• Title/Summary/Keyword: 암모늄

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Der EinfluB von Elektrolyten auf den Protonenaustausch in $H_2{^{17}}O$-haltigen waBrigen Losungen ($H_2{^{17}}O$을 포함하는 수용액에서 양성자 교환속도에 미치는 전해질의 영향)

  • Young-Kook Shin;H. G. Hertz
    • Journal of the Korean Chemical Society
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    • v.33 no.2
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    • pp.185-191
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    • 1989
  • Es wurden die Protonenspektren $wa{\beta}rigerH_2{^{17}}O$-haltige Erdalkalimetall-und Tetraalkylammoniumchlorid-Losungen bei $25^{\circ}$ und verschiededenen pH-Werten mit Hilfe der kernmagnetischen Resonanz-spektroskopie aufgenommen. Aus der Halbwertsbreite der Signale wurde die Austauschrate des Protons im Wassermolekul berechnet. Die Austauschrate, die in diesen Losungen beobachtet werden konnte, ist pH-abhangig. Bemerkernwerterweise ist die minimalle Austauschrate pH-abhangig. Dieses letztere Phanomen wird durch den Strukturbildungseffekt der Erdalkalimetallchloride und die hydrophobe Hydratation an Tetraalkylammoniumionen erklart.

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Stability of concentrated Colloidal Liquid Aphrons containing a quaternary ammonium salt in the continuous phase (사차 암모늄 염을 함유하는 농축된 콜로이드 액상 에이프런의 연속상에서의 안정성)

  • Hahm, Hyung Chul;Hong, Won Hi;Lee, Choul Ho
    • Clean Technology
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    • v.7 no.4
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    • pp.291-297
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    • 2001
  • In this study, the stability of concentrated colloidal liquid aphrons (CLAs) containing Aliquat 336 was measured. CLAs in the continuous phase are stabilized by water-soluble surfactant and oil-soluble surfactant. To compare the stability of CLAs, half-life was introduced. According to the change of state of solution, the rate of break-up of concentrated CLAs changed rigorously at critical coagulation concentration. Critical coagulation concentration was measured with changing pH. The effects of ionic strength and concentration of Sodium Dodecyl Benzene Sulfonate (SDBS) on the stability of concentrated CLAs in the continuous phase were also investigated.

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Sorption Behavior of Cesium-137, Cerium-144 and Cobalt-60 on Zeolites (제오라이트에 대한 세슘-137, 세슘-144 및 코발트-60 흡착거동)

  • Kim, Seok-Chul;Lee, Byung-Hun
    • Journal of Radiation Protection and Research
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    • v.10 no.1
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    • pp.3-13
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    • 1985
  • The sorption behavior of some typical fission products such as Cs-137, long-lived radionuclide; Ce-144, rare-earth element; and Co-60, corrosion product on zeolite A, zeolite F-9 (faujasite) and amorphous zeolite was determined with the salt concentrations, 0.01 M- to 2.0 M- nitric acid and ammonium nitrate, and the shaking time, 15 minutes interval from 15 minute to 90 minute. Kd values were obtained through the batch experiment. In conclusion, the optimal conditions for isolation and removal of the typical radionuclides are as following: zeolite, amorphous zeolite; concentration, $0.01\;M-HNO_3\;and\;0.1\;M-NH_4NO_3$; pH4; shaking time, one hour; the most effective species, Cs-137.

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Analysis of Explosion Energy related to the Cause of Tianjin Explosion Accident in China (중국 텐진항 폭발사고 원인과 관련된 폭발 에너지 분석)

  • Kwon, Sangki;Kim, Ha Yung
    • Explosives and Blasting
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    • v.34 no.1
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    • pp.1-10
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    • 2016
  • On August 12, 2015, two huge explosions were accidently happened in Tianjin port, China. The explosion energies of the two explosions were similar to those of TNT 3 tons and TNT 21 tons. Until now, the cause of the explosions was not clearly announced but some guesses of the cause were released. One of the possible cause of the explosion is the generation of explosive acetylene gas from the chemical reaction between $CaC_2$ and spraying water to extinguish fire happened at the storage site of different chemical compounds. The explosion of acetylene gas might ignite the explosion of 800 tons of ammonium nitrate. In this study, the explosion due to the scenario was analyzed in order to check that such a chemical reaction can produce the huge explosion observed at the Tianjin accident.

Antibacterial Activity by Chitosan Derivatives with Quaternary Ammonium Salt (4차 암모늄기를 가진 키토산 유도체의 항균성)

  • Kim, C.H.;Choi, Y.S.;Choi, K.S.
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.1020-1026
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    • 1996
  • Chitosan is the deacetylation product of chitin. Chitosan was converted to N-alkyl chitosan derivatives using proper aldehyde having different alkyl chains, then chitosan derivatives with quaternary ammonium salt were producted by quaternization with methyl iodide. Their antibacterial activities aganst S. aureus(ATCC 6538P) and E. coli (ATCC 14339), gram-positive bacteria and gram-negative bacteria, respectively, as introduced alkyl length were evaluated by shake flask method using colony count. The antibacteiral activity was found to be increased as alkyl chains. hydrophobic goups. These antibacterial agents were more active against S. aureus than E. coli. It may be due to the different of structure of cytoplasmic membrane.

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Moisture-Related Properties of PET Fabrics treated with Quaternary Ammonium Compound/Alkaline Solution (사급(四級) 암모늄 화합물(化合物)과 알칼리 혼합액(混合液)으로 처리(處理)된 PET직물(織物)의 수분특성(水分特性) 연구(硏究))

  • Kim, Do-Hee;Jeon, Dong-Won;Kim, Jong-Jun
    • Journal of Fashion Business
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    • v.7 no.2
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    • pp.69-81
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    • 2003
  • Among the various properties of textile fabrics, the moisture-related properties are important for the textile processes or the apparel comfort characteristics. Alkaline hydrolysis results in pitting on the surface of fibers and increases the amount of hydroxyl and carboxyl end groups of the PET molecules on the fiber surface. The purpose of this study is to investigate the moisture-related properties of PET fabrics treated with quaternary ammonium compound/alkaline solution. The wetting and wicking properties of the PET fabrics were measured using the following experiments: contact angle, surface free energy, work of adhesion, vertical wicking height, moisture regain, and frictional static voltage. It was concluded that by the alkaline hydrolysis process, surface hydrophilicity and reactivity were considerably improved especially at lower levels of weight loss% and that the pitting of the fiber surface resulted in at higher levels of weight loss% was disadvantageous in moisture-related properties of PET.