• Title/Summary/Keyword: 암모늄

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Electrodeposition of Manganese from Ferromanganese Slag with Ammonium Sulfate (황산암모늄에 의한 훼로망간 슬랙으로부터 망간의 전착)

  • Duk Mook Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.4
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    • pp.390-396
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    • 1985
  • The manganese was extracted from ferromanganese slag with 6N ammonium sulfate and purified with ammonium sulfide. The current efficiencies were substantially increased when small amounts of selenious acid is used as an additive. Stainless steel was used as cathodic electrode and lead (+1% Ag) as anodic electrode. The effects of several variables were investigated, and the optimum conditions were found to be; 40g/l Mn in electrolyte at pH 7.0 with 1$20g/l (NH_4)_2SO_4$, Cathode current density 60mA/cm$^2$, Current efficiency 90% and up at the temperature about $25^{\circ}C.$ The metal produced has been consistantly of high quality.

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The effect of ammonium hydroxide with different concentration on fabrication of CdS thin film by Chemical Bath Deposition (CBD) (용액성장법 (CBD)으로 CdS 박막 성장 시 수산화 암모늄 농도 조절이 미치는 영향)

  • Chun, Seung-Ju;Lee, Hyun-Ju;Kim, Dong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.365-365
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    • 2009
  • CBD 증착 방법은 저비용으로 양질의 CdS 박막을 얻을 수 있는 증착 밥법으로, 고효율의 CdTe/CdS 태양전지를 얻기에도 적당하다. CdS 박막의 증착 과정에서 수산화 암모늄 (ammonium hydroxide) 은 박막의 특성을 결정하는 주요한 요소 인자 이다. ITO가 증착된 유리기판위에 CdS 박막 증착 과정에서 동일한 조건에서 산화 암모늄 (ammonium hydroxide) 의 농도만을 조절하여서, XRD, Raman spectrometer, UV-Vis, SEM 분석 장치를 이용하여 구조 및 광학 특성의 변화를 살펴보았다.

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A Study on the Recovery of Mn Component from the Spent Manganese Batteries with Ammonium Sulfate (廢 망간電池로부터 黃酸 암모늄에 의한 Mn 성분의 분리 회수에 관한 연구)

  • 박용성;우제원;황영애
    • Resources Recycling
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    • v.9 no.6
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    • pp.3-8
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    • 2000
  • A reaction between the depolarizing mixture in the spent manganese batteries and ($NH_4$)$_2$$SO_4$was carried out to find a new process for the extraction of Mn component from the spent manganese batteries. The optimum conditions were as follows : the reaction temperature $425^{\circ}C$, ($NH_4$)$_2$$SO_4$weight ratio to the depolarizing mixture in the spent manganese batteries 12.0, reaction time 60 min. Under above conditions manganese was extracted 93.5%.

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Studies on ammonium adsorption by and desorption from various soils (I) -Langmuir adsorption isotherm of ammonium (토양별(土壤別) 암모늄의 흡착(吸着) 및 탈착(脫着)에 관(關)한 연구(硏究) (I) -암모늄의 Langmuir 등온흡착(等溫吸着))

  • Shim, Sang-Chil;Kim, Kwang-Rai;Kim, Moo-Sung;Park, Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.10 no.1
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    • pp.1-6
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    • 1977
  • Fifteen soils including volcanic ash, acid sulfate and degraded saline soils were investigated for Languir adsorption isotherm of ammonium using $NH_4H_2PO_4$. The results are as follows. Languir adsorption maxima of ammonium (LAMA) ranged from 2.4me/100g soil to 12.3 and the average was 5.3. Initial concentration of 30 to 60 or 40 to 80 ppm(as N) appears to be suitable for LAMA measurement. There were two LAMA in some soils. Difference between adsorption constants (bonding energy) was mostly greater than that between LAMA. LAMA ranged from 9.4% to 72% of cation exchange capacity and average was 47%. It did not show any clear tendency with CEC, pH, organic matter content, base saturation percent, P, K, Ca, Mg, Na and Si. Except volcanic ash soils which were grouped into two groups according to ammonium adsorption LAMA was significantly (r=0.951 at 1%) correlated with adsorption at 200ppm. This single concentration seems suitable for LAMA measurement. Probable mechanism of ammonium adsorption was discussed, in which the associated anions were combined with iron and aluminum and then ammonium was bound to phosphorus. Applicability of Langmuir adsorption isotherm model to the soils under field condition was also discussed.

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Preparation of Cr2O3/AP Composites and their Thermal Decomposition Characteristics (Cr2O3/AP 복합체 제조 및 그 열분해 특성)

  • Jung, Jae-Yun;Kim, Jae-Kyeong;Shim, Hong-Min;Kim, Hyoun-Soo;Koo, Kee-Kahb
    • Applied Chemistry for Engineering
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    • v.26 no.2
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    • pp.145-153
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    • 2015
  • $Cr_2O_3/AP$ (ammonium perchlorate) energetic composites were prepared by a method of solvent/anti-solvent. XRD analysis revealed that the crystalline structure of AP in $Cr_2O_3/AP$ composites is the same as that of pure AP. SEM photomicrograph shows that an average size of cuboid $Cr_2O_3/AP$ composites is approximately $2.5{\mu}m$. TGA analysis shows that the addition of submicron $Cr_2O_3$ particles into AP lowers the HTD (high-temperature decomposition) compared to that of neat AP and the activation energy of the $Cr_2O_3/AP$ composites was calculated by the isoconversional Starlink method. Considering changes in the activation energy, the decomposition reaction mechanism of AP was suggested as follows; the decomposition with the formation of nucleation sites renders formation of porous structure in the composites up to conversion of about 0.25 and after further conversion of over 0.3, it seems that decomposition reaction vigorously takes place rather than sublimation of AP.

Studies on the Fire Retardant Treatment of Wet Forming Mat for Hardboard (경질섬유판(硬質纖維板)의 습식(濕式)매트 내화처리(耐火處理)에 관(關)한 연구(硏究))

  • Shin, Dong-So;Lee, Hwa-Hyoung;Shim, Chong-Supp
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.3
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    • pp.180-188
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    • 1982
  • This study was carried out to make hardboard fire retardants and to examine the properties of the hard-board treated with them. The fire retardant treatment was achieved by surface impregnation of water soluble retardant chemicals into the forming mat with 55 percent of moisture content. followed by the hot pressing process. Ammonium monophosphate, ammonium diphosphate, sodium borate, and boric acid were used as the fire retardants. Fire retardant test was carried out by using the differential thermal analysis thermogram. The results are summarized as follows: 1. Fire retardant-treated hardboard showed higher values of the specific gravity. water absoption, and flexural strength than those of untreated hardboard. Especially, the treatment of ammonium monophosphate gave the best results in the flexural strength, and a 10 gr/$ft^2$ loading of the fire retardant compound of ammonium monophoshate, ammonium diphosphate, and sodium borate drew the best flexural strength value among the three different experimental loadings of 10, 20 and 30 gr/$ft^2$. 2. There were no definite differences in moisture content between the fire retardant-treated hardboard and the untreated hardboard. 3. The fire retardant compound of ammonium monophosphate, ammonium diphosphate, and sodium borate resulted in the best fire retardancy, and its fire retardancy was increased in proportion to the increase of loading.

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Improvement of Growth and Benzo[c]phenanthridine Alkaloids Production by Modifying Nitrogen Source in Suspension Cell Culture of Eschscholtzia californica (Eschscholtzia californica의 현탁 세포배양에서 질소원 조절에 의한 세포 성장 및 Benzo[c]phenanthridine Alkaloids 생산량 향상)

  • Lee, Song-Eun;Rhee, Hong-Soon;Son, Seok-Young;Park, Jong-Moon
    • KSBB Journal
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    • v.24 no.2
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    • pp.195-200
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    • 2009
  • The effect of nitrogen source on cell growth and benzo[c]phenanthridine alkaloids production by modifying $NO_3\;^-:NH_4\;^+$ ratio in cell suspension culture of Eschscholtzia califarnica was investigated. When total nitrogen concentration is maintained (60 mM), maximum benzo[c]phenanthridine alkaloids production is about 60.72 mg/L at 50:10 (mol/mol). This productivity was 3.8 times higher than that obtained when cells were grown instandard MS medium. The decrease of $NO_3\;^-:NH_4\;^+$ ratio at 60 mM of total nitrogen caused the decline of both growth and benzo[c]phenanthridine alkaloids production. Under the same concentration of $N0_3\;^-$ (50 mM), higher concentration of $NH_4\;^+$ inhibited cell growth strongly but induced alkaloids production slightly. Also, under the same concentration of $NH_4\;^+$ (25 mM), higher concentration of $N0_3\;^-$ induced alkaloids production strongly but high concentration of $N0_3\;^-$ (${\geq}$100 mM) interfered alkaloids instead. Maximum benzo[c]phenanthridine alkaloids production is about 62.71 mg/L at 50:25 (mol/mol). These results suggest that higher biomass and higher alkaloids production could be obtained by optimizing each nitrogen concentration as well as $NO_3\;^-:NH_4\;^+$ ratio in the culture medium. Nitrate and ammonium in culture medium have distinct role in the regulation of growth and alkaloids production; ammonium had a strong influence on growth while nitrate had an influence on alkaloids production.

4급암모늄염계 항균제를 이용한 PET의 내구성항균가공

  • 최영주;윤남식;박현민;조광호;허만우
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2003.04a
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    • pp.119-122
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    • 2003
  • 최근, 건강, 쾌적성을 추구하는 소비자들의 요구에 응하여 항균가공처리된 섬유제품들이 많이 출품되고 있다. 그 중에서 대부분이 면제품을 상대로 한 항균가공제품이다. 면용항균가공제의 대표적인 제품으로서는 미국Dow Corning사의 내구성항균 가공제 인 DC-5700 (3-(trimethoxysilyl)-propyloctadecyl-dimethyl ammonium chloride)(Scheme 1)이다. 이는 4급암모늄염계 항균제의 오랫동안 문제로 되 온 내구성을 해결한 반응형 항균제로서 많은 각광을 받고 있다. (중략)

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