• Title/Summary/Keyword: 액체 가진

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Influence of the Cation Parts of Imidazolium Hexafluorophosphate on Synthesis of Pd/C Particles as a HFP Hydrogenation Catalyst (Imidazolium Hexafluorophosphate의 양이온이 HFP 수소화 반응용 Pd/C 촉매 제조에 미치는 영향)

  • Kim, Chang-Soo;Yoo, Kye Sang
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.249-253
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    • 2014
  • Palladium on carbon catalysts for hexafluoropropylene hydrogenation were prepared using imidazolium hexafluorophosphate with various cation parts. The morphology of palladium was relatively affected by the cation parts of the ionic liquid. With increasing alkyl chains of the ionic liquid cation, the shape of palladium particle changed from spherical to cylindrical due to the effect of steric stabilization. After calcination at $500^{\circ}C$, all catalysts possessed the comparable crystal structure. Under the identical reaction conditions, the catalyst prepared using the ionic liquid with hexyl chain in cation parts showed the most effective reactivity.

Study on Properties of High Energetic and High Dense Cyclic Hydrocarbons by the Structure (고에너지 고밀도 고리탄화수소 화합물의 구조에 따른 물성 연구)

  • Cho, Joon-Hyun;Kwon, Tae-Soo;Jeong, Deok-Jin;Oh, Chang-Ho;Park, Dae-In;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.463-466
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    • 2008
  • The weapon systems with a liquid propulsion engine have been used for various purposes and demands of the liquid fuel with variety of properties for its operational purposes and environment. The cyclic hydrocarbons including norbornane or dicyclopentane structures have many applications to the guided weapon systems due to the high density and high energy characteristics, also efforts have been given in many fields. In this study, the cyclic hydrocarbons that we designed and fabricated were investigated to obtain tendency on the structures.

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Evaluation for Sloshing Behaviors of Liquid Storage Tank (액체연료탱크의 슬로싱 거동 평가기법)

  • 윤성호;박기진;심국상
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.314-317
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    • 2002
  • The sloshing phenomenon sometimes happens to be occurred in the liquid storage tank due to the unexpected and/or inevitable vibrating conditions and may result in severe effects on the structural stability. This study deals with the development of experimental techniques for the evaluation of sloshing behavior in the liquid storage tank and for the identification of natural frequencies and mode shapes by varying with various vibrating conditions. In addition, suitable method is suggested to minimize the sloshing effect on the liquid storage tank and its validity is experimentally investigate d.

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양성자 빔 조사중의 0-18 target의 상태변화에 대한 고찰

  • 허민구;오환섭
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.05a
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    • pp.112-112
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    • 2004
  • 양전자 단층촬영(PETㆍ Positron Emission Tomography)에 가장 널리 사용되는 방사성의약품인 FDG는 방사성동위원소인$^{18}$ F가 사용되며, 이는 안정물질인 H$_2$$^{18}$ O을 액체표적에 주입한 후, 고 에너지의 양성자빔을 조사하여 생산한다. 표적은 내화학성 및 높은 인장강도론 가진 재질인 titanium으로 제조하며, 0.075mm의 얇은 박판이 양성자빔 입사부에 사용된다. H$_2$$^{18}$ O가 주입된 표적에 양성자빔이 입사되는 순간 표적 내부는 높은 에너지로 인하여 표적물은 고온상태로 기화가 일어나고 이것이 압력을 증가시켜 target window는 바깥쪽으로 팽창한다.(중략)

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표면처리를 통한 울의 젖음성 변화를 적용한 실 기반 Microfluidics

  • Jeon, So-Hyeon;Hwang, Gi-Hwan;Seo, Hyeon-Jin;Bu, Jin-Hyo;Yun, Sang-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.143.1-143.1
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    • 2013
  • 최근 실 기반 microfluidics device는 많은 응용 가능성을 보이고 있다. 예를 들면 의료진단, 환경측정 그리고 식품 안정성 분석 등의 분야에서 사용이 가능하다. 이러한 가능성을 가진 반면 해결해야 하는 문제점들이 존재한다. 실 한가닥에 Capillary force에 의해 빨려 올라오는 액체의 속도를 조절하기 힘들다는 것이다. 속도 조절은 실 기반 microfluidics에서는 매우 중요한 역할을 하는 것이므로 이는 굉장히 치명적일 수 있다. 본 그룹은 울의 젖음성을 변화시킴으로써 그 속도를 조절하였다. 울은 본래 소수성의 성질을 가졌으며 본 그룹의 표면처리를 통하면 친수성을로 바뀌는 것을 확인하였다. 표면처리의 종류와 정도에 따라 친수성을 띄는 정도가 달라지는 것을 확인하였다. 결과적으로는 표면처리에 따라 서로 액체를 빨아들이는 속도가 다른 울들을 microfluidics device에 응용할 수 있다는 결론을 지을 수 있다.

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Influence of Ionic Liquid for Separation of D-tryptophan and N-CBZ-D-phenylalanine (D-tryptophan과 N-CBZ-D-phenylalanine의 분리에서 이온성 액체의 영향)

  • Jin, Yinzhe;Zheng, Jinzhu;Polyakova, Yulia;Koo, Yoon Mo;Row, Kyung Ho
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.453-459
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    • 2006
  • D-tryptophan and N-CBZ-D-phenylalanine were separated using ionic liquid as additives for the mobile phase in high performance liquid chromatography (HPLC). The ionic liquid of 1-butyl-3- methylimidazolium tetrafluoroborate (${[BMIm]}^+{[BF_4]}^-$) was used. Mobile phases were 65%, 70%, and 80% methanol in water with addition of different concentrations (0.5, 1.0, 1.5, 2.0, 4.0, 6.0, 8.0, 10.0, 12.0, and 15.0 mmol/L) of the ionic liquid. The experiments were performed on stainless steel column, $3.9{\times}300mm$ i.d., packed with $15{\mu}m$ octadecyl-bonded silica gel at laboratory.The retention factor of D-tryptophan was not negligibly changed while that of N-CBZ-D-phenylalanine was decreased. The resolution between the two components were affected by the contents of methanol and ionic liquid in the mobile phase. With the small content of methanol and the high concentration of ionic liquid, the resolution was improved.

Separation Characteristics in Stirred Deadend Microfiltration System (교반형 Deadend 정밀여과 시스템의 투과특성)

  • 장규만;장건용
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.04a
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    • pp.101-104
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    • 1999
  • PEFE, Asypore, PC, Nylon 등의 정밀여과막에 0.1내지 4$\mu\textrm{m}$의 입자분포를 가진 kaolin 용액을 dead-end 형 여과장치(Amicon Cell, 8050)를 이용하여 투과실험을 하였다. 또한 공칭세공이 0.2$\mu\textrm{m}$ 인 PTFE(Sartorius 사) 막에 kaolin, bentonite, yeast, starch 등 입자의 크기 및 특성이 다른 0.1%의 용액들을 1 bar 의 운전압력과 200rpm의 회전속도로 투과실험을 하였다. 투과 실험한 자료를 근거로 저항모델을 적용하여 분석하였으며 순수 하락도와 액체전이법으로 세공분포를 확인하였다.

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Enzymatic Biodiesel Synthesis from Canola Oil in Liquid Carbon Dioxide (액체 이산화탄소 조건에서의 캐놀라 오일 유래의 효소적 바이오디젤 생산)

  • Lee, Myung-Gu;Park, Chul-Hwan;Cho, Jae-Hoon;Lee, Jun-Hak;Lee, Do-Hoon;Kim, Sang-Yong
    • KSBB Journal
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    • v.25 no.4
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    • pp.337-343
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    • 2010
  • It has been well known that organic solvents like t-butanol and n-hexane can protect lipases from the inhibition by short-chain alcohols in the enzymatic transesterification. However, use of the organic solvents should be minimized considering their negative effects on environment and human health. Therefore, use of the greener solvents has been pursued in various are as including the enzymatic biotranformation. In this study, the liquid carbon dioxide ($LCO_2$) was employed as an alternative media for the enzymatic transesterification of canola oil. The conversion in the $LCO_2$ was comparable with those in organic solvents and the supercritical carbon dioxide, and under optimum conditions, the value reached 99.7%. It is expected that this method can provide a new type of biodiesel production process with higher energy efficiency and lower environmental impact.

Study on Modal Test Method for Vibration Characteristics of the Cylindrical Structure Filled with Liquid (액체가 채워진 원통형 구조물의 진동 특성 규명을 위한 모달 시험 방법 연구)

  • Kim, Gen-Sang;Kim, Mun-Guk;Kim, In-Gul;Park, Jae-Sang;Park, Soon-Hong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.8
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    • pp.621-630
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    • 2018
  • In the case of launch vehicles using liquid fuel, natural frequency changes due to fuel consumption after launch, and a modal test is essential to investigate its effect. However, when relying on modal test to characterize the free vibration characteristics, the testing time is excessively increased and accuracy is reduced. Therefore, this paper suggests a modal test method with finite element analysis to overcome these drawbacks. A cylindrical structure filled with liquid are considered as a study model, and modal tests and finite element analyses are performed. The modal tests are conducted by an impulsive method using an impact hammer and accelerometers. Through the comparison of the modal test and the finite element analysis results, the validity of the proposed modal test method is verified. In addition, the free vibration characteristics and the tendency for the cylindrical structure according to the liquid filled ratio were investigated.

Experimental Verification of a Liquid Damper with Changeable Natural Frequency for Building Response Control (고유진동수 조절이 가능한 액체댐퍼의 건물응답 제어실험)

  • Kim, Dong-Ik;Min, Kyung-Won;Park, Ji-Hun;Kim, Jae-Keon;Hwang, Kyu-Seok;Gil, Yong-Sik
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.25 no.4
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    • pp.323-330
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    • 2012
  • This study deals with the experiments of liquid dampers with multi cells whose vertical tubes are divided into several square columns for easily changing natural frequencies. Shaking table test is performed to verify control effectiveness of the dampers which are installed on a building structure. To design liquid dampers, a 64-story building structure is reduced to a SDOF structure with 1/20 of similitude laws based on acceleration. The structure model is made up to adjust its mass and stiffness easily, with separate mass and drive parts. Mass parts indicate real structure's weights and drive parts indicate real structure's stiffness with springs and LM guides. Manufactured liquid damper has 18 cells and its natural frequency ranges are 0.65Hz to 0.81Hz. Shaking table test is carried out with one way excitation to compare with only accelerations of a large-scale structure and a structure installed with liquid dampers. Control performance of the liquid damper is expressed by the transfer function from shaking table accelerations to the large-scale structure ones. Testing results show that the liquid damper reduced a large-scale structure's response by tuned natural frequencies.