• Journal of the Korean Chemical Society
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• v.31 no.3
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• pp.207-214
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• 1987

Rates of solvblysis of benzyl chloride in ethanol-water mixtures have been measured at 30 and $40^{\circ}C$ under various pressures up 1.6 kbar. The plots of 1n k as a function of pressure are fitted to a second order function in p, and values of ${\Delta}V^{\neq}$and ${\Delta}{\beta}^{\neq}$ are obtained from the results. Also the values of various pseudo thermodynamic quantities were evaluated from the rate constants. The relationships of the 1n k to $Q_w$ or 1n $C_w$ indicate that the reaction proceeds through $S_N1$ mechanism. A comparison between the present and the previous results gives that the increasing order of ${\mid}{{\Delta}V_0}^{\neq}{\mid}$ and n-values are $p-Cl>p-H>p-CH_3$ and $p-CH_3>p-H.p-Cl$, respectively. From these results, it is believed substituent such as the $p-CH_3$group favors the $S_N1(1)$ character, while the p-Cl group leads to the $S_N1(2)$ character.

• Journal of Advanced Marine Engineering and Technology
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• v.33 no.2
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• pp.244-251
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• 2009

Porous media have especially large surface area per volume, which contain complex fluid passage. If porous media can be applied to cool a CPU or an electronic device with large heat dissipation, it could result in heat transfer enhancement due to the enlargement of the heat transfer area and the flow disturbance. This study is aimed to identify the heat transfer and pressure drop characteristics of high-porosity metal foams in a horizontal channel. Experiment is performed with the various heat flux, velocity and pore density conditions. Permeabilities, which is deduced from Non-Darcy flow model, become lower with increasing pore density. Nusselt number also decreases with higher pore density. High pore density with same porosity case shows higher pressure loss due to the increase of surface area per unit volume. The fiction factor decreases rapidly with increase of Reynolds number in Darcy flow region. However, it converges to a constant value of the Ergun coefficient in Non-Darcy flow region.

• Journal of ILASS-Korea
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• v.1 no.3
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• pp.20-28
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• 1996

It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with 24 m of the inner diameter and 1,500 mm of the length. The used polymer materials are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results were shown that the drag is higher reduced by co-polymer rather than polyanylamide.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.491-495
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• 2004

The industries use polymer materials for many purposes for they have many merits. The costs of these materials take up too great a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2$, $N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This characteristic of microcellular foaming process has influenced by cell morphology. The cell morphology means cell size and cell density. The cell morphology has influenced by many factors. The examples of factor are pressure drop rate, foaming temperature, foaming time, saturation pressure, saturation time etc. Among their factors, pressure drop rate is the most important factor for cell morphology in microcellular foaming injection molding process. This paper describes about the cell morphology change in accordance with the pressure drop rate of microcellular foaming injection molding process.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.4
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• pp.126-132
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• 2009

Automotive heat exchangers use louver fins for their high efficiency. However, the efficiency can significantly drop for constructional vehicles or heavy equipments due to dust deposited on the louver fins with narrow slits. Thus it is necessary to develop new fins that lead to less fouling, so that a better performance can be achieved after exposure to a dusty environment over long period of time. New wavy fins were considered in the study and numerically analysed to compare with louver fins in the areas of air-side pressure drop, heat release rate, and particulate deposition. In addition, an experiment was done on the pressure drop and the particulate deposition. The results showed that the wavy fins would be a better choice for long-term use due to the excellent dust-proof performance in comparison to louver fins, in spite of the initial inferior performance of heat release.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.1
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• pp.187-197
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• 1996

Many investigations have been made to determine the pressure drop and heat transfer characteristics for single phase flow in tape generated swirl flow. But few studies have been carried out to investigate the heat transfer in two component, two phase swirl flow with non-boiling. An experimental study has been conducted to determine the effects of tape twist ratios on two phase convective heat transfer coefficients, pressure drop, and void fraction distribution in a non-boiling, air-water, two phase flow. The flow conditions were both swirl and non swirl flows. The internal diameter of the test section is 42.5mm. The tape twist ratios of pitch to diameter ratio varied from 4.0 to 10.6. The heating conditions were isothermal and nonisothermal. The flow patterns identified with experiments were bubbly, bubbly-slug, slug, and slug-annular flow in up-flow. This study has concluded that no significant difference in void fraction distribution were observed both isothermal and nonisothermal conditions, the pressure drop for two phase flow with twisted tape swirler increase as the tape twist ratio decrease, and that values of two phase heat transfer coefficient increase when the tape twist ratio decreases.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.24 no.12
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• pp.858-866
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• 2012

A numerical study was performed to predict the performance of a fin-and-tube condenser. A condenser model was developed and verified by comparing the simulation results with experimental data for a R410A condenser in a residential air-conditioning system. The prediction error was 0.07% and -5.77% for the condenser capacity and pressure drop, respectively. In simulation results, the capacity and pressure drop of the condenser with even air velocity distribution were 0.67% and 12.93% higher than those with uneven distribution of air velocity. It was predicted by the model that the refrigerant distribution at the condenser inlet to the two first passes was not significantly influenced by the air distribution. The simulation results presented that the 1.49% of capacity and 64.6% of pressure drop were reduced by replacing helical microfin tubes with smooth tubes for the condenser.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.4
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• pp.251-257
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• 2011

In the present study, a 3-dimensional (3D) numerical model was developed to mimic the micro porous structure of a geological $CO_2$ storage reservoir. Especially, 3D modeling technique assigning random pore size to a 3D micro porous structure was devised. Numerical method using CFD (computational fluid dynamics) was applied for the 3D micro porous structure to calculate supercritical $CO_2$ flow field. The three different configurations of 3D micro porous model were designed and their flow fields were calculated. For the physical conditions of $CO_2$ flow, temperature and pressure were set up equivalent to geological underground condition where $CO_2$ fluid was stored. From the results, the characteristics of the supercritical $CO_2$ flow fields were scrutinized and the influence of the micro pore configuration on the flow field was investigated. In particular, the pressure difference and consequent $CO_2$ permeability were calculated and compared with increasing $CO_2$ flow rate.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.573-580
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• 2005

This study was to investigate the removal characteristics of toluene in a gas stream by using a biotrickling filter packed with zeolite-contained polyethylene media. The specific surface area and the void fraction of the media were $500\;m^2/m^3$ and 82%. The surface roughness of the media was higher than that of pure polyethylene media. The toluene removal efficiency decreased with increasing the inlet toluene concentration and gas flow rate. The maximum elimination capacity of toluene in the biotrickling filter was $64\;g/m^3{\cdot}hr$. During 200 days operation, toluene removal efficiency was maintained from 90% to 98% until 167 days, hereafter, it was rapidly reduced with a rise in pressure drop due to an excess proliferation of biomass on the media. Pressure drop and removal capability of the biotrickling filter was fully recovered after backwashing.

• Journal of Energy Engineering
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• v.18 no.2
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• pp.87-92
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• 2009

An experimental investigation is conducted to study a 2-phase vertically upward hydraulic transport of solid particles by water and non-Newtonian fluids in a slim hole concentric annulus with rotation of the inner cylinder. Rheology of particulate suspensions in viscoelastic fluids is of importance in many applications such as particle removal from surfaces, transport of proppants in fractured reservoir and cleaning of drilling holes, etc. In this study, a clear acrylic pipe was used in order to observe the movement of solid particles. Annular velocities varied from 0.3 m/s to 2.0 m/s. The mud systems included fresh water and CMC solutions. Main parameters considered in the study were inner-pipe rotation speed, fluid flow regime and particle injection rate. A particle rising velocity and pressure drop in annulus have been measured for fully developed flows of water and of aqueous solutions. For both water and 0.2% CMC solutions, the higher the concentration of the solid particles is, the larger the pressure gradients become.