• Title/Summary/Keyword: 알칼리 영향

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Effects of Soluble Alkalis on the Rheological Properties of Belite-rich Cement with Polycarbonate Superplasticizer (폴리카르복실산계 유기 혼화제를 첨가한 Belite-rich Cement의 유동특성에 미치는 가용성 알칼리의 영향)

  • 황인수;정재현;송종택
    • Journal of the Korean Ceramic Society
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    • v.38 no.2
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    • pp.152-157
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    • 2001
  • 본 연구에서는 고유동, 저발열 및 고강도 특성을 발현하는 belite-rich cement(BRC)에 있어서 카르복실산계 유기혼화제를 사용했을 때 가용성 알칼리의 함량 변화에 따른 흡착거동과 유동특성에 미치는 영향성에 대해 검토하였다. BRC에서 알칼리 0.1~0.2 wt% 및 알칼리 설페이트 0.3~0.5 wt% 첨가시 슬럼프가 증가하거나 손실이 거의 없었으며, 그 이상의 함량을 첨가하였을 때 다시 유동서 저하를 가져왔다. 그러나, 보통 포틀랜드 시멘트(OPC)의 슬럼프 유지능력은 알칼리 및 알칼리 설페이트를 첨가할수록 감소되었다.

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The Effect on the Kind of Alkali-Activator of Cement ZERO Mortar (알칼리 활성화제 종류가 시멘트 ZERO 모르타르에 미치는 영향)

  • Ryu, Gum-Sung;Kang, Hyun-Jin;Ko, Kyung-Taek;Kang, Su-Tae;Kim, Sung-Wook;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.397-398
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    • 2009
  • Recently, the research about alkaline activity concrete is being progressed actively. In this paper, the effect of many kinds of alkaline activation to fly ash based cement zero mortar is examined.

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The Effect on the Alkali-Activator Mixture Ratio of fly Ash Mortar (알칼리 활성화제 혼합비가 플라이애시 모르타르에 미치는 영향)

  • Kang, Hyun-Jin;Kang, Su-Tae;Ko, Kyung-Taek;Ryu, Gum-Sung;Park, Jung-Jun;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.395-396
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    • 2009
  • The purpose of this study is to observe the effect of mixture ratio of alkali-activator on workability and compressive strength of alkali-activated mortar that using 100% fly ash.

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The Strength Properties of Alkali-Activated Slag Mortars by Combined Caustic Alkali with Sodium Carbonate as Activator (가성알칼리와 탄산나트륨을 혼합한 활성화제를 사용한 알칼리 활성화 고로슬래그 모르타르의 강도 특성)

  • Kim, Tae-Wan
    • Journal of the Korea Concrete Institute
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    • v.24 no.6
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    • pp.745-752
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    • 2012
  • This paper studies the effect of the compressive strength for combined alkali-activated slag mortars. The effect of activators such as alkali type and dosage factor on the strength was investigated. The alkalis combinations made using five caustic alkalis (sodium hydroxide (NaOH, A series), calcium hydroxide ($Ca(OH)_2$, B series), magnesium hydroxide ($Mg(OH)_2$, C series), aluminum hydroxide ($Al(OH)_3$, D series), and potassium hydroxide (KOH, E series)) with sodium carbonate ($Na_2CO_3$) were evaluated. The mixtures were combined in different dosage at 1M, 2M, and 3M. The study results showed that the compressive strength of combined alkali-activated slag mortars tended to increase with increasing sodium carbonate. The strength of combined alkali-activated slag mortars was better than that of control cases (without sodium carbonate). The result from scanning electron microscopy (SEM) analysis confirmed that there were reaction products of calcium silicate hydrate (C-S-H) and alumina-silicate gels from combined alkali-activated slag specimens.

A Study of Sewage Sludge Solubilization by Alkali and Ultrasonic pretreatment (알칼리처리와 초음파처리를 이용한 슬러지 가용화 연구)

  • Kim, Jae-Hyung;Yang, Hong-Gyu;Lee, Joon-Cheol;Park, Hong-Sun;Choi, Gwang-Geun;Pak, Dae-Won
    • Journal of Energy Engineering
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    • v.20 no.2
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    • pp.84-89
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    • 2011
  • In this study, individual(alkaline, ultrasonic) and combined(alkaline+ultrasonic) pretreatment effect on sewage sludge solubilization was investigated. COD solubilization rates increased with the dose of NaOH added: solubilization reached 27.6%. Additional alkaline agents did not increase solubilization further. Ultrasonic pretreatment achieved 33~39% solubilization when 140 W/L amplitude. In(alkaline(pre-treatment)+ultrasonic (after-treatment)) treatment, solubilization increased as the combined intensity in creased($70.4{\pm}9.4%$). SCOD rising rate(0.076) was achieved.

Effect of the Combined Using of Fly Ash and Blast Furnace Slag as Cementitious Materials on Properties of Alkali-Activated Mortar (결합재(結合材)로 플라이애시와 고로(高爐)슬래그의 혼합사용(混合使用)이 알칼리 활성(活性) 모르타르의 특성(特性)에 미치는 영향(影響))

  • Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Ryu, Gum-Sung;Lee, Jang-Hwa;Kang, Hyun-Jin
    • Resources Recycling
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    • v.19 no.4
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    • pp.19-28
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    • 2010
  • Attempts to increase the utilization of a by-products such as fly ash and blast furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/slag, type of alkaline activator and curing condition on the workability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/slag and the type of alkaline activator always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

Alkali-Silica Reaction of Accelerating Agents in Shotcrete (숏크리트용 급결제의 알칼리-실리카 반응성 검토)

  • Choi, Bo-Ra;Hong, Byung-Tak;Lee, Jae-Wan;Lee, Su-Jin;Park, Hae-Kyun;Won, Jong-Pil
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.323-324
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    • 2010
  • The purpose of this study was to investigate alkali-silica reaction of accelerating agents in shotcrete. The test was performed with accelerating agents (aluminate, alkali-free, cement based mineral admixture) in the Type I cement. As a test result, using the nonreactive aggregates, detrimental expansion due to alkali-silica reaction doesn't occurred regardless of equivalent alkali contents of accelerating agent.

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Studies on Alkali Digestibility of Soybean Seeds and Its Inheritance (콩에 있어서 알칼리 붕괴도와 그의 유전에 관한 연구)

  • Lee, H.S.;Park, E.H.;Lim, B.K.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.29 no.2
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    • pp.179-185
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    • 1984
  • These studies were carried out to evaluate the feasibility of using Alkali Digestibility Value (ADV) of soybean seeds as a selection criterion for cooking quality of soybean grain with rice, and to find out an optimal testing condition, varietal differences in ADV and the effect of cultural environment on the ADV, and its mode of inheritance. The ADV test was achieved succesfully by soaking the soybean grain for 24 hours in 25 to 30% KOH solution at 25 to $30^{\circ}C$. Varietal differences in the ADV were conspicuous, but cultural conditions affected the ADV little. All collected lines for cooking with rice showed high ADV and all the small grain cultivars introduced from abroad had low ADV, while recommended cultivars showed great variation in ADV. The characteristic of low ADV in soybean grains was controlled by single dominant gene.

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Effects of Alkaline Reagent on the Rheological Properties of Wheat Flour and Noodle Property (알칼리제가 밀가루의 리올로지와 국수의 성질에 미치는 영향)

  • Kim, Sung-Kon;Kim, Heung-Rae;Bang, Jung-Bum
    • Korean Journal of Food Science and Technology
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    • v.28 no.1
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    • pp.58-65
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    • 1996
  • The effects of sodium carbonate (Na), potassuim carbonate (K) and their mixtures (Na/K=0.7-2.0) on pasting properties by amylograph and mixing properties by farinograph of wheat flour (9.45% protein), and of alkali mixtures (0.16%) on noodle property were examined. The concentrations of alkali used were 0.08%, 0.10% and 0.16% based on flour weight (14% mb). The salt (1.7%) and alkali decreased the initial pasting temperature but increased the amylograph peak viscosity. The peak viscosity increased with the increase of alkali concentration, but the mixing ratio at a fixed concentration had no effect on peak viscosity. The farinograph absorption decreased by salt, but the effect of salt diminished in the presence of alkali. The salt and alkali increased the farinograph stability, of which the former was more pronounced. The effect of alkali alone and mixtures in the presence of salt on amylograph and farinograph were essentially the same regardless the concentrations and mixing ratios. The yellowness and breaking force of dry noodle prepared with salt and alkali was higher than that prepared with salt only. The weight and volume gain of the optimum cooked noodle remained essentially constant, but the shear force and compression force were increased by the alkali.

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A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction II. Effect of Alkali Metal Salt on the Activity of CoMo Catalyst (황에 저항성을 가지는 수성가스 전환반응 촉매의 연구 II. CoMo 촉매의 활성에 미치는 알칼리 금속염의 영향)

  • Kim, Joon Hee;Lee, Ho In
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.696-702
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    • 1998
  • The effect of alkali metal salt on the activity of Co-Mo catalyst which has high resistance to sulfur poisoning for water gas shift reaction(WGSR) was studied. Two groups of catalysts were prepared to investigate the effects of anion and cation in alkali metal salts. For K-doped catalysts made with various potassium salts having different anion, the catalytic activity was explained to depend mainly on the BET surface area. Among the catalysts prepared by various nitrates of alkali metal as precursor, the Li-doped catalyst showed the best activity, and the others did not make significant differences giving relatively low activities. And the change of BET surface area by varying the loading of alkali metal showed a similar trend to that of activity. In this case, the activity was dependent on both BET surface area and the ratio of $Mo^{6+}$ with a tetrahedral coordination symmetry to $Mo^{6+}$ with an octahedral one, $Mo^6+[T]/Mo^{6+}[O]$ value.

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