• KSBB Journal
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• v.11 no.4
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• pp.462-469
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• 1996

Biosolubilization of an Australian lignite was investigated by using Streptomyces viridosporus and Poria cocos. In order to solubilize coals effectively they were pretreated by nitric acid both in surface and liquid cultures. The optimum growth pH was 7.5 for S. viridosporus and 4.5 for P. cocos. The effects of various carbon, nitrogen and metal sources on overall solubilization were also studied. Solubility increased with the addition of urea for S. viridosporus, and peptone and tryptone for P. cocos. However carbon and metal sources had little or negative effects on solubilization. Maximum amount of coal solubilized was 85%(w/w) in a batch fermentation culture. Extracellular materials produced by micro-organism were found to be responsible for the coal solubilization. Approximately 70 to 80% of coal solubilization was determined to be the result of non-enzymatic reactions, and the rest to be the result of enzymatic reactions. Characteristics of the solubilized coal were compared with those of original coal and pretreated coal by the approximate and ultimate composition analysis, and IR-spectrum analysis. The spectroscopic results showed that the mechanism of coal solubilization was caused by continuous oxidation.

• Journal of Korea Foresty Energy
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• v.21 no.3
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• pp.1-9
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• 2002

Various types of acids, such as mineral acids, organic acids, and organic sulfonic acids, were used as catalysts in order to investigate their effectiveness during phenol liquefaction of pine bark. Hydrochloric arid was the most effective acid catalyst of the mineral acids used in this experiment for the phenol liquefaction, but the amount of the acid needed for more than 90% liquefaction was at least 11 mmol. Among the carboxylic acids used triflouroacetic acid (TFA) was effective for the liquefaction, but it was not possible to obtain liquefaction of more than 80%. Organic sulfonic acids, p-toluenesulfonic acid (PTSA) and methanesulfonic acid (MSA), showed remarkable effects for liquefaction, even in small amounts and at low liquefaction temperatures. Especially in the case of PTSA, a 92% liquefaction yield was obtained at the liquefaction condition of 14$0^{\circ}C$ for 2 h. Therefore, it was evident that the PTSA is a good acid catalyst for the phenol-pine bark liquefaction system.

• 기계와재료
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• v.24 no.1
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• pp.26-35
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• 2012

가스액화플랜트는 질소, 산소, 헬륨 등 고순도의 가스를 효율적으로 저장 및 운송을 위해 가스를 액체로 변환하는 플랜트로, 대표적인 플랜트로는 질소, 산소, 아르곤 등의 가스를 생산하는 공기분리플랜트, 헬륨액화플랜트, 수소액화플랜트, 천연가스액화플랜트 등이 있다. 질소, 산소, 수소 등의 가스는 산업의 전반적인 분야에서 널리 사용되고 있으며, 국내의 경우 철강, 반도체, 디스플레이제조산업 등 가스 다소비 분야의 비약적인 발전에 따라 급격하게 수요가 증가하고 있는 상황이다. 대용량의 가스액화플랜트는 원료로부터 불순물을 제거하고, 팽창 또는 열교환 과정을 통해 가스를 액체로 변환하는 극저온기술로 주로 구성되며, 이와 같은 과정은 압축기, 열교환기, 증류탑, 팽창터빈, 콜드박스 등의 구성요소에 의해 구현된다. 따라서 가스액화플랜트에서 효율적인 극저온의 생성 및 유지는 플랜트의 경제성 제고를 위해 핵심적인 요소이다.

• LP가스
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• v.23 no.2
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• pp.40-41
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• 2011

국가경쟁력강화위원회에서 확정(2011. 1. 19. 제24차 회의)된 하위법령 특별정비 추진에 따라 행정제재처분기준을 경감할 수 있는 사유를 명확히 마련함으로써 행정제재처분을 합리화하는 한편, 액화석유가스 총전사업 등의 허가요건에 관한 세부적인 사항을 조례로 정하도록 하는 내용으로 "액화석유가스의 안전관리 및 사업법"이 개정(법률 제10350호, 2010. 6. 8. 공포, 9. 9. 시행)됨에 따라 종전에 고시로 정하고 있던 액화석유가스 충전사업 및 액화석유가스 판매사업의 시설기준 중 안전거리, 도로의 폭, 용기보관실 사무실 주차장의 면적에 대하여 일반 기준의 2배 이내의 범위에서 강화된 기준을 조례로 정하려는 것임.

• Journal of the KSME
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• v.53 no.4
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• pp.38-43
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• 2013

이 글에서는 수소 연료전지차, 우주개발용 로켓추진체의 연료공급기술로 활용이 예상되는 수소액화 기술 및 영하 253도의 극저온 액체수소의 저장기술에 대해 살펴보고 액화사이클 및 극저온 액화수소 저장용기로의 열침입을 차단하기 위한 다양한 단열기술에 대해 기술한다.

• Journal of the Korean Institute of Gas
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• v.15 no.3
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• pp.1-5
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• 2011

For the hydrogen liquefaction, the large amount of energy is consumed, because precooling, liquefaction and ortho/para conversion heats should be eliminated. In this paper the basic design and thermal analysis are carried out to reduce the energy consumption by using LNG cold energy for precooling process in hydrogen liquefaction processes. The LNG cold energy utilization for hydrogen precooling enables not only to get energy saving for liquefaction, but to recover the wasted cold energy to sea water at the LNG terminal. The results show that the energy saving rate for liquefaction using LNG cold energy is almost 75% of current industrial hydrogen liquefaction plant. The demand flow-rate of LNG is only 15T/D for 1T/D hydrogen liquefaction.

• Journal of Energy Engineering
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• v.5 no.2
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• pp.176-182
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• 1996

The effects of some additives (black liquor, NaOH, water and wood) on the conversion of coal and product were investigated in the lab-scale, high pressure reacting system around 375$^{\circ}C$. The addition of black liquor enhances the coal conversion yield about 38.6%, which is mainly due to NaOH in black liquor. Also, sulfur of the black liquor in coal liquefaction process evolved hydrogen sulfide, which causes the odor problem. Addition of water in coal liquefaction increased CO$_2$content in the gas phase, and low boiling range components in liquid products. Coprocessing of wood and coal at 400$^{\circ}C$ increased yield of liquid product about 8%, but higher temperature above 400$^{\circ}C$ reduced liquid product due to increase of gas products.

• Journal of the Korean Professional Engineers Association
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• v.12 no.3
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• pp.12-17
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• 1979

The form of the Enterprise of the L.N.G project Consists of such three enterprises that the Construction and operation of the liquefcation plant of the Natural gas, and L.N.G. tankers Operating enterprise and the receiving and storaging plant of the L. L.N.G., above mentined three enterprises Concerned with capital and technique mutually, and so it arises such results that the foundmental requirements of the fuel the long-term and safty-price suply of the L.N.G. are met.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.35 no.1
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• pp.32-38
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• 2012

몽골은 석탄 매장량이 매우 풍부하고 석유연료를 전적으로 수입에 의존하기 때문에, 석탄액화플랜트 건설에 필요한 충분한 여건을 갖추고 있다. 본 연구에서는 몽골에 하루 10,000배럴의 석유연료를 생산할 수 있는 석탄액화플랜트를 건설할 경우에 대한 경제성분석을 수행한다. 먼저 기존에 있는 산업계의 석탄액화플랜트 프로젝트 데이터와 학계의 연구결과를 토대로 몽골 석탄액화플랜트 건설에 필요한 비용과 기대수명, 그리고 예상 수명기간 동안 운영했을 때 발생하는 운영비용과 소득을 추정한다. 추정된 비용과 소득을 이용하여 네 가지 시나리오(기본, 악화 1, 악화 2, 매우 악화) 하에서의 경제성 분석을 실시한다. 분석결과 투자수익률이 기본 시나리오에서는 45%에 가까우며, 가장 나쁜 시나리오에서도 5%보다 컸다. 이는 몽골 석탄액화플랜트 건설이 경제적으로 충분히 타당성이 있음을 나타낸다.

• Journal of Korea Foresty Energy
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• v.18 no.1
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• pp.17-24
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• 1999

This study was conducted to examine the change in the structure of the lignin during liquefaction of kraft pulp lignin in Pinus korainsis and lignin sulfonic acid. The lignin liquefied compounds were extracted with chloroform from aqueous, liquefied lignins. Through the examination by IR, H($^{13}$C) - NMR and GC-MS spectrometers, phenolic compounds such as diguaiacol, acetic acid phenyl ester, phenol, 1-phenyl ethanone were identified with many of unknown phenolic compounds.