• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.30 no.12
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• pp.26-34
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• 2001

흡수식 사이클에 이용되는 이성분 혼합물인 암모니아/물의 작동유체로 하는 상온에너지의 장거리수송 및 변환기술을 소개한다.

• Clean Technology
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• v.21 no.2
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• pp.108-116
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• 2015

Hydrogen sulfide and ammonia are one of the common malodorous compounds that can be found in emissions from many sewages treatment plants and industrial plants. Therefore, removing these harmful gases from emissions is of significance in both life and industry because they can cause health problems to human and detrimental effects on the catalysts. In this work, pyrolytic carbon blacks from waste tires were used to develop adsorbent with good adsorption capacity for removal of hydrogen and ammonia. Pellet-type adsorbents were prepared by a mixture of carbon black, metal oxide and sodium hydroxide or hydrochloric acid, and their adsorption capacities were estimated by using breakthrough curve of a continuous fixed bed adsorption column at ambient condition. The adsorbent manufactured with a mixture of carbon black, iron oxide(III) and sodium hydroxide showed the maximum working capacity of hydrogen sulfide. For ammonia, maximum working capacity was obtained by the adsorbent manufactured with a mixture of carbon black, copper oxide(II) and hydrochloric acid.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.6
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• pp.483-491
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• 2014

In this study, a thermodynamic analysis was carried out for a combined power generation system using a low-temperature heat source in the form of sensitive energy and liquefied natural gas cold energy. An ammonia-water mixture, which is a zeotropic mixture, was used as the working fluid, and systems with and without a regenerator were comparatively analyzed. The effects of the mass fraction of ammonia and the condensation temperature of the working fluid on the system variables, including the net work production, exergy destruction, and thermal and exergy efficiencies, are analyzed and discussed. The results show that the performance characteristics of the system varied sensitively with the ammonia concentration or condensation temperature of the working fluid. The system without regeneration was found to be better in relation to the net work per unit mass of the source fluid, whereas the system with regeneration was better in relation to the thermal or exergy efficiency.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.6
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• pp.570-579
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• 2010

Since the temperature of waste heat source is relatively low, it is difficult to maintain high level of efficiency in power generation when the waste heat recovery is employed in the system. In an effort to improve the thermal efficiency and power output, use of ammonia-water mixture as a working fluid in the power cycle becomes a viable option. In this work, the performance of ammonia-water mixture based Rankine cycle is thoroughly investigated in order to maximize the power generation from the low temperature waste heat. In analyzing the power cycle, several key system parameters such as mass fraction of ammonia in the mixture and turbine inlet pressure are studied to examine their effects on the system performance. The results of the cycle analysis find a substantial increase both in power output and thermal efficiency if the fraction of ammonia increases in the working fluid.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.1
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• pp.109-117
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• 2011

Since the thermal performance of cycles for use of low-temperature source is low if a pure working fluid is used, the cycles using ammonia-water binary mixture as a working fluid has attracted much attention over past two decades. Recently, several commercial power plants using Kalina cycles have been built and being operated successfully. In this work thermodynamic performance of Kalina cycles using ammonia-water mixture as a working fluid is investigated for the purpose of extracting maximum power from low-temperature energy source. Special attention is paid to the effect of system parameters such as concentration of ammonia and turbine inlet pressure on the characteristics of the system. Results show that the system performance is influenced sensitively by the ammonia concentration, and the role of the performance of heat exchangers is crucial.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.3
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• pp.223-230
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• 2011

The power cycle using ammonia-water mixture as a working fluid is a possible way to improve efficiency of the system of low-temperature source. In this work thermodynamic performance of the ammonia-water regenerative Rankine cycle with partial-boiling flow is analyzed for purpose of extracting maximum power from the source. Effects of the system parameters such as mass fraction of ammonia, turbine inlet pressure or ratio of partial-boiling flow on the system are parametrically investigated. Results show that the power output increases with the mass fraction of ammonia but has a maximum value with respect to the turbine inlet pressure, and is able to reach 22 kW per unit mass flow rate of source air at $180^{\circ}C$.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.1
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• pp.65-72
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• 2012

Rankine cycle using ammonia-water mixture as a working fluid has attracted much attention, since it may be a very useful device to extract power from low-temperature heat source. In this work, the thermodynamic performance of regenerative ammonia-water Rankine cycle is thoroughly investigated based on the second law of thermodynamics and exergy analysis, when the energy source is low-temperature heat source in the form of sensible energy. In analyzing the power cycle, several key system parameters such as ammonia mass concentration in the mixture and turbine inlet pressure are studied to examine their effects on the system performance including exergy destructions or anergies of system components, efficiencies based on the first and second laws of thermodynamics. The results show that as the ammonia concentration increases, exergy exhaust increases but exergy destruction at the heat exchanger increases. The second-law efficiency has an optimum value with respect to the ammonia concentration.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.2
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• pp.148-154
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• 2018

This paper presents a comparative analysis of thermodynamic performance of ammonia-water Rankine cycles with and without regeneration and Kalina cycle for recovery of low-temperature heat source. Special attention is paid to the effect of system parameters such as ammonia mass fraction and turbine inlet pressure on the characteristics of the system. Results show that maximum net power can be obtained in the regenerative Rankine cycle for high turbine inlet pressures. However, Kalina cycle shows better net power and thermal efficiency for low turbine inlet pressures, and the optimum ammonia mass fractions of Kalina cycle are lower than Rankine cycles.

• Journal of the Korean Solar Energy Society
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• v.31 no.1
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• pp.15-22
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• 2011

It is a great interest to convert more energy in the heat source into the power and to improve the efficiency of power generating processes. Since the efficiency of power generating processes becomes poorer as the temperature of the source decreases, to use an ammonia-water mixture instead of water as working fluid is a possible way to improve the efficiency of the system. In this work performance of ammonia-water regenerative Rankine cycle is investigated for the purpose of extracting maximum power from low-temperature waste heat in the form of sensible energy. Special attention is paid to the effect of system parameters such as mass fraction of ammonia and turbine inlet pressure on the characteristics of system. Results show that the power output increases with the mass fraction of ammonia in the mixture, however workable range of the mass fraction becomes narrower as turbine inlet pressure increases and is able to reach 16.5kW per unit mass flow rate of source air at $180^{\circ}C$.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.6
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• pp.621-628
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• 2019

The use of the ammonia-water zeotropic mixture as a working fluid in the power generating system has been considered as a proven technology for efficient recovery of low-grade heat sources. This paper presents a thermodynamic performance analysis for ammonia-water evaporator using low-grade heat source, based on the exergy and entransy which has been recently introduced as a physical quantity to describe the heat transfer ability of an object. In the analysis, effects of the ammonia mass fraction and source temperature of the binary mixture are investigated on the system performance such as heat transfer, effectiveness, exergy destruction, entransy dissipation, and entransy dissipation based thermal resistance. The results show that the ammonia mass concentration and the source temperature have significant effects on the thermodynamic system performance of the ammonia-water evaporator.