• Title/Summary/Keyword: 액체 건조제

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안전관리 - 용접공사의 화재.폭발 등 안전사고 예방대책(2)

  • 대한설비건설협회
    • 월간 기계설비
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    • s.267
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    • pp.65-71
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    • 2012
  • 지난 8월 13일 서울 종로구 소격동 국립현대미술관 서울관 공사현장에서 화재 발생으로 4명이 숨지고 18명이 중경상을 입는 등 많은 인명피해를 냈다. 이처럼 인명피해가 컸던 것은 우레탄 공사를 하던 밀폐공간에서 불이 나면서 발생한 유독가스 때문에 사람들이 제대로 대피하지 못했기 때문이다. 사고발생 원인으로 '용접공사' 여부를 놓고 공방을 벌였으나 경찰은 '전기합선'이라는 잠정 결론을 내렸다. 지난 2008년 1월에 발생한 경기도 이천 냉동창고 화재는 40명의 목숨을 앗아갔다. 화재 원인은 냉동배관을 설치하면서 전기 용접을 하기 위해 불을 붙였다가 공기 중에 차 있던 유증기(기름증기)와 만나면서 폭발이 일어난 것이었다. 인화성 액체(유기용제)를 취급하는 건설현장에서는 다량의 유증기가 발생할 수 있을 뿐만 아니라 건조한 조건일 경우 정전기에 의한 화재 폭발 누출사고의 발생 위험이 높다. 기계설비공사에서 화재, 폭발 위험성이 가장 큰 공사는 용접공사이기에 용접공사를 할 때 화재, 감전의 위험성을 배제한 후 공사에 들어간다. 용접으로 인한 사망사고의 유형으로는 용접 중 추락사고와 더불어 용접 불꽃이 가연성 물질에 옮겨 붙어 화재 발생으로 인한 질식사, 용접작업 중 절연체가 파손된 용접기 홀더 충전부의 접촉으로 인한 감전사 등이 있다. 본지는 용접으로 인한 화재 감전 등의 사고발생을 미연에 방지하기 위해 안전작업 수칙 및 안전수칙 체크리스트, 재해사례를 지난호부터 시리즈로 연재하고 있다.

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Response Surface Approach to Design Optimization of Regenerator Using Hot Air Heated by Solar Collector (태양열 온풍 이용을 위한 재생기의 설계 최적화 모델에 관한 연구)

  • Woo, Jong-Soo;Choi, Kwang-Hwan;Yoon, Jeong-In
    • Journal of the Korean Solar Energy Society
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    • v.23 no.3
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    • pp.7-14
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    • 2003
  • Absorption potential of desiccant solution significantly decreases after absorbing moisture from humid air, and a regeneration process requires a great amount of energy to recover absorption potential of desiccant solution. In an effort to develop an energy efficient regenerator, this study examines a regeneration process using hot air heated by solar radiation to recover absorption potential by evaporating moisture in liquid desiccant. More specifically, this study is aimed at finding the optimum operating condition of the regenerator by utilizing a well-established statistical tool, so-called response surface methodology(RSM), which may provide a functional relationship between independent and dependent variables. It is demonstrated that an optimization model to find the optimum operating condition can be obtained using the functional relationship between regeneration rate and affecting factors which is approximated on the basis experimental results.

Optimization of Fermentation Conditions for the Production of Citric Acid by Aspergillus niger NRRL 567 Grown on Agricultural by Products (목질계 농부산물을 이용한 고체발효에서 발효조건 최적화를 통한 구연산 생산 증대)

  • Kim, Jin-Woo
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.402-406
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    • 2014
  • The present study was carried out to evaluate the potential of lignocellulosic byproducts for the production of citric acid through solid-state fermentation by Aspergillus niger NRRL 567. A sequential optimization based on one-factor-at-a-time method was applied to optimize fermentation conditions and media constituents. The results obtained from the optimization indicated that $30^{\circ}C$, 70% moisture content, 0.5~1.0 mm particle size, pH 5.5 and 4% methanol were found to be the optimum condition at 72 hr fermentation. The application the optimization resulted in an improvement of maximum citric acid production from 74.5 to 206.0 g/kg dry material (DM) from wheat straw. The optimal condition was used to produce citric acid from A. niger grown on different lignocellulosic byproducts, including wheat straw, corn stover and peat moss. A. niger produced the highest citric acid levels of 231.8, 213.8 and 240.2 g/kg DM at 120 hr fermentation, respectively.

Research on the Performance of Total Heat Exchanger in a Solar Air-Conditioning System (태양열 이용 냉난방 공조시스템 중 전열교환기 성능에 관한 연구)

  • Kim, K.H.;Choi, K.H.;Kum, J.S.;Kim, B.C.;Kim, J.R.
    • Solar Energy
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    • v.19 no.4
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    • pp.45-53
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    • 1999
  • This report Introduces a total heat exchanger in a solar air-conditioning system using Lithium Chloride(LiCl) solution. The hot and humid outside air is cooled and dehumidified by LiCl solution that is sprayed on the packed layer of the total heat exchanger. LiCl solution once diluted is concentrated again in a regenerator using solar energy. Three types as the packed materials were used in this experiment and the dehumidification performance was evaluated by the value of $k_xa(kg/h{\cdot}m^3{\cdot}{\Delta}x)$, overall mass transfer coefficient based on a humidity ratio potential difference, the influence of inlet LiCl solution flow rate, air flow rate, packed layer height on $k_xa$ was investigated. It was found that air flow rate, LiCl solution flow rate, packed layer height for all types had a great influnce on the value of $k_xa$.

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Effect of Nanotube Length on Rheological Characteristics of Polystyrene/Multi-walled Carbon Nanotube Nanocomposites Prepared by Latex Technology (라텍스 기법으로 제조한 폴리스티렌/다중벽 탄소나노튜브 나노복합재료의 나노튜브 길이가 유변학적 특성에 미치는 영향)

  • Woo, Dong-Kyun;Noh, Won-Jin;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.534-539
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    • 2010
  • Polystyrene (PS)/multi-walled carbon nanotube (MWCNT) nanocomposites were prepared via latex technology and the effect of nanotube length on rheological properties were investigated. Monodisperse PS particle was synthesized by the emulsifier-free emulsion polymerization and two types of MWCNTs were used after surface modification to improve dispersion state and to remove impurities. Final nanocomposites were prepared by the freeze-drying process after dispersing the PS particles and the surface-modified MWCNTs in a ultrasonic bath. The effects of MWCNT content and nanotube length on rheological properties were evaluated by imposing the small-amplitude oscillatory shear flow. The PS/MWCNT nanocomposites showed that rheological properties were enhanced as the amount and length of MWCNT increased. It is speculated that the rheological characteristics of nanocomposites change from liquid-like to solid-like as the MWCNT amount increases, and the critical concentration to achieve network structure decreases as the nanotube length increases.

Studies on the Culture Media and the Optimal Storage Conditions of Bioluminescent Bacteria Photobacterium phosphoreum (생체발광균주 Photobacterium phosphoreum의 배양배지 및 최적 저장조건에 관한 연구)

  • 조동욱;전억한;김병용;김은기;함영태
    • Korean Journal of Microbiology
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    • v.36 no.1
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    • pp.74-78
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    • 2000
  • Vibrio, Photobacterium, Alteromonas and Xenorhabdus species are capable of emitting light, called bioluminescence. They exist in marine, freshwater and terrestrial environments. Bacterial bioluminescent reaction is that reduced riboflavin phosphates and a long-chain aldehyde are oxidized in the presence of molecular oxygen and enzyme luciferase. This experiment aims to develop the proper culture media and to optimize the storage condition for the recovery of bioluminescent activity in Photobacterium phosphoreum. The Luria broth (LB) medium was modified for cultivation of Photobacterium phophoreum, called as modified LB(mLB) medium. The mLB medium is LB fortified with 3% glycerol and 1.5% NaCl. In mLB medium. bacterial growth and bioluminescent activity are 25% higher than those in a Nutrient broth medium. When the cell stocks were stored at $-20^{\circ}C$, $-70^{\circ}C$ and LN2 for 3 months, cell growth and bioluminescent activity of culture after stored at $-20^{\circ}C$ were better than those of other treatments. The highest bioluminescent activity obtained at the late exponential phase in all treatments. When the cell stock was freeze-dried with 5% adonitol as a cryoprotectant, the recovery of cell was better than those of control and freeze-dried cell stock without addition of cryoprotectant.

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Studies on the Lipid Components of Potato Tubers - I. Lipid Composition in Free and Bound Lipids - (감자의 지방질(脂肪質) 성분(成分)에 관한 연구(硏究) - 제(第) 1보(報) : 유리(遊離) 및 결합(結合) 지질(脂質)중의 지방질(脂肪質) 조성(組成)에 관하여 -)

  • Lee, Sang-Young;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.11 no.4
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    • pp.291-297
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    • 1979
  • The experimentally cultivated potatoes of 4 varieties, Irish Cobbler, Warba, Shimabara, and Saco were dried in a frozen state, powdered subsequently and subjected to the extraction of free and bound lipids. Constituents of the prepared lipids were fractionated, quantified, and compared by the methods of column and gas-liquid chromatographies. The results were summarized as follows : 1. The total crude lipid content in potato on a dry weight basis was 0.57 % of which 0.2 % was free lipid and 0.37 % was bound lipid. 2. The neutral lipid content in the free lipid was 14.9 %, approximately 3 times as much as the 4.5 % contained in the bound lipid, whereas the glycolipid content in the free lipid was 15.1 %, slightly less than 22.2 % contained in the bound lipid. However, the phospholipid content was 33.9 % in the bound lipid, approximately 4.5 times as much as the 7.2 % contained in the free lipid. This fact revealed that the bound lipid consisted mainly of polar lipid, while the free lipid consisted of neutral lipids, glycolipids and phospholipids in about the same proportion. 3. The main fatty acids constituting more than 90 % in the free and bound lipids were linoleic, palmitic and linolenic acids. The content of the saturated fatty acid was slightly less in the free lipid than in the bound lipid, whereas the unsaturated fatty acids were more abundant in the free lipid.

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A study on the fabrication of foamed glass by using refused coal ore and its physical properties (석탄 폐석을 이용한 발포유리의 제조 및 물리적 특성 연구)

  • Lim, Tae-Young;Ku, Hyun-Woo;Hwang, Jong-Hee;Kim, Jin-Ho;Kim, Jung-Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.6
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    • pp.266-273
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    • 2011
  • Foamed glass was fabricated by using glass powder and foaming agents. For the glass powder, we used sodalime glass which's manufactured by using refused coal ore obtained as by-product from Dogye coal mine in Samcheok. And for the foaming agents, we used Calcium carbonate, Calcium phosphate and powder of shale type refused coal ore itself which has high content of carbon materials. We additionally used liquid binder for forming, and mixed together. And we formed rectangular shape and treated $800^{\circ}C$ for 20 min in an electrical furnace. The various kinds of foam glass samples were fabricated according to the kinds of foaming agents. The physical properties of samples, as specific gravity and compressive strength, were measured. Pore structure of each samples were investigated too. Foam glass with specific gravity of 0.4~0.7 and compressive strength of 30~72 kg/$cm^2$. Especially we get satisfying foam glass sample with low specific gravity of 0.47 and high compressive strength of 72 kg/$cm^2$ by the use of liquid calcium phosphate as foaming agent. It also had small and even shape of pore structure. Therefore, it is concluded that refused coal ore can be used for raw materials to manufacture secondary glass products such as a foamed glass panel for construction and industrial materials.

Isolation and Purification of Berberine in Cortex Phellodendri by Centrifugal Partition Chromatography (Centrifugal Partition Chromatography에 의한 황백으로부터 Berberine의 분리 및 정제)

  • Kim, Jung-Bae;Bang, Byung-Ho
    • The Korean Journal of Food And Nutrition
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    • v.27 no.3
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    • pp.532-537
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    • 2014
  • Cortex Phellodendri (CP) is derived from the dried bark of Phellodendron amurense. It has been widely used as a drug in traditional Korea medicine for treating diarrhea, jaundice, swelling pains in the knees and feet, urinary tract infections, and infections of the body surface. Many analytical methods have been used to study oriental herbal medicines, such as thin-layer chromatography, column liquid chromatography, and high performance liquid chromatography (HPLC). In this study, preparative centrifugal partition chromatography (CPC) was successfully carried out in order to separate pure compounds from a CP methanol extract. The optimum two-phase CPC solvent system was composed of n-butanol: acetic acid: water (4:1:5 v/v/v). The flow rate of the mobile phase was 3 mL/min in ascending mode with rotation at 1,000 rpm. The CPC-separated fraction and purification procedures were carried out by preparatory HPLC. The $^1H$ NMR spectrum revealed that the resonances at ${\delta}$ 4.10 and 4.20 ppm corresponded to three protons ($-OCH_3$), whereas those at ${\delta}$ 6.10 ppm corresponded to two protons ($-OCH_2O-$). Further, two aromatic protons (H-11 and H-12) conveys a doublet-doublet pattern. The H-11 doublet and H-12 doublet appear at ${\delta}$ 7.98 and 8.11, respectively. The $^{13}C$ NMR. spectrum showed a tetrasubstituted with a methylenedioxy group at C2 and C3, and two methoxy groups at C9 and C10. The chemical structure of the berberine was identified by $^1H$, $^{13}C$-nuclear magnetic resonance and electrospray ionization-mass spectroscopy spectral data analysis.

Studies on the Biological Activity of Rosemarinus officinalis L. (Rosemary (Rosemarinus officinalis L.) 추출물의 생리활성 탐색)

  • Cho, Young-Je;Kim, Jeung-Hoan;Yoon, So-Jung;Chun, Sung-Sook;Choi, Ung-Kyu
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.970-975
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    • 2005
  • Based on their biological activity, phenols from rosemary extract were evaluated for inhibition of Helicobacter pylori. Contents of total phenolic compounds and inhibition zone of water and ethanol extracts from rosemary were 24.3mg/g and 25.7mg/g, and 11mm, 14mm, and, at $200{\mu}g/mL$ phenol content, 20.9% and 78.2% inhibitory activities were observed, respectively. Electron donating abilities and 2.2-Azino-bis-3-ethylbenzothiazoline-6-sulfonic acid cation radicals of water and ethanol extracts were 89.1% and 62.0% and 98.4% and 96.5%, respectively. Thiobarbituric acid reactive substances values of all extracts were lower than that of control. Ethanol extract showed 98.8% angiotensin-converting enzyme inhibitory activity. Xanthin oxidase inhibitory activities of water and ethanol extracts were very high, at 84.8%, 100%, respectively. These results indicated phenolic compounds from rosemary can be utilize as a potential antioxidant, antimicrobial, anti-hypertension and anti-gout sources.