• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 1996.10a
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• pp.81-84
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• 1996

퇴비화온실의 재배환경은 퇴비화 과정중에 발생하는 발효열이나 탄산가스로 인하여 관행온실과는 큰 차이가 있다. 본 연구는 퇴비화과정중에 발생하는 암모니아가스의 동태와 퇴비화에 수반되는 환경의 변화가 토마토의 생육에 어떠한 영향을 미치는지 구명하고자 관행온실과 퇴비화온실의 환경변화를 추적하면서 토마토의 생장과 수량 및 과일의 품질을 비교하였다. (중략)

• Korean Chemical Engineering Research
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• v.52 no.2
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• pp.191-198
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• 2014

A semi-pilot hybrid system composed of a photocatalytic reactor and a biofilter was operated under various operating conditions in order to treat malodorous waste air containing both hydrogen sulfide and ammonia which are major air pollutants emitted from composting factories and many publicly owned treatment works (POTW). When both hydrogen sulfide and ammonia contained in malodorous waste air were treated simultaneously by a biofilter system, its performance of ammonia removal was much more poor than that by a biofilter system treating waste air containing only ammonia, unlike its performance of hydrogen sulfide removal. For semi-pilot hybrid system, the removal efficiencies of hydrogen sulfide and ammonia turned out to be ca. 83 and 65%, respectively. Therefore, for semi-pilot hybrid system, the removal efficiencies of hydrogen sulfide and ammonia was increased by ca. 4 and 30%, respectively, compared to those of semi-pilot biofilter system (control). In addition, the maximum elimination capacities of hydrogen sulfide and ammonia for semi-pilot hybrid system turned out to be ca. 60 and $37g/m^3/h$, respectively. These maximum elimination capacities of hydrogen sulfide and ammonia were estimated to be ca. 9.1% and ca. 23.3% greater than those for semi-pilot biofilter system (control), respectively. Therefore, the semi-pilot hybrid system contributed the enhancement of removal efficiency and the maximum elimination capacity of ammonia in a higher degree than that of hydrogen sulfide, compared to the semi-pilot biofilter system.

• Korean Chemical Engineering Research
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• v.51 no.5
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• pp.568-574
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• 2013

A semi-pilot biofilter packed with media with immobilized Thiobacillus sp. IW and return sludge, was operated under various operating conditions in order to treat malodorous waste air containing both hydrogen sulfide and ammonia which are major air pollutants emitted from composting factories and many publicly owned treatment works (POTW). At the incipient and middle stages of a semi-pilot biofilter operation, the hydrogen sulfide-removal efficiency behaves regardless of an inlet-load of ammonia. However, the ammonia-removal efficiency decreased as an inlet-load of hydrogen sulfide increased. Nevertheless, at the final stage of the semi-pilot biofilter operation, the ammonia-removal efficiency was not affected by the increase of hydrogen sulfide-inlet load. It is attributed to that a serious acidification of semi-pilot biofilter-media did not occur due to continuous injection of buffer solution at the final stage of the semi-pilot biofilter operation. When both hydrogen sulfide and ammonia contained in malodorous waste air were treated simultaneously by semi-pilot biofilter, the maximum elimination capacities of hydrogen sulfide and ammonia turned out to be ca. 58 and $30g/m^3/h$, respectively. These maximum elimination capacities were estimated to be ca. 39 and 46% less than those for lab-scaled biofilter-separate elimination of hydrogen sulfide and ammonia, respectively. Thus, for the simultaneous biofilter-treatment of hydrogen sulfide and ammonia, the maximum elimination capacity of ammonia decreased by 7% more than that of hydrogen sulfide.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.11-18
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• 2023

This study explained the need for ammonia fuel and the value chain as a hydrogen carrier. The basic concept of ammonia combustion characteristics and the development of flame stability and low NOx combustion technology were introduced. In addition, through the trend of ammonia combustion technology, the characteristics of ammonia combustion technology in the power generation and industrial sectors were examined, and the author's opinions were included. Through this paper, the author intends to give some overview of basic knowledge about ammonia fuel and its future development direction and meaning.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2001.04a
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• pp.34-34
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• 2001

열CVD법에 의하여 아세틸렌 가스를 탄소 원으로 사용한 탄소 나노튜브의 성장거동을 조사하였다. 닉켈 분말의 직경을 15nm 내지 90nm 범위로 조정하여 기판 에 촉매로 배열하였다. 탄소 나노튜브는 질소, 수소, 알곤, 암모니아 등 여러가지의 가스 분위기에서 증착되었으며 이들 가스의 혼합 분위기가 탄소나 노튜브의 성장에 미치는 영향을 조사하였다. 증착은 대기압 압력하에서 85$0^{\circ}C$ 의 온도에서 이루어졌다. 순수한 질소 분위기에서는 탄소 나노튜브의 성장이 이루어지지 않고 두꺼운 탄소 층이 기판 위에 중착되었다. 이 조건에서는 탄소로 뒤덮혀진 닉켈 입자가 탄소 나노튜브 형성의 촉매 역할을 담당하지 못했다. 그러나 질소와 수소의 혼합분위기에서는 수소의 농도가 증가함에 따라 탄소 나노튜브의 성장이 증진되었다. 순수한 수소 분위기에서는 일정한 방향이 없이 꼬여진 탄소 나노튜브가 성장되었다. 탄소 나노튜브의 성장은 분위기 가스로 암모니아를 사용하였을 때 훨씬 더 증진되었다. 수직으로 배열된 탄소 나노튜료를 암모니아 분위기에서는 성장시킬 수 있었으나 암모니아와 같은 비율의 수소와 질소 가스의 혼합 분위기 하에서 는 탄소 나노튜브의 성장을 얻을 수 없었다. 이러한 결과를 여기에서는 닉켈 촉매의 표면에 과도하게 석출된 탄소의 촉매 passivation으로 설명하였다. 탄소 나노튜브의 증착을 위해서는 아세틸렌 가스의 분해율이 너무 과도하지 않게 즉 촉매의 표면이 과도한 탄소의 증착으로 수동태화 되지않도록 조절되어야 한다는 것이다. 이 연구결과는 분위기 가스의 조성이 탄소 나노튜브의 성장에 있어서 그 반웅 kinetics에 큰 영향을 미친다는 것을 잘 보여주고 있다. 또한 암모니아 분위기에서는 촉매 닉켈입자 표면에 질화물층이 형성되어 탄소 나노튜브의 성장에 영향을 미쳤다는 것도 알 수 있었다.며 실제 가공업체에서도 터짐 문제가 발견되지 않았다. 결론적으로 표면층의 인장강도가 패션/구부림에 가장 중요한 변수로 작용하며 어떠 한 형태로 표면층의 인장강도를 향상시킬 경우 침엽수 펄프는 재생펄프로 대체가 가능 할 것으로 판단된다.하는 통계기법 중의 하나인 주성분회귀분석을 실시하였다. 주성분 분석은 여러 개의 반응변수에 대하여 얻어진 다변량 자료의 다차원적인 변 수들을 축소, 요약하는 차원의 단순화와 더불어 서로 상관되어있는 반응변수들 상호간 의 복잡한 구조를 분석하는 기법이다. 본 발표에서는 공정 자료를 활용하여 인공신경망 과 주성분분석을 통해 공정 트러블의 발생에 영향 하는 인자들을 보다 현실적으로 추 정하고, 그 대책을 모색함으로써 이를 최소화할 수 있는 방안을 소개하고자 한다.금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다. within minimum time from beginning of the shutdown.및 12.36%, $101{\sim}200$일의 경우 12.78% 및 12.44%, 201일 이상의 경우 13.17% 및 11.30%로 201일 이상의 유기의 경우에만 대조구와 삭제 구간에 유의적인(p<0.05) 차이를 나타내었다.는 담수(淡水)에서 10%o의 해수(海水)로 이주된지 14일(日) 이후에 신장(腎臟)에서 수축된 것으로 나타났다. 30%o의 해수(海水)에 적응(適應)된 틸라피아의 평균 신사구체(腎絲球體)의 면적은 담수(淡水)에

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.272-278
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• 2013

The hybrid system composed of a photocatalytic reactor and a biofilter was operated under various operating conditions in order to treat malodorous waste air containing ammonia which is a major air pollutant emitted from composting factories and many publicly owned treatment works. Total ammonia removal efficiency of the hybrid system was maintained to be ca. 80% even though its inlet loads were increased at a higher operating stage according to an operating schedule of the hybrid system. The ammonia removal efficiency of photocatalytic reactor was decreased from 65% to 22% as ammonia inlet loads to photocatalytic reactor were increased. In spite of same inlet loads of ammonia to the photocatalytic reactor, the ammonia removal efficiency of photocatalytic reactor with lower ammonia concentration of fed-waste air was higher than that with higher ammonia concentration of fed-waste air. To the contrary, during the first half of the hybrid system operation the ammonia removal efficiency of a biofilter was quite suppressed while, despite of increased ammonia inlet loads, the ammonia removal efficiency of the biofilter was continuously increased to 78% and reached the ammonia removal efficiency similar to what Lee et al. attained. The maximum ammonia elimination capacity of the photocatalytic reactor was observed to be ca. 16 g-N/$m^3$/h. In an incipient stage of hybrid system run, the ammonia elimination capacity of the biofilter showed little sensitivity against ammonia inlet loads to the hybrid system. However, in the 2nd half of its run, the ammonia elimination capacity of the biofilter was increased abruptly in case of high ammonia inlet loads to the hybrid system. In 6th stage of hybrid system run, total ammonia inlet load attained at ca. 80 g-N/$m^3$/h corresponding to 16 g-N/$m^3$/h of ammonia elimination capacity of the photocatalytic reactor. Then, the remaining ammonia inlet load to the 2nd and main process of the biofilter and its elimination capacity was expected and shown to be ca 64 g-N/$m^3$/h and ca 48 g-N/$m^3$/h, respectively. The ammonia elimination capacity of the biofilter was close to 1,200 g-N/$m^3$/day of the maximum elimination capacity of the investigation performed by Kim et al.

• Journal of the Korea Convergence Society
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• v.12 no.5
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• pp.185-190
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• 2021

An electrolyzed-acidic water treatment was investigated as a methods for removing ammonia, which is a cause of odor in life environment. The prepared electrolyzed-acidic water was found out as stable solvent capable of neutralizing weak alkaline ammonia by measuring changes in pH and ORP. It was found out that ammonia was removed from the mixture solution of electrolyzed-acidic water and ammonia water by the UV-vis absorbance analysis and electrochemical open-circuit potential measurement. The neutralized ammonia by electrolyzed-acidic water and effectively removed odor was measured using ammonia gas detecter. Consequently, we recommend the electrolyzed-acidic water can effectively and safely remove ammonia in eco-friendly.

• Journal of the Korean Chemical Society
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• v.65 no.4
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• pp.260-267
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• 2021

Increasing the needs for eco-friendly natural materials, much attention on natural dyes has been attracted. Curcumin, one of abundant natural dyes available in nature, is an eco-friendly molecule found in turmeric. In this study, the colorimetric sensing behavior characteristics of ammonia and hydrogen chloride gases was analyzed using curcumin ink-printed paper and cotton fabric by inkjet printing method. The fabricated paper and fabric were utilized as a colorimetric sensor that can track food spoilage. The color changes of the samples printed on the paper and cotton upon exposure to the toxic gases, the reversibility of the color changes, and the water resistance were investigated. Both samples showed reversible reactions with NH3 and HCl, and small amount of ammonia produced by food spoilage was successfully sensed with naked eyes, confirming its capability to warn food spoilage in our daily life.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.204-206
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• 2014

석탄 화력발전소에는 연소가스의 질소산화물(NOx) 저감을 위한 SCR(selective catalytic reduction)설비가 운전되고 있으며, SCR은 환원제인 암모니아($NH_3$)를 이용하여 연소가스 내에 질소산화물을 물과 질소로 분해하는 역할을 한다. 그러나, 연소가스 중의 일부 삼산화황($SO_3$)과 미반응 암모니아가 결합하여 황산암모늄염(Ammonium bisulfate; $NH_4HSO_4$)을 생성하며, 이는 후단 APH(air preheater)의 열소자에 점착된 후 분진들과 함께 성장하여 막힘을 야기한다. 막힘이 발생된 APH는 연소가스의 흐름을 방해하기 때문에 차압을 증가시키며, 이는 발전효율의 감소뿐만 아니라 급전정지를 초래한다. 이를 해결하기 위하여 $CO_2$ 드라이아이스 세정 방법을 적용하였으며, pilot-scale plant에서 실험을 수행하였다. 또한, 드라이아이스 공정변수인 분사압력과 분사시간을 제어하여 pilot-scale plant의 APH 열소자 표면에 생성되어있는 오염물질들의 제거효율을 관찰한 결과 95 %의 높은 제거효율을 보였다.

• Monthly Korean Chicken
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• s.152
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• pp.74-79
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• 2008