• Title/Summary/Keyword: 알코올 분해

Search Result 320, Processing Time 0.025 seconds

Study of Toxic Gas Removal Characteristics by Chemical Analysis of Essential Oil using SPME Method (SPME법을 이용한 식물정유 성분분석을 통한 유해가스 제거 특성연구)

  • 박영규
    • KSBB Journal
    • /
    • v.19 no.3
    • /
    • pp.231-235
    • /
    • 2004
  • This paper was investigated to clarify the possibility of ammonia gas removal by essential oil. First of all, the chemical analysis was peformed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil react with ammonia by neutralization and their reaction mechanism was elucidated. Based on their chemical neutralized reaction, the removal efficiencies of ammonia gas were studied to derive the optimal conditions in the scrubber tower such as optimal temperature and pH. The experimental result shows that the removal efficiency of ammonia gas was achieved over 98 % by the misty aerosol dispersion of scrubber tower.

Enzyme Production Related to Alcohol Metabolism from Thermophilic Fungus Thermoascus aurantiacus (호열성 사상균 Thermoascus aurantiacus의 알코올분해대사 관련 효소학적 특성)

  • Ko Hee-Sun;Kim Hyun-Soo
    • Microbiology and Biotechnology Letters
    • /
    • v.34 no.3
    • /
    • pp.216-220
    • /
    • 2006
  • Thermophillic fungus Thermoascus aurantiacus showed excellent growth and produced high amount of alcohol oxidase and catalase in a pectin medium. Besides, the strain produced enzymes which related with pectin or alcohol decomposition. We detected extracellular pectin esterase (EC 3.1.1.11) activity and, both intracellular and extracellular pectinase (EC 4.2.2.10) activity, as pectinolytic enzymes produced by T. aurantiacus. The production of methanol decomposition enzymes, such as alcohol oxidase (AOD, EC 1.1.3.13), alcohol dehydrogenase (ADH, EC 1.1.1.1), formaldehyde dehydrogenase (FADH, EC 1.2.1.1) and formate dehydrogenase (FDH, EC 1.2.1.2) follows by pectin esterase reaction which is converted to methanol. We concluded that T. aurantiacus has pectinolytic and alcohol - oxidative enzymological mechanism which produced carbon dioxide as a final material, started from pectin.

The Production of Alcohol from Municipal Waste(II) - The Effects of Physical or Chemical Treatment on the Enzymatic Hydrolysis of Waste Paper - (도시 폐기물로부터 알코올 생산 (II) - 물리적, 화학적 전처리된 폐지의 효소가수분해 조건 검토 -)

  • Lim, Bu-Kug;Yang, Jae-Kyung;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
    • /
    • v.25 no.1
    • /
    • pp.65-70
    • /
    • 1997
  • The effects on the enzymatic hydrolysis of waste paper treated with physical or chemical treatment were investigated. To gain the higher saccharification rate, physical or chemical treatment are necessary in enzymatic conversion process of waste paper. The major deterrents to the effective utilization of waste paper for enzymatic conversion process are phenolic compounds, cellulose crystallinity and coating materials. In the enzymatic hydrolysis of waste paper, the deterrents through enzymatic conversion process can be eliminated by the physical or chemical treatment. This study was performed to obtain the optimal condition for enzymatic conversion process of non-treated waste paper and to review effects on enzymatic conversion process of waste paper treated with physical or chemical methods. In the aspect of saccharification rate, waste paper treated with 1.5% sodium hypochlorite was the most effective and in physical treatment methods, multi-stage treatment(autohydrolysis+refining treatment) was more effective than the other physical treatment.

  • PDF

Activity of Glutathione S-transferase and Effect of Alcohol Decomposition on the Fruit of Hovenia dulcis Thunb (지구자의 Glutathione S-transferase 활성과 알코올 분해효과)

  • Cha, Bae-Cheon;Lee, Eun-Hee;Lee, Eun;Park, Hang-Ho
    • YAKHAK HOEJI
    • /
    • v.48 no.3
    • /
    • pp.213-217
    • /
    • 2004
  • For the determination of glutathione S-transferase activity, a new method was established by using HPLC system. Moreover, amount of enzyme for a optimum reaction was determined by a comparative study with a variety concentration of enzyme. Using a established method, activity of glutathione S-transferase that is alcohol metabolizing enzyme was investigated on the fruit of Hovenia dulcis Thunb. As the result of experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed visible a synergistic effect of glutathione S-transferase activity. On a continuous experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed alcohol decomposition activity on the in vivo test using rat. These results suggest that the fruit of Hovenia dulcis Thunb may be useful in the prevention of hangover.

Antioxidant Activities and the Effect of Reducing Serum Alcohol Concentration of Lentinus edodes (표고버섯의 항산화능과 알코올분해능에 미치는 영향)

  • Kim, Chae-Hyun;Jeong, Jong-Gil
    • The Korea Journal of Herbology
    • /
    • v.24 no.4
    • /
    • pp.159-164
    • /
    • 2009
  • Objectives : The purpose of this study is to evaluate antioxidant activities and reducing serum alcohol concentration of extract of Lentinus edodes on the alcohol administered rats. Methods : Antioxidant effect was measured by total phenolic compound and DPPH-radical scavenging activity of extract of Lentinus edodes in vitro. Blood alcohol concentration, aldehyde concentration, malondialdehyde concentration, glutathion concentration were measured in vivo. Results : The extract of Lentinus edodes increased DPPH-radical scavenging activity dose-dependently. The water extract with boiling water showed lower antioxidant activity and phenolic content than 70% ethanol extract in vitro. Blood alcohol concentration was significantly reduced by pre-treatment of ethanol extract of Lentinus edodes. The effect was more significant than commercial product used as a positive control. Conclusions : This study suggest that Lentinus edodes can be a potential nature resource for the management of ethanol toxicity although the mechanism of action involved in the treatment remains to be explored.

Effects of the Artemisia capillaris Extract on the Hepatotoxicity in Ethanol-induced Rats (에탄올 투여 랫트에서 인진쑥 열수 추출물이 간 독성 저하에 미치는 영향)

  • Yu, Keun-Hyung;Lee, Sun-Yeop;Yang, Hyun-Mo;Ham, Young-Ahn;Lee, Soo-Ung;Chae, Seoung-Wan;Lee, Yong-Jin
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.42 no.10
    • /
    • pp.1560-1566
    • /
    • 2013
  • This study was conducted to find out the effects of aqueous extract from the leaves of Artemisia capillaris (AA) on the reduction of hepatotoxicity induced by ethanol in rats. In this experiment, Sprague Dawley rats were used in the experimental groups, which were divided into 5 groups; normal group, ethanol+UDCA (ursodeoxycholic acid)-treated group (positive control), ethanol-treated group (control), ethanol+Artemisia capillaris aqueous extract-treated group (200 mg/kg of BW) and ethanol+Artemisia capillaris aqueous extract-treated group (400 mg/kg of BW). AST (aspartate aminotransferase), ALT (alanine aminotransferase), GGT (gamma(${\gamma}$)-glutamyl transferase) and LDH (lactate dehydrogenase) activities of the ethanol+Artemisia capillaris aqueous extract-treated group (400 mg/kg of BW) were significantly decreased compared to that of the ethanol-treated group (P<0.05). The triglyceride level of the ethanol-treated group was significantly increased and the HDL-cholesterol level was significantly decreased compared to the normal group (P<0.05). On the other hand, the triglyceride level was significantly decreased (P<0.05) and the HDL-cholesterol level was significantly increased (P<0.05) in the ethanol+Artemisia capillaris aqueous extract-treated groups. Superoxide dismutase (SOD) activity was enhanced significantly (P<0.05) in the ethanol+Artemisia capillaris aqueous extract-treated groups. Also, malondialdehyde contents were decreased in this group (P<0.05). Histologically, in the control group, there was a mild degenerative change around central venule. The AA treated group showed well preserved lobular architectures with no evidence of steatosis or liver damage in aqueous extract from the leaves of Artemisia capillaris treated group (H&E, ${\times}20$). As the results of this study, it is thought that Artemisia capillaris aqueous extract may have effects on the improvement of hepatic damage by ethanol.

Quality Characteristics on Enzyme Treatment of Brown Rice(Goami) Alcohol Fermentation By-Product (현미(고아미) 알코올발효 부산물의 효소처리에 따른 품질특성)

  • Jang, Se-Young;Woo, Seung-Mi;Kim, Tae-Young;Yeo, Soo-Hwan;Kim, Sang-Burm;Hong, Ju-Yeon;Jeong, Yong-Jin
    • Food Science and Preservation
    • /
    • v.15 no.3
    • /
    • pp.477-482
    • /
    • 2008
  • The quality characteristics of Goami by-product under the mixed enzyme treatment condition of $\alpha$-amylase and cellulase have been compared, and found the highest amount of soluble solids and reducing sugars at the $\alpha$-amylase treated group (A), and the contents revealed to show gradual decrease with the increase of cellulase content. The amounts of total dietary fiber and total sugars did not show large difference by both of enzyme concentration. The result of sugar analysis revealed the presence of all $G{\sim}G5$ in all treatment groups, and the content of malto-oligosaccharide recorded the highest content of 2,200 mg% at the $\alpha$-amylase treatment group (A). When the quality characteristic of the hydrolyzed powders manufactured by the optimum hydrolysis condition was compared, no significant color difference was found between samples. Among the contents of dietary fibers, insoluble dietary fiber was found to present in the lowest content of 6.95% at the Goami flour (GF) and the Goami by-product powder (GBPP) and Goami by-product hydrolysate powder (GBPHP) resulted the similar content around 14% and the highest soluble dietary fibers content was found in Goami by-product hydrolysate powder (GBPHP), which was followed by in the order of Goami by-product powder (GBPP) and Goami flour (GF), but the content variation was not large. The free amino acid was found to be highest in Goami by-product hydrolysate powder (GBPHP) followed by in the order of Goami by-product powder (GBPP) and Goami flour (GF). In the sugar analysis, the Goami by-product hydrolysate powder (GBPHP) was found with all $G{\sim}G5$ sugars by showing the highest amount of 1,800 mg% At the Goami by-product powder (GBPP), $G{\sim}G2$ sugars were detected with about 66 mg% and malto-oligosaccharides were not detected at the Goami flour (GF). Based upon the results, the functionality of Goami by-product hydrolysate powder (GBPHP) was found to be enforced compared to Goami flour (GF) and Goami by-product powder (GBPP), which allow us to expect it to be used as the various rice processing food source.

Plasma-assisted Catalysis for the Abatement of Isopropyl Alcohol over Metal Oxides (금속산화물 촉매상에서 플라즈마를 이용한 IPA 저감)

  • Jo, Jin Oh;Lee, Sang Baek;Jang, Dong Lyong;Park, Jong-Ho;Mok, Young Sun
    • Clean Technology
    • /
    • v.20 no.4
    • /
    • pp.375-382
    • /
    • 2014
  • This work investigated the plasma-catalytic decomposition of isopropyl alcohol (IPA) and the behavior of the byproduct compounds over monolith-supported metal oxide catalysts. Iron oxide ($Fe_2O_3$) or copper oxide (CuO) was loaded on a monolithic porous ${\alpha}-Al_2O_3$ support, which was placed inside the coaxial electrodes of plasma reactor. The IPA decomposition efficiency itself hardly depended on the presence and type of metal oxides because the rate of plasma-induced decomposition was so fast, but the behavior of byproduct formation was largely affected by them. The concentrations of the unwanted byproducts, including acetone, formaldehyde, acetaldehyde, methane, carbon monoxide, etc., were in order of $Fe_2O_3/{\alpha}-Al_2O_3$ < $CuO/{\alpha}-Al_2O_3$ < ${\alpha}-Al_2O_3$ from low to high. Under the condition (flow rate: $1L\;min^{-1}$; IPA concentration: 5,000 ppm; $O_2$ content: 10%; discharge power: 47 W), the selectivity towards $CO_2$ was about 40, 80 and 95% for ${\alpha}-Al_2O_3$, $CuO/{\alpha}-Al_2O_3$ and $Fe_2O_3/{\alpha}-Al_2O_3$, respectively, indicating that $Fe_2O_3/{\alpha}-Al_2O_3$ is the most effective for plasma-catalytic oxidation of IPA. Unlike plasma-alone processes in which tar-like products formed from volatile organic compounds are deposited, the present plasma-catalyst hybrid system did not exhibit such a phenomenon, thus retaining the original catalytic activity.

Measurement of Flash Point for Binary Mixtures of 2-Butanol, 2,2,4-Trimethylpentane, Methylcyclohexane, and Toluene at 101.3 kPa (2-Butanol, 2,2,4-Trimethylpentane, Methylcyclohexane 그리고 Toluene 이성분 혼합계에 대한 101.3 kPa에서의 인화점 측정)

  • Hwang, In Chan;In, Se Jin
    • Clean Technology
    • /
    • v.26 no.3
    • /
    • pp.161-167
    • /
    • 2020
  • For the design of the prevention and mitigation measures in process industries involving flammable substances, reliable safety data are required. An important property used to estimate the risk of fire and explosion for a flammable liquid is the flash point. Flammability is an important factor to consider when developing safe methods for storing and handling solids and liquids. In this study, the flash point data were measured for the binary systems {2-butanol + 2,2,4-trimethylpentane}, {2-butanol + methylcyclohexane} and {2-butanol + toluene} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a Stanhope-Seta closed cup flash point tester. A minimum flash point behavior was observed in the binary systems as in the many cases for the hydrocarbon and alcohol mixture that were observed. The measured flash points were compared with the predicted values calculated via the following activity coefficient (GE) models: Wilson, Non-Random Two-Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC) models. The predicted data were only adequate for the data determined by the closed-cup test method and may not be appropriate for the data obtained from the open-cup test method because of its deviation from the vapor liquid equilibrium. The predicted results of this work can be used to design safe petrochemical processes, such as the identification of safe storage conditions for non-ideal solutions containing flammable components.

Popping Pretreatment for Enzymatic Hydrolysis of Waste Wood (팝핑 전처리를 이용한 폐목재의 효소당화)

  • Kim, Hyun-Joo;Cho, Eun-Jin;Lee, Kwang-Ho;Kim, Su-Bae;Bae, Hyeun-Jong
    • Journal of the Korean Wood Science and Technology
    • /
    • v.39 no.1
    • /
    • pp.95-103
    • /
    • 2011
  • We have investigated pretreatment of waste wood using milling refinery combined with poping method, which can save energy for pretreatment and enzyme loading for enzymatic hydrolysis. The chemical analysis of holocellulose of non and popping treated waste wood showed 65.9% and 58.8%, and the lignin, organic extracts and ash were increased by 3%, 4% and 0.7% after pretreatment, respectively. The reducing sugar yields of pretreated waste wood were increased four times more than non-pretreated one and the synergistic effect of cellulase and xylanase were evaluated compare with individual enzyme treatment. Especially, enzyme cocktail (cellulase 50 U and xylanase 50 U) treatment was very efficient in 1% substrate (50 mg). Also, glucose and xylose conversion rate of pretreated waste wood by GC analysis were 45.9% and 38.7%, respectively.