• Journal of the Korea Concrete Institute
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• v.17 no.6 s.90
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• pp.1011-1018
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• 2005

The influence of liquid shotcrete accelerators(alkali aluminate, two types of alkali-free) was investigated. Comparing to the existing alkali aluminate accelerator, new alkali-free accelerator, AF2, shortened initial and final setting of cement system, and after curing for 1 day compressive strength was analogous with others. On the other hand, compressive strength of specimen cured for 12 hour was the highest by the addition of alkali aluminate accelerator, but final strength was the lowest by that. But compressive strengths of AF1, AF2 were similar to Plain up to 28day. Further from XRD(X-Ray Diffractometer) and DSC(Differential Scanning Calorimeter) analyses, we confirmed that setting promoted by alkali aluminate was mainly because of Ca(OH)2(calcium hydroxide), but the accelerating behavior of alkali-free was influenced by the needle-like ettringite$(6CaO{\cdot}Al_2O_3{\cdot}3SO_3{\cdot}32H_2O)$ crystal.

• Cement Symposium
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• s.48
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• pp.6-9
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• 2021

• Journal of the Korea Concrete Institute
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• v.19 no.6
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• pp.701-706
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• 2007

This study evaluated the durability of high-performance shotcrete mixed in the proper proportions using alkali-free and cement mineral accelerators as a permanent support that maintains its strength for the long term. Durability tests were performed the chloride permeability, repeated freezing and thawing, accelerated carbonation, and the effects of salt environments. Test results showed that all the shotcrete mixes included silica fume had low permeability. In addition, after 300 freeze/thaw cycles, the shotcrete mix had excellent freeze/thaw resistance more than the 85% relative dynamic modulus of elasticity. The accelerated carbonation test results were no effect of accelerator type but, the depth of carbonation was greater in the shotcrete mix containing silica fume. No damage was seen in a salt environments. Therefore, the high performance shotcrete mix proportions used in this study showed excellent durability.

• Journal of the Korea Concrete Institute
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• v.16 no.1 s.79
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• pp.70-78
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• 2004

Although set accelerating agents are used generally in New Austrian Tunneling Method, the standards for test methods and quality of set accelerating agents are not prescribed domestically. In this study, the proprieties of the various standards and the characteristics of set accelerating agents for shotcrete were evaluated. The alkali contents of set accelerating agents based on silicate, aluminate and cement were higher than those of alkali-free ones. From the result, it is thought that the quality control of aggregate should be enhanced and that the number of test cycle of alkali-aggregate reaction should be increased. The setting times of cement paste with set accelerating agents based on silicate and alkali-free ones were different largely with mixing methods. Compressive strength of mortar with set accelerating agents based on silicate, aluminate and cement at one day satisfied the specifications of Korea Concrete Institute. However, the strength ratio compared to control mix at 28 days showed as $50{\~}65\%$ except for the alkali-free set accelerating agents. As a results of setting time and strength test, the establishment of domestic standards that can reflect the characteristics of materials and construction methods of tunnels and that can increase quality of set accelerating agents is required immediately.

• Journal of the Korea Concrete Institute
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• v.22 no.5
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• pp.633-640
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• 2010

This study was performed to get basic information about properties of high blaine cement for shotcrete use. Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of high blaine cement. Setting time of high blaine cement was shorter and compressive strength was higher than those of ordinary portland cement (OPC). Results of analysis showed early hydration products of high blaine cement is smaller and spread widely due to increased specific surface. From the SEM observation and analysis of DSC and XRD results, it was seen that the aluminates accelerators promoted calcium aluminium hydrates while the alkali free accelerators increased ettringite and monosulfates formation. Strength and setting time measurement of cement paste with aluminate accelerator is more effective than the alkali free accelerator in reducing the setting time and increasing early strength while alkali free accelerator is more effective in increasing the strength after 7 days.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.2C
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• pp.121-131
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• 2006

The strength standard of shotcrete in Korea is relatively lower than that in Europe where high-strength shotcrete has been developed and actively applied to the common practice, so it is hard to test a quality of high-strength shotcrete. In this study, field test was performed to find a solution improving the strength and a long-term durability on domestic shotcrete. In field test, a high-strength shotcrete was produced using high-quality additions and accelerators, and an effect of additions and accelerators was observed. In addition, quality test based on EFNARC was also performed. As a result of field test, a promotion ratio of early strength is 90~97% in case of using alkali-free accelerators, therefore, alkali-free accelerators had an effect on an increase of early strength on shotcrete. A compressive strength of shotcrete using Micro-silica fume was 45.2~55.8MPa and flexible strength was 5.01~6.66MPa, so a promotion ratio of strength was 37~79%, 17~61% respectively. It was showed that increment effect of strength by the silica fume replacement of 7.5~10% for cement mass was remarkable. As a result of test, it was possible to apply high-strength shotcrete to the domestic practice using high-quality additions such as Micro-silica fume and accelerators such as alkali-free.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.323-324
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• 2010

The purpose of this study was to investigate alkali-silica reaction of accelerating agents in shotcrete. The test was performed with accelerating agents (aluminate, alkali-free, cement based mineral admixture) in the Type I cement. As a test result, using the nonreactive aggregates, detrimental expansion due to alkali-silica reaction doesn't occurred regardless of equivalent alkali contents of accelerating agent.

• Magazine of korean Tunnelling and Underground Space Association
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• v.14 no.6
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• pp.59-63
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• 2012

• Journal of Korean Tunnelling and Underground Space Association
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• v.10 no.1
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• pp.59-68
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• 2008

The experiment was carried out to investigate the influence of coarse aggregate, admixture, and accelerator on the properties of concrete. As the maximum size of coarse aggregate decreased from 13 mm to 8 mm, fluidity of fresh concrete declined but compressive strength and dynamic modulus of elasticity of hardened concrete increased remarkably. The mechanical properties of concrete substituted silica fume to the plain concrete improved, the compressive strength of that substituted blast furnace slag increased slightly. The hydration reaction and compressive strength of specimen with sodium luminate type accelerator were high at initial, but specimen with alkali free type accelerator improved largely in 28 days.

• Tunnel and Underground Space
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• v.29 no.6
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• pp.532-541
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• 2019

Even though shotcrete is a main support for securing the stability of tunnel, the performance of shotcrete is not properly checked due to various difficulties arisen from the characteristics of materials themselves which constitute shotcrete, such as steel fibers and accelerators, and the on-site quality control. In this study, the actual conditions of shotcrete applied to expressway tunnel construction sites were tried to find out, and then some improvement was tried to derive. For this purpose, the characteristics of steel fibers and accelerators supplied to the expressway construction sites were investigated. Also, shotcrete specimens were prepared at the tunnel sites and performance tests were carried out. For steel fiber, domestic production states were investigated, and carbon content and tensile strength were measured using the steel fibers collected in the construction sites. For three types of accelerators such as aluminate, cement mineral and alkali-free, basic properties and total amount of alkali contents were analyzed. Shotcrete specimens were prepared using on-site shotcrete machine with regard to mix designs and types of accelerators. Using these specimens, uniaxial compression tests and flexural tests were performed. As the results, compressive strength, flexural strength, flexural toughness, and etc. were compared with types of acclerators and mix designs.