• Title/Summary/Keyword: 알칼리 부식

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Present Condition on the Recycling and Management for Waste Alkali (폐(廢)알칼리의 재활용(再活用) 현황(現況) 및 관리(管理) 방안(方案))

  • Sim, Yeon-Ju;Kim, Eui-Yong
    • Resources Recycling
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    • v.19 no.4
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    • pp.13-18
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    • 2010
  • Effort of reducing wastes and their recycling is increasing in worldwide. Especially, extreme care for alkali recycling is required because of its environmental pollution and its corrosive characteristics. In order to manage alkali wastes effectively, it is necessary to make quality standards for recycling products from the alkali wastes because there are no quality specifications yet. In this study, we selected several recycling candidates from the alkali wastes based on the analysis of the most recent data of the various industrial sites. As a result, the recycling candidates from the alkali wastes are sodium hydroxide, aluminum sulfate, poly aluminum chloride. It is believed that the proper management system for waste products is required in governmental point of view and it propagates positively for resolving various environmental issues.

Relationship Between Local Wall Thinning and Velocity Components of Deflected Turbulent Flow Inside the Tee Sections of Carbon Steel Piping (탄소강 배관 티에서 편향 난류유동에 따른 속도성분과 국부감육의 상관관계)

  • Kim, Kyung-Hoon;Hwang, Kyeong-Mo;Kang, Deok-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.7
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    • pp.717-722
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    • 2011
  • The aim of this study is to identify the locations at which local wall thinning occurs and to determine the turbulence coefficients related to local wall thinning. Experiments and numerical analyses of the tee sections of different down-scaled piping components were performed and the results were compared. Numerical analyses of full-scale models of actual plants were performed in order to simulate the flow behaviors inside the piping components. In order to determine the relationship between the turbulence coefficients and the rate of local wall thinning, numerical analyses of the tee components in the main feedwater systems were performed. The turbulence coefficients obtained from the numerical analyses were compared with the local wear rate obtained from the measurement data. From the comparison of the results, the vertical flow velocity component (Vr) flowing to the wall after separating in the wall due to the geometrical configuration and colliding with the wall directly at an angle of some degree was analogous to the configuration of local wall thinning.

Shape Changes of Mg(OH)2 with Different Magnesium Precursors in Low Temperature (전구체에 따른 Mg(OH)2의 저온합성에서 형상변화)

  • Kang, Kuk-Hyoun;Jeong, Sun-In;Lee, Dong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.2049-2054
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    • 2013
  • Recently, magnesium hydroxide ($Mg(OH)_2$) has many applications in various field, due to its outstanding characteristics such as a nontoxic, noncorrosive and thermal stable properties. In this study, different shapes of flower and flake type magnesium hydroxide were synthesized by precipitation method at room temperature using $MgSO_4$, $MgCl_2$ and $Mg(NO_3)_2$ as magnesium sources, NaOH and $NH_3$ as alkaline sources. Influence of synthesis on the morphological characteristics, sizes and shapes of magnesium hydroxide particles, was investigated, such as different precursors and parameters. The shape of magnesium hydroxide depend on magnesium and alkali sources. Average size of flower particle had about $1{\mu}m$, and flake had about 20 ~ 50 nm. The synthesised magnesium hydroxide groups were characterized by XRD, FE-SEM, FT-IR, EDS, PSA and TG.

An Ecochemical Study on Soil Sickness (인삼 연작 장해의 발생 원인 구명을 위한 생태화학적 연구)

  • 이춘영;임선욱
    • Journal of Ginseng Research
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    • v.1 no.1
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    • pp.51-58
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    • 1976
  • The phenomenon of sail sickness in the continuous cropping of ginseng is n serious problem for the cultivation practices and is an unelucidated subject scientifically. Present study is concerned mainly with ecochemical search on the cause of soil sickness in the continuous cropping of ginseng and the obtained results are summarized as follows: The humic substances isolated from both cultivated and uneulvidated soils with ginseng were compared with respect to its IR spectra but any difference which may be causative of sail sickness between them was not detected. In contrast, same saponin-like substances extracted from the ginseng cultivate soil in root tone were detected but not from the uncultivated soil. Presumably. the saponin like substances in the soils are originate) from the ginseng radices and are accumulaetd in root zone year by year, while the interrelation between the root exudate of ginseng and soil sickness is still obscure. According to a survey on the distributive Pattern of microflora in rhizosphere of ginseng radices the number of fungi is relatively diminished with the cul tivation years, while the number of actinomycetes is increased. It is supposed that the soil sickness in the continuous cropping of ginseng has any correlation between the activities of microflora in rhizosphere and the reef exudates.

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Advances of Post-combustion Carbon Capture Technology by Dry Sorbent (건식흡수제 이용 연소배가스 이산화탄소 포집기술)

  • Yi, Chang-Keun
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.140-146
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    • 2010
  • This paper addresses recent status and trends of carbon dioxide capture technologies using dry sorbents in the flue gas. The advantages of dry sorbent $CO_2$ capture technology are broader operating temperature range, less energy loss, less waste water, less corrosion problem, and natural properties of solid wastes. Recently, U.S.A. and Korea have been developing processes capturing $CO_2$ from real coal flue gas as well as sorbents improving sorption capacity to decrease total $CO_2$ capture cost. New class of dry sorbents have been developed such as chemisorbents with alkali metals of which material cost is low, amines physically adsorbed on silica supports, amines covalently tethered to the silica support, carbon-supported amines, polymer-supported amines, amine-containing solid organic resins and metal-organic framework. The breakthrough is needed in the materials on dry sorbents to decrease capture cost.

Corrosion Characteristics by CCPP Control in Simulated Distribution System (CCPP 조절에 따른 모의 상수관로의 부식특성에 관한 연구)

  • Kim, Do-Hwan;Lee, Jae-In;Lee, Ji-Hyung;Han, Dong-Yueb;Kim, Dong-Youn;Hong, Soon-Heon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1249-1256
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    • 2005
  • This study was performed to investigate the efficiency of the corrosion prevention in the simulated distribution system using CCPP(Calcium Carbonate Precipitation Potential) as the anti-corrosive index by adjusting pH, total dissolved solids, alkalinity and calcium hardness in the water treatment pilot process. The materials of the simulated distribution system(SDS) were equiped with same materials of real field water distribution system. CCPP concentrations controlled by $Ca(OH)_2$, $CO_2$ gas and $Na_2CO_3$ in the simulated distribution system and uncontrolled by the chemicals in the general water distribution system were average 0.61 mg/L and -7.77 mg/L. The concentrations of heavy metals like Fe, Zn, Cu ions in effluent water of the simulated distribution system controlled with water quality were decreased rather than the general water distribution system uncontrolled with water quality. In simulated distribution system(SDS), corrosion prevention film formed by CCPP control was observed that scale was come into forming six months later and it was formed into density as time goes on. We were analyzed XRD(X-ray diffraction) for investigating component of crystal compounds and structure for galvanized steel pipe(15 mm). Finding on analysis, scale was compounded to $Zn_4CO_3(OH)_6{\cdot}H_2O$ (Zinc Carbonate Hydroxide Hydrate) after ten months late, and it was compounded on $CaCO_3$(Calcium Carbonate) and $ZnCO_3$(Smithsonite) after nineteen months later.

Study on Properties of Natural Adhesives with Lacquer for Ceramic Conservation (옻을 활용한 토기 복원용 천연 접착재료의 특성 연구)

  • Jeong, Se Ri;Kim, Eun Kyung;Yu, Jae Eun
    • Journal of Adhesion and Interface
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    • v.12 no.4
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    • pp.111-116
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    • 2011
  • The characteristics of natural resin, sap of the lacquer tree were examined as an adhesive for the ceramic conservation since it has such outstanding properties like corrosion resistance against acid and alkali, heat-resistance, waterproof, antiseptic and protection against insects. In order to utilize raw lacquer as an adhesive not under the hardening conditions of lacquer like high humidity (RH 75 to 85%) and high temperature (120 to $170^{\circ}C$), but under normal condition, isinglass and animal glue were added to raw lacquer at certain ratio. In addition, the viscosity and the drying time were measured and their possibilities of application were also investigated through measurement of tensile and adhesive strength. As a result of experiment, it was possible to dry at room temperature and RH $50{\pm}5%$ to mix with raw lacquer and glue, and the drying time of sample with animal glue was faster than that of isinglass. Furthermore, the adhesion of sample with glue was increased more than raw lacquer. It seems to be possible to use the environmental friendly traditional adhesive for the ceramic conservation and restoration, if there are studies or examinations of safety of applications on objects and weathering resistance.

Performance Based Evaluation of Concrete Carbonation from Climate Change Effect on Curing Conditions of Wind Speed and Sunlight Exposure Time (기후변화의 풍속과 일조시간 양생조건에 따른 콘크리트 탄산화 성능중심평가)

  • Kim, Tae-Kyun;Shin, Jae-Ho;Choi, Seung-Jai;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.45-55
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    • 2015
  • Currently, extreme weather events such as super typhoon, extreme snowfall, and heat wave are frequently occurring all over the world by natural and human caused factors. After industrial growth in the 1970s, earth's temperature has risen sharply. due to greenhouse effect. Global warming can be attributed to gases emitted from using fossil fuel such as average carbon dioxide, perfluorocarbons, nitrous oxide, and methane. Especially, carbon dioxide has the highest composition of about 90%. in the fossile fuel usage emitted gas. Concrete has excellent durability as a building material climate change. However, due to various of physical and chemical environmental effect such as conditions during its curing process, the performance degradation may occur. Carbon dioxide in the atmosphere causes steel corrosion and durability decreases by lowering the alkalinity of concrete. Therefore, in this study, concrete durability performance with respect to carbonation from curing conditions change due to wind speed and sunshine exposure time. Concrete carbonation experiment are performed. using wind speed (0, 2, 4, 6) m/s and sunlight exposure time (2, 4, 6, 8) hrs. Also, performance based evaluation through the satisfaction curve based on the carbonation depth and carbonation rate test results are performed.

Occurrence and Cenesis of Perlite from the Beomgockri Group in Janggi Area (장기지역 범곡리층군에 부존되는 진주암의 산출상태와 생성관계)

  • Noh Jin Hwan;Hong Jin-Sung
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.4 s.46
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    • pp.277-288
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    • 2005
  • Perlite, a hydrated volcanic glass, occurs mainly as a bed-like body, and is distributed intermittently along the unconformity surface between the Beomgockri Group and its lower formations, viz. Janggi Group. The perlite is intimately associated with surrounding pumiceous welded tuff and rhyodacites in space and time. Compared to the typical perlite, the perlite is rather silica-poor and impure, and thus, includes lots of phenocrysts and rock fragments. Nearly the perlite is compositionally rather close to a pitchstone than a perlite in water contents. Petrographic comparison between perlite and associated volcanic to volcaniclastic rocks indicates that pumiceous welded tuff and rhyodacite seem to be Protolith of the Perlite. A Zr/$TiO_{2}$-Nb/Y diagram and field occurrence of perlite and their protolithic rocks also conforms the above interpretation. Kn addition, remnant vesicles in perlite strongly reflect that the precursor of perlitic glass appeared to be pumice fragment as well as volcanic glass. The perlite was diagenetically formed by way of a pervasive water-rock interaction at the deposition of the Manghaesan Formation in lacustrine environment. During perlitization, $SiO_{2}$ and alkali tend to be consistently depleted. Preexisting system of the Beomgockri Group based on the perlite formation should be corrected, because the perlite was formed diagenetically without lateral persistence in its occurrence.