• Journal of the Korean Chemical Society
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• v.42 no.4
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• pp.443-448
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• 1998

The thermodynamic parameters for the interaction of metal ions with dibenzo-16-crown-5 and its derivatives have been determined by solution calorimetry in methanol at 25$^{\circ}C$. Thermodynamic properties of log K, ${\Delta}H$, and $T{\Delta}S$ have been determined for the complexation of metal cations by dibenzo-16-crown-5 and its derivatives. Dibenzo-16-crown-5 and its derivatives have been studied as metal cations carrier in bulk liquid membrane (BLM) and supported liquid membrane (SLM) system. $Ag^+$ has been much more transported using dibenzo-16-crown-5 derivatives as carriers and several other metal cations have been small transported using carrier in BLM and SLM system. Ligand structure, the length of side arm, donor atom, stability constant, and carrier concentration are also important parameters in the transport of cations.

• Resources Recycling
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• v.21 no.6
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• pp.45-50
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• 2012

The room-temperature electrodeposition of metallic lithium was investigated from ionic liquid, 1-methyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13TFSI) with lithium bis (trifluoromethanesulfonyl)imide (LiTFSI) as a lithium source. Cyclic voltammograms on gold working electrode showed the possibility of the electrodeposition of metallic lithium, and the reduction current on a gold electrode was higher than the value on platinum and copper. The metallic lithium could be electrodeposited on the gold electrode under potentiostatic condition at -2.4 V (vs. Pt-QRE) and was confirmed by analytical techniques including XRD and SEM-EDS. The dendrite-typed electrodeposits were composed of a metallic lithium and a alloy with gold substrate. And any impurity could be detected except for trace oxygen introduced during handling for the analyses.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.576-583
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• 2018

Silicon carbide is considered to be a potentially useful material for high-temperature electronic devices, as its band gap is larger than that of silicon and the p-type and/or n-type conduction can be controlled by impurity doping. Particularly, porous n-type SiC ceramics fabricated from ${\beta}-SiC$ powder have been found to show a high thermoelectric conversion efficiency in the temperature region of $800^{\circ}C$ to $1000^{\circ}C$. For the application of SiC thermoelectric semiconductors, their figure of merit is an essential parameter, and high temperature (above $800^{\circ}C$) electrodes constitute an essential element. Generally, ceramics are not wetted by most conventional braze metals,. but alloying them with reactive additives can change their interfacial chemistries and promote both wetting and bonding. If a liquid is to wet a solid surface, the energy of the liquid-solid interface must be less than that of the solid, in which case there will be a driving force for the liquid to spread over the solid surface and to enter the capillary gaps. Consequently, using Ag with a relatively low melting point, the junction of the porous SiC semiconductor-Ag and/or its alloy-SiC and/or alumina substrate was studied. Ag-20Ti-20Cu filler metal showed promise as the high temperature electrode for SiC semiconductors.

• Applied Chemistry for Engineering
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• v.8 no.3
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• pp.482-488
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• 1997

Copper recovery from waste water of electronic industry has been conducted effectively in a fluidized bed reactor. Initial concentration of copper in the waste water, liquid flow rate in the reactor, reaction temperature and time and current density between the cathode and anode in the reactor have been selected as operating variables. The effects of operating variables on the recovery of copper have been studied. It has found that the copper resolved in the waste water can be recovered continuously by means of a fluidized bed reactor The recovery of copper decreased with an increase in the initial concentration of copper in the waste water, while it increased with increasing reaction time and current density, however, it exhibited its maximum value with the variations of liquid flow rate and reaction temperature. The optimum reaction condition to maintain the copper recovery around 85% is as follows ; $X_o=3wt%$, $U_L=0.5cm/s$, $T=25^{\circ}C$, $I=7A/dm^2$ and t=2hrs within this experimental condition.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.209.1-209.1
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• 2016

우리에게 잘 알려져 있지 않은 강장동물 히드라는 뛰어난 세포 분열 능력을 가지고 있다. 출아(무성생식)를 하면서도 환경에 따라 유성생식을 하기도 하는 몇 안 되는 생물 중 하나인 히드라는 재생능력이 강하여 몸의 200분의 1만 잘려도 재생을 할 수 있는 능력을 가지고 있다. 이러한 히드라의 재생능력을 높은 에너지인 플라즈마에 노출시켜 보았다. 플라즈마는 열, 빛, 화학 활성종, 이온, 전자를 발생하며 이 중 열 및 화학적 자극을 중심으로 관찰하였다. 생물이 수용할 수 있는 열에너지를 넘게 받는다면 그 성질이 변하는 점을 이용해 액체 방전소스를 이용하여 플라즈마의 열적인 효과를 주었고, DBD소스로는 약 염기를 띠는 라디칼(활성종)용액을 배양액으로 만들어 히드라에게 배양시켜 히드라의 생장능력 변화를 알아보았다. 생장능력의 변화는 히드라의 개체 수를 통해 관찰하였다. 플라즈마를 발생시키는 소스는 다양하며 그 중 이번 실험에서는 액체 방전 소스와 DBD를 이용하였다. 액체방전 소스는 누전을 막기 위해 세라믹 관에 금속선을 넣어 고전압을 인가하여 방전하였고, DBD(Dielectric Barrier Discharge의 약어)는 유전체 장벽을 이용하여 기체를 방전시키는 방식이다. DBD는 주로 살균 용도로 연구 중이며, DBD는 주변 기체들을 반응시켜 라디칼을 상당히 만들어 낼 수가 있다. 한편, 생물학에서 주목 받고 있는 히드라는 200분의 1만 잘려도 재생이 되는 재생능력을 갖고 있다. 히드라의 이러한 생장 및 재생속도는 생체모방 기술로도 주목을 받고 있다. 이번 실험은 최근 연구되고 있는 플라즈마의 효과를 히드라에 적용한 것으로 플라즈마의 간접적인 영향이 히드라에 어떠한 영향을 줄 것인지 알아보았다. 간접적인 영향으로는 크게 열적인 요인과 화학적인 요인으로 나누어 관찰하였다. 실험을 통해 히드라의 변화를 알아보고 그 결과가 실용가능한지를 알아보고자 한다.

• Journal of the Earthquake Engineering Society of Korea
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• v.3 no.1
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• pp.75-92
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• 1999

In this paper, the seismic analysis model for seismically isolated KALIMER reactor structures is developed and the modal analysis and the seismic time history analysis are carried out for seismic isolation and non-isolation cases. To check the seismic stress limit according to the ASME Code, the equivalent seismic stress analyses are preformed using the 3-D finite element model. From the seismic stress analysis, the seismic margins are calculated for structural members. The limit of seismic load is defined to show that the maximum input acceleration ensures the structural safety for seismic load. In comparison of seismic responses between seismic isolation and non-isolation cases, the seismic isolation design gives significantly reduced acceleration responses and relative displacements between structures. The seismic margin of KALIMER reactor structure is high enough to produce the limit seismic load 0.8g.

• Membrane Journal
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• v.33 no.5
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• pp.240-247
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• 2023

Even among gas separation methods, CO₂ capture and separation via membranes is an ever-growing field, with many different membrane compositions continually being developed. Ionic liquid (IL) based composite membranes show excellent performance values in separating CO₂. Similarly, various copolymer/IL composite membranes also display improved performance. The addition of fillers such as graphene oxide to these copolymer/IL composite membranes shows a further enhanced version of these fillers, most likely due to the strong interactions that occur between ILs and organic fillers, which consequently improves factors such as the affinity, selectivity, and adsorption of CO₂. Copolymer/IL composite membranes utilizing a metal-organic framework (MOF) showed improved CO₂ permeability. This review discusses the study of various combinations of ionic liquid and copolymer composite membranes for carbon dioxide separation.

• Korean Journal of Materials Research
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• v.7 no.3
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• pp.218-223
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• 1997

At the aim of finding a Fehased amorphous alloy with a wide supercooled liquid region (${\Delta}T_{x}=T_{x}-T_{g}$) before crystallization, the changes in glass transition temperatudfI$T_{g}$ and crystallization temperature ($T_{x}$) by the dissolution of additional M elements were examined for the $Fe_{80}P_{10}C_{6}B_{4}$(x~6at%. M= transition metals) amorphous alloys. The ${\Delta}T_{x}$ value is 27K for the Fe,,,P,,,C,,R, alloy and increases to 40K for the addition of M=4at%Hf, 4at%Ta or 4at%Mo. The increase in ${\Delta}T_{x}$ is due to the increase of $T_{x}$ exceeding the degree in the increase in $T_{g}$. The $T_{g}$ and $T_{x}$ increase with decreasing electron concentration (e/a) from about 7 38 to 7.05. The decrease of e/a also implies the increase in the attractive bonding state between the M elements and other constitutent elements. It is therefore said that $T_{g}$ and $T_{x}$ increase kith increasing attractive bonding force.

• Korean Journal of Metals and Materials
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• v.48 no.10
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• pp.914-921
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• 2010

Studies were carried out to assess the microstructural and mechanical properties of ferriticmartensitic steel under a flowing sodium environment. HT9 (12Cr-MoVW) and Gr.92 (9Cr-MoVNbW) steel were exposed to liquid sodium at $650^{\circ}C$ containing dissolved oxygen of 20 ppm for 2333 hours and evaluations of the microstructure as well as the mechanical properties of the microhardness and nanoindentation were carried out. The result showed that both HT9 and Gr.92 exhibited macroscopic weight loss caused by general corrosion as well as localized types such as intergranular corrosion and pitting. Decarburization at the steel surface took place as the test proceeded. As the Cr content increased, dissolution and decarburization were suppressed. Assessment of the actual cladding geometry revealed that an aging process rather than decarburization governed the mechanical properties, which resulted in a decrease of the microhardness and yield stress.

• Journal of Environmental Science International
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• v.2 no.1
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• pp.61-72
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• 1993

Result of this study indicate that two criteria must be met in order to have effective macrocycle-mediated transport in these emulsionsystem. First, one must effective extraction of the post transition metals, $Cd^{2+}$. $Pb^{2+}$ and $Hg^{2+}$ , into toluene membrane. The effectiveness of this extraction is greatest if log K values for the metal-macrocycle interaction is large. Second, the ratio of the log K values for the metal ion-receiving phase to the metal ion-macrocycle interaction must be large enough to ensure quantitative stripping of the metal ion at the toluene phase interface. Control of the first step can be obtained by appropriate selection of macrocycle donor atom, substituents, and cavity radius. The second step can be controlled by selecting the proper complexing agent for inclusion in the receiving phase. The order of the transport, when using the several $A^-$ species such as $SCN^-$, $1^-$, $Br^-$ and $Cl^-$ is the order of the changing degree of solvation for $A^-$ and the transport of the metals is also affected by the control of concentration for receiving species because of solubility-differences. In this study, we can seperate each single metal ion from the mixture of $Cd^{2+}$, $Pb^{2+}$, and $Hg^{2+}$ ions by using the toluene membranes controlled by optimized conditions. Transport of the single metal is also very good, and alkaline and alkaline earth metals as interferences ions did not affect the seperation of the metals in this macrocycle-liquid membrances but transition metal ions were partially affected as interferences for the post transition metal ions.