dusts using GIS (GIS를 이용한 도로 분진의 중금속원소 함량 해석에 관한 연구)

  • 이효재;이근상;이언호;장영률
    • Spatial Information Research
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    • v.10 no.2
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    • pp.201-213
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    • 2002
  • Chemical analyzes were carried out the samples from roadsides of the Gwangju city. The purpose of this research is to investigate the concentrations and distribution patterns of heavy metals due to urbanization and industrialization in the Gwangju city This study area is not significantly contaminated based on the concentrations of Cd, Cu, Fe, Mn, Pb and Zn. However, the concentrations of the chemical elements analyzed are locally higher than those of serious contamination level indicated by Ministry of environment. The dust pH is in the rage of 5.60-7.09 and was generally neutral, and there are no difference in pollution area and nonpollution area. Chemical analyses utilized are dilution by 0.1N HCl. In result of analysis by the method using 0.1N HCl, concentrations of Cd and Cu are a little high in Gwangchondong of Seo-Gu. Concentrations of Mn and Pb are a little high in Buk-Gu and Nam-gu, and Concentrations of Zn are generally higher than average of soils. Zn, in the study area, keeps polluting greatly as Zn concentration of average is 150.9ppm. All of P.I values are lower than 1, it means heavy metal pollution is not serious.

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Evaluation of Seismic Performance of Mixed Building Structures by using the Nonlinear Displacement Mode Method (비선형 변위모드법을 적용한 복합구조물의 내진성능평가)

  • 김부식;송호산
    • Journal of the Earthquake Engineering Society of Korea
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    • v.7 no.6
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    • pp.71-80
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    • 2003
  • Though a nonlinear time history analysis may be provided to estimate more exactly the seismic performance of building structure, approximation methods are still needed in the aspect of practicality and simplicity, In converting a multi-story structure to an equivalent SDOF system, the mode vectors of the multi-story structure are assumed as the mode shape in elastic state regardless of elastic or elastic-plastic state. However, the characteristics of displacement mode are also changed after the yielding made in the structural elements, because the structure becomes inelastic in each incremental load step. In this research, a method of converting MDOF system to ESDOF system is presented by using nonlinear displacement mode considering the mode change of structures after the yielding. Also, the accuracy and efficiency of the method of the nonlinear displacement mode method of the estimate of seismic response of Mixed Building Structures were examined by comparing the displacements of the roof level of the multi-story building structures estimated from this converted displacement response of ESDOF with the displacement of the roof level through the nonlinear dynamic analysis of the multi-story building structures subjected to an actual earthquake excitation.

Characteristics of mycelial culture of Sparassis crispa (꽃송이버섯 균사배양적 특성)

  • Chang, Hyun-You;Choi, Seung-Oh
    • Journal of Mushroom
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    • v.2 no.3
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    • pp.163-167
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    • 2004
  • It shows that there is the fastest growth of S. crispa in the weak acid pH5. Also, it shows that S. crispa has the best environment in the MEF media. The next desirable one was as in this array: MES, MEI, YMF, YMM, YMT, YMB, YMI, MEA, PDA. The best fungi-growth of S. crispa is shown within the 0.2% addition of multi-mineral. The slow fungi-growth of S. crispa is shown within as the opposite. The phisical growth of S. crispa has a absolute need of comparatably large amount of P,K,N,S etc as inorganic minerals. In addition of that, as a minor element, Fe, Zn, Cu, Mo, Co, Mn, Cl etc are should be included. The best fungi-growth of S. crispa is shown within the 0.1% addition of biotin. The slow fungi-growth of S. crispa is shown within as the opposite. The best fungi-growth of S. crispa is shown within the 2% addition of fructose. The slow fungi-growth of S. crispa is shown within as the opposite.

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Vegetation Structures and Ecological Properties of Sterwartia koreana Community (노각나무(Stewartia koreana)군락의 식생구조와 생태특성)

  • Kwon, Hyejin;Song, Hokyung
    • Journal of Korean Society of Forest Science
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    • v.97 no.3
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    • pp.296-304
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    • 2008
  • This study was carried out to analyze vegetation and soil characteristic, and ordination of Stewartia koreana community. The Stewartia koreana community was classified into Acer mono subcommunity, Pinus densiflora subcommunity, Sapium japonicum subcommunity, and Stewartia koreana typical subcommunity. In the study sites, soil organic matter, nitrogen, available phosphorous, exchangeable K, exchangeable Ca, exchangeable Mg concentration, cation exchange capacity, and soil pH were ranged from 14.31~34.27%, 0.33~0.77%, 7.83~22.88(mg/kg), 0.23~1.07(me/100 g), 0.29~2.93(me/100 g), 0.33~1.49(me/100 g), 10.47~22.48(me/100 g), and 4.65~4.96, respectively. The area of the Acer mono subcommunity, found in highlands, showed that contained the highest organic substances, nitrogen, available phosphorous, and cation exchangeable capacity concentration among the communities. The low elevation regions where the Pinus densiflor subcommunity is formed, showed the lowest concentrations of exchangeable Ca, and Mg.

Solvent Extraction of Organotin from Ship Wash Wastewater (선박 세척폐수에 함유된 유기주석화합물의 용매추출특성)

  • Song, Young-Chae;Woo, Jung-Hui;Kim, In-Soo;Park, Sang-Ho;Kim, Dong-Geun
    • Journal of Navigation and Port Research
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    • v.28 no.5
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    • pp.463-468
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    • 2004
  • A lab-scale fundamental study to develop the solvent extraction process of ship wash wastewater containing TBT was carried out. For various solvents, including diesels for car and ship, bunker B, thinner, toluene, and ether, the extraction efficiencies of TBT from synthetic ship wash wastewater were compared The effect of extraction conditions, such as solvent amount, time and intensity of agitation, and pH, on the extraction efficiency of TBT was evaluated Diesel for ship showed better extraction efficiency of TBT than those of other tested solvents, and the proper amount of the extraction solvent for 1L of the wastewater was l0mL. When the agitation intensity was increased from 50rpm to 250rpm, the TBT remained in the wastewater after the extraction was decreased from around 120ppb to 2.8ppb. The remaining TBT in the wastewater was sharply decreased from 1hr of the extraction time, but was slightly increased again after 5hrs of the extraction time. The efficiency of TBT extraction was good in the weak acid range of pH, but was not significant as much as the others.

Contamination of Heavy Metals from Dongmyeong Au-Ag Mine Area (동명 금-은 광산 주변의 중금속 오염)

  • 이광춘;김세현;이승호;서용찬
    • Economic and Environmental Geology
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    • v.36 no.1
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    • pp.17-25
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    • 2003
  • Researches were carried out to investigate the characteristics and concentration of heavy metal elements of stream water through Dongmyoung abandoned metal mine and soil adjacent to the mine. The pH range of water was 5.9∼7.1 that implies the water environment was acidic to neutral. The contents and distribution aspects of heavy metals in water samples varied with geochemical characteristics of element, but the concentration of heavy metals has the tendency of increase closer to the mine in general. The results of soil analysis show that total heavy metal concentration of agricultural soil near mine was far lower than those of ore tailing and dumping site. Therefore, the effects of the abandoned mine on stream water and agricultural products were supposed to be insignificant, particularly because the portion of absorbed carbonates and reducible fractions among total heavy metal concentration was relatively lower than the other. Since, however total heavy metal concentrations of mining site were relatively higher than those of adjacent region, there is a possibility of heavy metal difussion when the chemical environment of the site changes due to migration of surface and underground water. It is suggested that the preventive measures for water and soil pollution by the heavy metals would be considered around the region.

Preliminary Study on Seed Germination and Bacterial Bioluminescence for Assessing the Toxicity of Domestic Bentonites (씨앗 발아와 박테리아 발광을 이용한 국내 벤토나이트 독성 평가를 위한 사전 연구결과)

  • Kong, In Chul;Lee, Mun Hee;Jang, Hyun Jin;Lee, Eun Jin;Ko, Kyung Seok;Kang, Il Mo
    • Economic and Environmental Geology
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    • v.49 no.5
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    • pp.411-415
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    • 2016
  • In this preliminary study, we assessed the toxicity of domestic bentonites using environmental toxicity testings of seed germination and bacterial bioluminescence. In cases of tested bulk bentonite samples, following ranges of toxicity were observed: -3 ~ 95% bioluminescence, 7.1 ~ 92.1% Lactuca germination. Similar results were also observed among tested other seeds, except seed Raphanus. No significant correlations between toxicity and metals contents of bentonite extractants were observed throughout this investigation. Interestingly, distinct different effects were observed according to bentonite colors (blue $67{\pm}8.7%$, pink $27{\pm}10.4%$, brown $58{\pm}14.5%$).

Flora and Restoration Plan of Sandeul Wetland in Mt. Jaeyak, Miryang-si, Korea (밀양시 재약산 산들늪의 식물상과 복원방안)

  • You, Ju-Han;Park, Kyung-Hun;Jung, Sung-Gwan;Kim, Kyung-Tae;Lee, Woo-Sung
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.1
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    • pp.13-31
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    • 2009
  • The objectives of this study were to offer the basic data for the restoration and conservation of forest wetland by surveying systematically the vascular plants of Sandeul wetland in Mt. Jaeyak, Miryang-si, Gyeongsangnam-do, Korea. The vascular plants in this wetland were recorded as 232 taxa; 74 families, 178 genera, 200 species, 27 varieties and 5 forma. The major communities were Quercus mongolica, Tripterygium regelii, Alnus japonica, Molinia japonica, Salix gracilistyla and Stephanandra incisa. The numbers of plant species by routes were 168 taxa in A-route, 126 taxa in B and 132 taxa in C. The ecological problems in Sandeul wetland were the afforestation of Pinus koraiensis and P. thunbergii, the appearance of naturalized plants, the invasion of species and the scour of valley. The Korean endemic plants were 5 taxa; Salix hallaisanensis, Hepatica insularia; Chrysosplenium barbatum, Ajuga spectabilis and Weigela subsessilis. The rare plants designated by Korea Forest Service were 3 taxa; Aristolochia manshuriensis, Chrysanthemum lineare and Iris ensata var, spontanea. The naturalized plants were 8 taxa; Rumex acetocella, R. crispus, Trifolium repens, Oenothera lamarckiana, Ambrosia artemisifolia var. elatior, Helianthus tuberosus, Erigeron annuus and Phleuum pratense.

Systemic Amyloidosis in a Cocker Spaniel (Cocker spaniel 견에서 발생한 전신성 아밀로이드증)

  • Pak Son-Il;Kim Doo;Han Jeong-Hee
    • Journal of Veterinary Clinics
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    • v.23 no.2
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    • pp.186-189
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    • 2006
  • A 7-month-old female Cocker spaniel dog was examined for chronic anemia. Based on information provided by local clinician the patient had had a 'flu-like' illness three weeks before submission of the sample, had a fever of $40.9^{\circ}C$, and had mild hepatomegaly. This dog had also history of weight loss, vomiting, anorexia, dehydration, lethargy, ascites, polyuria and polydipsia. A blood smear showed non-regenerative anemia. Thoracic radiograph showed irregular shadowing in the left mid-zone. Serum biochemical results showed a hypercalcemia, azotemia, hypercholesterolemia, hyperphosphatemia, hypoalbuminemia, and metabolic acidosis. Results of urinalysis showed proteinuria, slightly acidic with isosthenuria. Histopathologic examination of tissue sections revealed amyloid deposits in multiple sites including kidneys, liver and spleen.