• Title/Summary/Keyword: 액정상태

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The Study of Microemulsion with PEG-8 Capryliccapric Glycerides and Polyglyceryl-3 Diisostearate (PEG-8 Capryliccapric Glycerides와 Polyglyceryl-3 Diisostearate를 이용한 마이크로 에멀젼에 관한 연구)

  • Kim, Kyung-Min;Kim, Sung-Ho;Lee, Geun-Su;Kang, Ki-Choon;Pyo, Hyeong-Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.3
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    • pp.209-217
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    • 2012
  • One of the popular formulations is microemulsion in cosmetics. A kind of microemulsions is liquid crystal emulsion. Liquid crystal emulsion is used by wrapping functional ingredients. As the meaning of the name, Liquid crystals (LCs) are a state of matter that has properties between those of a conventional liquid and those of a solid crystal. There are various types of Liquid crystals (LCs) consisting of micelles or two layer structures of surfactants. Recently, microemulsion has been studied to improve its stability in thermodynamics of colloid science field. In this study, we prepared the microemulsion with PEG-8 Capryliccapric Glycerides and Polyglyceryl-3 Diisostearate. We studied the microemulsion with different oil types and different and cosurfactant content ratio. Also, the aim of this study is to develop a facial oil or a cleansing oil containing liquid crystal emulsion with functional ingredients.

Study on the Gelling Formation and Anti-gelling Properties of Liquid Detergent Based on Sodium Lauryl Ethoxy Sulfate (SLES) (소듐 라우릴 에톡시 설페이트(SLES) 베이스 액체세정제의 겔링성 및 겔링방지 특성에 대한 연구)

  • Chi, Gyeong-Yup
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.620-625
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    • 2018
  • Liquid detergent based on sodium lauryl ethoxy sulfate (SLES) as main ingredient sometimes met gelling film on the surface when it is opened in the air. It was assumed because of the change of phase diagram of micelle by concentration change of surfactant, major ingredient of detergent when the water of detergent is evaporated. SLES showed strong hexagonal liquid crystal (LC) in 30~60 wt%, and lamellar LC over 60 wt%. In this research surface gelling formation of liquid detergent which is based on SLES as main ingredient was because of water evaporation. As water of detergent was evaporated, concentration of surfactant became higher. It was checked that surface gelling was LC of mixed surfactant system. Conclusionally we applied alpha olefin sulfonate (AOS) having good solubility, Sodium secondary alkane sulfonate (SAS) preventing hexagonal LC and hydrotrope sodium xylene sulfonate (SXS) and PEG1500 in order to prevent gelling film in SLES based liquid detergent. Like this, improved formula 4 and 5 can prevent the formation of gelling film on the surface of liquid detergent when it is opened in the air.

Integrated Optical Wave Plates Fabricated by Incorporating Reactive Mesogen in Polymer Waveguide (반응성 메조겐을 이용한 폴리머 광도파로 편광 변환기)

  • Do, Hyun-Soo;Chu, Woo-Sung;Oh, Min-Cheol
    • Korean Journal of Optics and Photonics
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    • v.22 no.5
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    • pp.219-222
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    • 2011
  • Integrated optical waveguide polarization converters are among the essential components for constructing various functional optical integrated circuits. The RM materials have been widely used in liquid crystal displays for fabricating waveplates. In this work, the polarization converters are fabricated by using a solution of Reactive Mesogen(RM) dissolved in liquid crystal(LC). In the middle of the polymer waveguide, a groove is defined by an oxygen plasma etching in a direction perpendicular to the optical waveguide. The solution of RM-LC is inserted to fill up the groove, and then liquid crystal is aligned in a certain direction by applying an electric field. After the alignment, RM materal is crosslinked by UV light so as to form a permanent waveplate. The phase retardation of the waveplate is determined by the width of the groove, and by the birefringence and the degree of alignment of the LC. Polarization conversion efficiency of 90% is obtained for the wavelength of 1550 nm.

The Preparation and Application of Lamella Liquid Crystal to Skin Care Product (Skin care 화장료로서 단상형 액정조성물의 제조 및 응용)

  • 박병덕;이명진;이종기;이승헌
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.93-106
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    • 2000
  • One phase liquid crystal formula was developed by using of nonionic surfactants, polyols, water and oils and its physical property was investigated. At the system oft to 1 ratio of POE octyldodecyl ether series, which have Y type (branch type) hydrophobic group, and POE glyceryl monostearate series, Y type hydrophilic group, it was examined that the formula at 7:3, 6:4, and 5:5 ratio of nonionic surfactant : polyols, shows L$\alpha$ , a pattern which is a typical characteristic of liquid crystal structure under the cross microscope polarized film. As results of L$\alpha$ phase diagram study, the formula which had high hydrophilic nonionic surfactant and the 7:3 ratio of nonionic surfactant : polyol appeared to increase the amount of oil containment and to be capable of the lamella formation. Besides it was examined that lamellar liquid crystal formula could contain about 25-40% water between lamella layers and it was transformed into w/o emulsion following as water content increased. When the lamella gel was applied into a human skin, it was investigated that it had effectiveness in increasing transepidermal water content of the skin.

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An Experimental Study for the Heat Transfer Augmentation of an Impinging Jet (충돌 분류의 열전달 특성향상을 위한 실험적 연구)

  • 정기호;김예용;김귀순
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.2
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    • pp.66-74
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    • 1999
  • In this study, the heat transfer augmentation without additional blower power was obtained by using punched plate. Though this scheme has some disadvantages such as decrease of momentum caused by the punched plate, it has significantly increased heat transfer coefficients in the stagnation region. Compared with the case of no punched plate, heat transfer coefficients were increased by punched plate more than 2 times near the optimum condition determined in this study. Liquid crystal and hue-capturing technique were used in this study to obtain heat transfer coefficients.

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Thermotropic Behavior of Hydroxypropyl Chitosans Bearing Cholesteryl and Acryloyl Groups (콜레스테릴과 아크릴로일 그룹을 지닌 하이드록시프로필 키토산들의 열방성 거동)

  • 김장훈;정승용;마영대
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.41-50
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    • 2004
  • A new hydroxypropyl chitosan capable of forming a thermotropic liquid crystalline phase and two kinds of derivatives based on the hydroxypropyl chitosan (6-cholesteryloxycarbonylpentoxypropyl) chitosans (CHPCTs) and acrylic acid esters of CHPCT (CHPCTEs) were synthesized. The crosslinked films with liquid crystalline order were also prepared by photocrosslinking CHPCTE in mesophase. The liquid crystalline properties for all the samples and the swelling behavior of the crosslinked samples in acetone were investigated. In contrast with the hydroxypropyl chitosan, all the uncrosslinked cholesteryl-bearing samples farmed monotropic cholesteric phases with left-handed helicoidal structures and exhibited reflection colors over the full cholesteric range. This is the first report of a thermotropic cholesteric liquid crystalline chitosan derivative with reflection bands in the visible region. Both the optical pitches (λ$\_$m/'S) of CHPCT and CHPCTE decrease with temperature or with cholesteryl content at a given temperature. However, the λ$\_$m/ of CHPCT was larger than that of CHPCTE at the same temperature and at the same cholesteryl content. All the crosslinked samples did not display reflection colors, indicating that the cholesteric structure of CHPCTE significantly changes upon crosslinking. The two-dimentional anisotropic swelling characteristic of liquid crystalline networks was observed for all the crosslinked samples.

Preparation of Liquid Crystalline with Gemini Surfactant (제미니형 계면활성제를 사용한 액정기술의 제조방법)

  • Zhoh Choon-Koo;Kim In-Young;Han Chang-Giu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.369-375
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    • 2004
  • In this study, liquid crystalline (LC) is formed using Gemini surfactant (GS) type and moisturizing effect in vivo is measured. $3.0\;wt\%$ of sodium dicocoyl ethylene diamine (PEG)-15 sulfate (SCD-PEG-15S) is used as GS and $4.0\;wt\%$ of hydrogenated dimer acid esters (HDAE) as booster. For stabilizers, $2.0\;wt\%$ of behenyl alcohol (BA) and $1.0\;wt\%$ of Iyso-lecithin (LyL) are utilized. It is stabilized in pH from 4.0 to 10.5 and the best condition is in pH 6.5. The value of viscosity is $8,000\pm500$ cP. The most excellent particles are formed within the range of 4.0 to 15.5 um. Formed LC is observed around LC particles using polarization microscope. It is also observed that lamellar gel network structure is formed around LC particles. Moisturizing effect is improved by $13.6\%$ (P<0.05) compared to control when measured 30 min later after coating samples. After 1 h, moisturizing effect is improved by 1$12.6\%$ (P<0.05) than control while showing $28.3\%$ (P<0.05) of improvement after 4 h. These results may be caused from that manufactured LC forms lamellar structure so that it has better water-holding ability and absorbance of oil increases. This formula could be utilized by delivery system (DS) on skin so that this technology can be applied for manufactuing pharmaceuticals and cosmetics.

Optimization of a 3-Stack Color TN LCD Using Color Polarizers (색 편광판을 이용한 3층 구조 칼라 TN LCD의 최적화)

  • 박경호;진현석;이기동;윤태훈;김재창
    • Proceedings of the Optical Society of Korea Conference
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    • 2001.02a
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    • pp.138-139
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    • 2001
  • 일반적으로, 표시 소자에서 원하는 색을 얻기 위해서는 가색 혼법, 감색 혼법 두 종류의 색 혼합 방법을 사용한다. 가색 혼법은 액정 cell에 적색, 녹색, 청색의 칼라 필터를 사용하여 3가지 색을 더함으로 색을 표현하는 방법이다. 가색 혼법은 매우 높은 명암 대비비를 얻을 수 있으며, 노트 PC와 휴대용 소자를 포함한 대부분의 LCD 분야에 적용된다. 그러나, 밝은 상태의 광 세기가 이론적으로 입사광의 1/3로 줄어들기 때문에 투과율이 낮다는 단점이 있다. (중략)

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Hybrid Liquid Crystal Cell for a Fast-Response High-Contrast Reflective Display (빠른 응답과 높은 대비비의 반사형 LCD를 위한 HAN Cell)

  • 문성훈;이기동;윤태훈;김재창
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.234-235
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    • 2000
  • 최근에 많이 사용되는 휴대용 기기의 표시장치인 액정표시장치(LCD)에는 반사형이 많이 사용되고 있다. 반사형 LCD는 전력소모의 많은 부분을 차지하는 backlight를 주변광원으로 대체하여 전력소모를 줄일 수 있는 표시장치로 많이 연구되고 있다. 특히, 반사형 LCD는 밝기면에서 우수한 single-polarizer mode가 적합하다$^{1.3}$ . 그러나 single-polarizer mode는 two-polarizer mode와 비교해서 dark 상태에서의 누설광이 많이 발생하여 대비비가 저하되는 단점이 있다. 이 점을 보완하기 위하여 전 파장 영역에서 편광판에 의해 반사광이 차단될 수 있도록 설계를 했다. (중략)

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Liquid crystal alignment on rubbed self-assembled monolayers according to alkyl chain length (알킬 사슬 길이에 따른 러빙 처리된 자기 조립 단분자막의 액정 배향 연구)

  • Park, Hong-Gyu;Park, Mu-Hun
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.14 no.5
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    • pp.362-368
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    • 2021
  • A homeotropic liquid crystal (LC) alignment state on rubbed fluorinated self-assembled monolayers (FSAMs) is described according to alkyl chain length. A simple procedure, gas-phase method, for the preparation of FSAM was used. The average optical transmittance in the visible light range of FSAMs were 76.63% to 78.21%, which were superior to the conventional polyimide layer having a transmittance of 75.89%. In addition, the excellent homeotropic LC alignment characteristics of FSAMs were observed through pretilt angle measurement and polarized optical microscope images. By measuring the contact angles and the surface energies of FSAMs, it was confirmed that pretilt angles of LC molecules increased according to the alkyl chain length. High optical transparency and uniform homeotropic LC alignment characteristics of FSAMs showed the possibility of FSAMs as an LC alignment layers.