• Title/Summary/Keyword: 암석화학

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Petrology and Petrochemistry of the Cretaceous Granites in the Southern Mungyeong Area (문경(聞慶) 남부일대(南部一帶)에 분포(分布)하는 백악기(白惡紀) 화남암류(花南岩類)의 암석학(岩石學) 및 암석화학(岩石化學))

  • Yun, Hyun Soo;Kim, Seon Eok
    • Economic and Environmental Geology
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    • v.23 no.3
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    • pp.343-352
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    • 1990
  • The Cretaceous granites are widely distributed in the studied area, Mungyeong-Sangju, which belongs to the southwestern part of the Ogcheon Folded Belt. The granites are characterized by medium-coarse grained, spotted miaroles, partly flow textures of biotite, aplitic dykes and pegmatitic pockets with druse. From the major compositions, the granites indicate peraluminous, calc-alkaline, salic and late stage products of differentiation. In the view of normative compositions of Qz-Ab-Or and perthitic alkali feldspar, they were formed under 1-4kb and $426^{\circ}-456^{\circ}C$ in acqueous conditions. The K/ Ar biotite age shows $72{\pm}1$ Ma for this grante, corresponding to the igneous activity of the Bulgugsa Disturbance periods in the area. The above results represent that these granite bodies are differentiated from a single magma.

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Effects of Rock Weathering on the Degradation of Engineering Properties (암반풍화도에 따른 지질공학적 특성 저감효과)

  • Lee Chang-Sup;Cho Taechin
    • Tunnel and Underground Space
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    • v.15 no.6 s.59
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    • pp.411-424
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    • 2005
  • Weathering is defined as a process by which surface rock, once formed in the deep ground, is broken down and altered to keep the equilibrium with the ambient environment. In this study granitic rock samples of different weathering grades were collected in the field and the microscopic observation, X-ray diffraction analysis, electron microscopic observation, chemical analysis, and rock property tests were carried out. Formation of secondary minerals, especially clay minerals, by weathering was identified and the mechanism for the change of engineering properties such as rock strength degradation was analyzed. Tunnel model test, Failure behaviour, Shallow tunnel, Unsupproted tunnel length.

Synthetic study of Zeolites from Some Glassy Rocks (I) L Low-Temperature Hydrothermal Synthesis of Zeolites Na-P, Na-X, and Na-A (유리질 암석으로부터 제올라이트 합성에 광한 연구 (I) : Na-P, Na-X 및 Na-A 제올라이트의 저온 수열 합성)

  • 노진환
    • Journal of the Mineralogical Society of Korea
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    • v.3 no.1
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    • pp.7-17
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    • 1990
  • 화산 유리질 암석을 출발 물질로 사용하여 저온 ($80^{\circ}C$)에서 수열 처리하여 Na-P Na-X 및 Na-A 제올라이트를 합성하였다. 합성과정은 (1) 유리질 분말 시료와 알칼리 용액과의 용해.변질 반응에 의한 1차적인 Na-P의 합성 방식과 (2) 여기서 잔류된 규산질 모액에 Al(OH)3나 NaAlO2의 수용액을 공급하여 보다 고순도의 Na-P, Na-X 및 Na-A를 효과적으로 합성할 수 있었다. 원암의 암상과 조성은 제올라이트들의 화학 조성과 순도 및 백색도같은 물리적 특성에는 영향을 주지만, 합성된 제올라이트의 광물종을 규제하는 주된 요인은 아닌 것으로 해석된다. 합성된 제올라이트의 광물상은 반응 용액의 pH, Al(OH)4 및 Na+에 대한 농도 조건에 주로 의존되는 경향을 나타낸다. 또한 화산 유리질 암석을 제올라이트 합성원료로 활용하는 데에 있어서 (2)와 같음 합성 방안이 보완적으로 시행되면 그 생산성과 효율성을 제고시킬 수 있을 것으로 여겨진다.

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A Process Study on the Cavities by Cave landform Deformation (동굴내부(洞窟內部)의 지형변형(地形變形)에 의한 동공(洞空)의 발달과정(發達過程) 연구(硏究))

  • Oh, Jong-Woo
    • Journal of the Speleological Society of Korea
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    • no.88
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    • pp.51-62
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    • 2008
  • 동굴내부의 지형변형은 동굴내의 외인적인 요인과 내인적인 요인에 의하여 발달된다. 외인적인 요인으로서 기후변동에 의한 기온의 변화와 침출수의 증감 및 외부 이입물질 등을 들 수 있으며, 내인적인 요인으로서는 암석의 공극율, 지질환경, 단층 및 습곡면의 형상, 절리 및 균열면의 유무, 동굴지천의 구배 및 유속, 층리간의 이종의 암석게재 여부 등을 들 수 있다. 동굴 시스템은 수문 물리화학적 요소에 의해 형성되며 외부 기준면 통제에 의해서 암석학, 구조학, 기후학, 생물학, 토양학 등과 밀접한 상태에서 의존적인 발달 과정을 가진다. 동혈 내부의 침식은 유수의 입력 경우 유출과정에서 형성되며, 또한 유수의 비 입력 경우유출 및 액체용액의 분출에 의해서 형성된다. 다수의 동굴학자들은 동굴은 계절마다 침수되거나 빨리 흐르는 홍수에 의한 폭우에 의해 epiphreatic 상태에서 간헐적으로 포화되는 과정을 거치며 선택적으로 발달한다고 주장하고 있다. 혼합지대 동굴의 가장 좋은 예는 현재의 카르스트 지역에서 나타나는 것이 아니라 과거 제4기의 200만년전 동안보다 해수면이 더 안정적이었던 때에 이루어진 고 카르스트(Paleo Karst)에서 발견되고 있다.

Multiple Magmas and Their Evolutions of the Cretaceous Volcanic Rocks in and around Mireukdo Island, Tongyeong (통영 미륵도 주변 백악기 화산암류의 복식 마그마와 그 진화)

  • Hwang, Sang Koo;Lee, So Jin;Ahn, Ung San;Song, Kyo-Young
    • The Journal of the Petrological Society of Korea
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    • v.27 no.3
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    • pp.121-138
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    • 2018
  • We have examined the petrotectonic setting and magmatic evolution from petrochemical characteristics of major and trace elements for the Cretaceous volcanic rocks in and around the Mireukdo Island. The volcanic rocks, can be devided into Jusasan, Unmunsa, Yokji and Saryang subgroups on the ascending order, are classified as basalt, basaltic andesite, andesite, dacite and rhyolite on TAS diagram. Petrochemical data show that the rocks are calc-alkaline series, and suggest that erupted earlier medium-K series and later high-K series. The volcanic rocks provide a case in which the calc-alkaline magma are formed, not only from separate protoliths, but following separate paths from source to surface. Earlier and later subgroups take different paths to the surface respectively, and are emplaced in the shallow crust as a series of discrete magma chambers through the volcanic processes. After emplacement, each chamber evolves indepently through fractional crystallization with a little assimilation of wall rock. The volcanic rocks have close petrotectonic affinities with orogenic suite and subduction-related volcanic arc. The rhyolitic magma can be derived from calc-alkaline andesitic magma by fractional crystallization with crustal assimilation, which may be derived from a partial melt of peridotite in the upper mantle.

Petrology of the Basalts in the Seongsan-Ilchulbong area, Jeju Island (제주도 성산일출봉 일대 현무암에 대한 암석학적 연구)

  • Koh, Jeong-Seon;Yun, Sung-Hyo;Jeong, Eun-Ju
    • Journal of the Korean earth science society
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    • v.28 no.3
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    • pp.324-342
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    • 2007
  • This study reports petrography and geochemical characteristics of the basalt lava flows in Seongsan-Ilchulbong area, the easternpart of Jeju island, Korea, to understand the evolutionary processes of magma. Basalt lavas are classified into the Pyoseon-ri basalt and the Seongsan-ri basalt. The Pyoseon-ri basalt is dark-gray colored with many vescicles, and mainly consists of olivine, feldspar and rarely of clinopyroxene as phenocrysts. The Seongsan-ri basalt is largely aphanitic basalt and bright-gray colored, divided into two lava-flow units: lower lava flow (B1) and upper lava flow (B2) by the intercalated yellowish lapillistone and paleosol. The lavas plotted into sub-alkaline tholeiitic basalt and alkaline basalt series. The tholeiitic basalts have characteristically higher $SiO_2,\;FeO^T$, and CaO contents, but lower $TiO_2,\;K_2O,\;P_2O_5$ and other incompatible elements compared to the alkali basalts. The tholeiitic basalts have higher $SiO_2$ to the same MgO contents than the alkalic basalts. The contents of Ni, Cr, and MgO show a strong positive correlation, which indicates that low-MgO phases like plagioclase and titanomagnetite were important during the differentiation of magma. The contents of incompatible elements against that of Th show a strong positive correlation. The chondrite-nomalized REE patterns of tholeiitic and alkalic basalts are subparallel each other. LREEs contents of the former are lower than, but HREEs contents are similar to the latter. They both are similar to their K/Ba ratios. The primitive-mantle normalized spider diagram demonstrates that the contents of Ba and Th of all basaltic magma are enriched, and yet Cr, Ni are depleted. The tholeiitic and alkalic basalts may be originated from a different degree of the partial melting of the same mantle material source, and one shows a higher degree of the partial melting than the other.

Geochemical Study on the Genesis of Chuncheon Nephrite Deposit (춘천 연옥의 기원에 관한 지구화학적 연구)

  • 박계현;노진환
    • The Journal of the Petrological Society of Korea
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    • v.9 no.2
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    • pp.53-69
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    • 2000
  • To reveal the origin of the Chuncheon nephrite deposit, radiogenic isotopes of Sr and Pb, stable isotopes of 0 and H, and rare earth elements concentrations were analyzed. Such geochemical data were integrated to track the stepwise changes during the various ore formation stages. All the samples from the nephrite deposit have significantly low 0 isotopic ratios compared with the marble from which they had been formed, which reflects the very important role of the crustal circulating water with low 6180 and 6D in every stage of ore formation. There were progressive decrease of 6180 and 6D during the genesis of Chuncheon nephrite deposit. Newly formed minerals during the ore formation reveal disequilibrium with existing minerals in the respect of 0 isotope, which suggests that the ore-forming fluid of circulating water origin was involved with significant water-rock ratios in every step of ore formation process. The ore samples have Sr and Pb isotopic ratios similar to the values of Kyeonggi gneiss complex within which the deposit is located, which also suggests the important role of crustal circulating water in the genesis of the deposit. In conclusion, all the geochemical data support that major portion of the ore-forming fluid of Chuncheon nephrite deposit was derived ultimately from the surface water of meteoric origin. The meteoric water supplied Sr and Pb through leaching the rocks surrounding the ore deposits.

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SHRIMP Zircon U-Pb Geochronology, Geochemistry and Sr-Nd Isotopic Study of the Cheongju granitoid rocks (청주 화강암의 SHRIMP 저어콘 U-Pb 연대, 지구화학 및 Sr-Nd 동위원소 연구)

  • Cheong, Won-Seok;Kim, Yoon-Sup;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
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    • v.20 no.4
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    • pp.191-206
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    • 2011
  • The emplacement ages, whole-rock geochemistry and Sr-Nd isotopic compositions of granitoid rocks from Cheongju area, South Korea, were investigated for delineating their petrogenetic link to the Jurassic Daebo granitoid rocks. Zircon crystals were collected from the diorite, biotite granite and acidic dyke samples in a single outcrop. Cross-cutting relationships show that the emplacement of diorite was postdated by the intrusion of biotite granite. Both rocks have been subsequently intruded by acidic dyke. The U-Pb isotopic compositions of zircon from the diorite, biotite granite, and acidic dyke were measured using a SHRIMP-II ion microprobe, yielding the crystallization ages of $174{\pm}2Ma$, $170{\pm}2Ma$, and $170{\pm}5Ma$, respectively, with 95% confidence limits ($t{\sigma}$). The emplacement ages are consistent with those determined from the above relative ages. The major and trace element patterns of the rocks are consistent with those of the Jurassic Daebo granitoid rocks, possibly suggesting a subduction-related I-type granite. The geochemical signature is, however, betrayed by the Sr and Nd isotopic compositions of these rocks. The isotopic signatures suggest that the rocks were produced either by the partial melting of lower-crust or by the mantle-derived magma contaminated by the basement rocks during its ascent and/or emplacement. In addition, the inherited ages of zircons of the rocks (ca. 2.1, 1.8, 0.8 and 0.4 Ga) suggest a possible assimilation with crustal rocks from the Gyeonggi massif and Ogcheon metamorphic belt.

Petrochemistry and magma process of Jurassic Boeun granodiorite in the central Ogcheon belt (중부 옥천대에 분포하는 쥬라기 보은 화강섬록암의 암석화학과 마그마과정)

  • 좌용주
    • The Journal of the Petrological Society of Korea
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    • v.5 no.2
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    • pp.188-199
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    • 1996
  • Boeun granodiorite, which intruded into the metasedimentary rocks of the Ogcheon Group, show chemical natures of metaluminous and calc-alkaline. Generating and emplacing environment of the Boeun granodiorite would have been a active continental margin. Comparing to the contemporaneous Inje-Hongcheon granodiorite in the Gyeonggi massif, the Boeun granodiorite seems likely to have formed under more immature continental arc environment. Compositional changes of major, trace and rare earth elements in granodiorite and felsic dyke are not certain to indicate crystallization differentiation. From this fact, the simple fractional crystallization model would be in question to explain the magma process which controlled the formation of the Boeun granitic mass. The model calculations for Rayleigh fractionation, fractionation with variable major-component composition, assimilation-fractional crystallization (AFC) were carried out to examine the magma process of the mass. The results of former two models do not agree with the compositional variations in the mass. The AFC model can be, however, applied to the magma process. The conditions for AFC process are (1) composition of assimilated wallrock is similar to that of primary magma. (2) assimilating rate is similar to crystallizing rate, and (3) mass of assimilated wallrock is about 10% of that of the magma. These conditions deny a possibility that the assimilated wallrock was the metasedimentary rocks of the Ogcheon Group. This indicates that after having experienced the assimilation process in deeper crust, the granodiorite magma intruded into the Ogcheon group. Every model calculating suggests that the felsic dyke was differentiated not from the granodiorite magma, but from a different source magma.

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