• Korean Journal of Materials Research
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• v.11 no.6
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• pp.465-471
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• 2001

The effect of sintering condition on the mechanical properties and leachability of polydispersed ceramic core body made by gel-casting process in aqueous medium have been investigated. The polydispersed ceramic slip that has low viscosity($\leq$1000cP, at 1000cP (at $50sec^{-1}$ ) and high solid loading(50vo1%) was obtained. The green bodies were fabricated through casting and gelation at room temperature followed by drying at $25^{\circ}C$for 48hrs under relative humidity of 80%. Crack-free green body was successfully fabricated through the above process. The strength at room temperature, apparent bulk density, and shrinkage of the ceramic core body increased propotionally with increasing sintering temperature(1100~150$0^{\circ}C$). However, porosity of the ceramic core body showed relatively low vague. Leaching rate of sintered core body increased with increasing porosity of the sintered body, and was significantly dependent upon the concentration of alkali caustic solution at the same leaching temperature.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.3
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• pp.1-10
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• 2012

In spite of high resistant to corrosion and its strength, over the last two decades, concerns still remain about the durability of FRP materials under severe environmental and thermal exposures. In this paper, authors experimentally examine the combined degradation by thermal and chemical attacks in heterogeneous FRP rebar be made up with various fibers and resins. Five types of Carbon, Glass and Hybrid FRP rebars had manufactured by different process and surface patterns are adopted for the experiments such as weight change, interlaminar shear strength, SEM and FT-IR analysis. FRP specimens were immersed in alkaline or distilled solution up to 150 days and then thermal exposed on 60, 100, 150 and $300^{\circ}C$ for 30 minutes. From the test results, the degradation of FRP bars are influnced by the resin type and manufacturing process as well as the fiber, and ILSS of exposed FRP bar in solutions is slightly increased in initial stage and then decresed with the passing of immersed time. But, in this test, it is observed that the discrepancy of ILSS between degraded by alkaline solution and distilled water is negligible value.

• Analytical Science and Technology
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• v.14 no.1
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• pp.80-87
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• 2001

This research was studied the action of the coupling ozone-hydrogen peroxide on aqueous humic acid. PEROXONE process is enhanced the generation of hydroxyl radicals which is effective for degradation of organic matters. Therefore the changes of $UV_{254}$ and TOC were investigated through the change of concentrations, injection time of $H_2O_2$, initial pH of aqueous humic acid and concentrations of radical savenger as $HCO_3{^-}$ in the PEROXONE processes. And the GC/ECD was used to detect the formaldehyde formed by ozonation of humic acid. From the experimental results, concentrations and injection time of $H_2O_2$ and initial pH in solution in the PEROXONE processes were very important for enhancing the efficiency of degradation in humic acid. The results indicated that removal efficiency of TOC was the highest when concentration of $H_2O_2$ was 5mg/L, injection time of $H_2O_2$ was 5 minutes and initial pH in solution was 10.5. And presence of alkalinity in solution was reduced the efficiency of treatment. The formaldehyde were formed less PEROXONE processes than only ozone. When initial pH in solution were changed from 3.5 to 10.5, the formaldehyde were formed highest concentration at pH 5.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.142-142
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• 2016

무전해 니켈 도금은 산업기계 부품, 자동차 부품, 항공 및 전자 통신 부품 등에 이르기까지 산업 전반에서 폭넓게 사용되고 있다. 이는 무전해 니켈 도금 층이 우수한 균일성, 내마멸성, 내식성 등을 지녀 관련 연구가 지속적으로 활발하게 진행되어 왔기 때문이다. 특히, 최근에 이르기까지 도금 층이 얇고, 우수한 내마멸성 및 낮은 마찰계수를 활용한 무전해 니켈 도금은 산업현장에서 기계 부품들의 수명을 연장시키고, 그 성능을 개선시키는데 용이하게 적용되고 있다. 본 연구에서는 이와 같이 무전해 니켈 도금 층의 우수한 특성을 활용하여 해수 부식과 캐비테이션-침식 복합 환경 하에 놓여 있는 금속 재료의 손상을 방지하고자 하였다. 이는 선박의 경우 최근 고속화, 대형화 추세에 따라 부품의 내구성 향상과 연비 효율성이 더욱 강조되고 있으며, 그에 따라 해수 속에서 고속 회전으로 더욱 가혹해진 캐비테이션 침식-부식 환경하에 놓인 선박의 프로펠러, 펌프 임펠러 및 케이싱 등의 금속재료 자체를 보호할 수 있는 고성능 재료의 개발이 요구되고 있기 때문이다. 또한 해양환경 하에서 무전해 니켈 도금 층에 대한 캐비테이션 침식 손상에 대한 연구는 미비한 실정이다. 본 연구에서는 회주철 표면에 무전해 니켈 도금을 실시하여 캐비테이션 침식 손상을 방지하고자 하였다. 무전해 니켈 도금을 실시하기 전 도금 층을 균일하게 형성하기 위해 샌드 페이퍼 #1200까지 연마 후 알칼리 탈지 실시하고, 산세(10% HCl)와 수세를 순차적으로 실시하여 전처리하였다. 이후 무전해 니켈 도금은 황산니켈, 차아인산나트륨, 구연산, 아세트산나트륨 그리고 미량의 질산납으로 구성된 도금욕에서 pH 4-6, $80-90^{\circ}C$의 조건으로 실시하였으며, pH는 NaOH를 이용하여 조정하였다. 이렇게 제작된 무전해 니켈 도금 층에 대하여 천연 해수 속에서 ASTM-G32 규정에 의거한 캐비테이션 침식실험을 통해 내구성을 평가하였다. 캐비테이션 실험 후에는 무게 감소량, 표면 손상깊이, 침식 손상 경향 등을 종합적으로 분석 비교하였다. 그 결과, 회주철에 대하여 무전해 니켈 도금을 실시할 경우 현저한 캐비테이션-침식 저항성 향상이 관찰되었다.

• Journal of Conservation Science
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• v.19
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• pp.57-66
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• 2006

The rock consisting the Naju-Dongmunoi-Seogdanggan (Stone Stele)(Treasure number 49) is biotite granite of medium to coarse grains which might be taken from nearby area. The rock is mainly composed of quartz, plagioclase, alkali feldspar and biotite. Due to strong weathering grail peel-off and surface exfoliation are well developed. The rock surface is changed into pale brown or pale black colors according to weathering, organism and weathering product of iron band. Major deterioration phenomena are grain peel-off, surface exfoliation, cracks and damage which may be originally classified into weathering, effect of weathering product of iron band, organisms, structural unstabilities and impact.

• Corrosion Science and Technology
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• v.11 no.3
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• pp.96-102
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• 2012

Outer diameter stress corrosion cracking (ODSCC) has occurred for Alloy 600 (Ni 75 wt%, Cr 15 wt%, Fe 10 wt%) as a heat exchanger tube of the steam generator (SG) in nuclear power plants (NPP) during long term operation. Among many causes for SCC, lead (Pb) is known to be one of the most deleterious species in the secondary system. In the present work, the oxide formed on Alloy 600 was characterized as a function of the PbO content in 0.1 M NaOH at $315^{\circ}C$ by using an electrochemical impedance spectroscopy (EIS), a transmission electron microscopy (TEM), equipped with an energy dispersive x-ray spectroscopy (EDS). The oxide property was analyzed in view of SCC susceptibility.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.7
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• pp.483-491
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• 2011

When pipe components made of carbon steel in nuclear, fossil, and industry are exposed to flowing fluid, wall thinning caused by FAC(flow accelerated corrosion) can be generated and eventually ruptured at the portion of pressure boundary. A study to identify the locations generating local wall thinning and to disclose turbulence coefficient related to the local wall thinning was performed. Experiment and numerical analyses for tee of down scaled piping components were performed and the results were compared. In particular, flow visualization experiment which was used alkali metallic salt was performed to find actual location of local wall thinning inside tee components. To disclose the relationship between turbulence coefficients and local wall thinning, numerical analyses were performed for tee components. The turbulence coefficients based on the numerical analyses were compared with the local wall thinning based on the measured data. From the comparison of the results, the vertical flow velocity component(Vr) flowing to the wall after separating in the wall due to the geometrical configuration and colliding with the wall directly at an angle of some degree was analogous to the configuration of local wall thinning.

• Journal of Conservation Science
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• v.6 no.2 s.8
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• pp.141-148
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• 1997

When we have entered high economic growth since 1970s, many archaeological excavations were performed all over the country. Excavated objects composed of variable materials are inevitably subjected to deformations owing to surrounding environments and storage conditions. Although the importance of conservation treatment of the objects is greatly increased, a few conservation laboratories are there comparing with excavation groups. The metallic objects excavated are very unstable and deformable state. So it is important not to allow iron objects, especially cast iron, to dry out once excavated. Because the corrosion reactions on the surface proceed rapidly, the objects may be destroyed at the moment. The conservation procedures of the excavated metallic objects are as follows: (1)It is stable on-site storage method for objects to keep vinyl film with envelop or to immerse alkaline solution to prevent the environmental changes. (2)The objects must be treated at once under suitable methods in the conservation laboratory after excavation. (3)The continued existence of objects depends on environmental factors such as relative humidities, regular inspection, light etc.

• Journal of Conservation Science
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• v.37 no.2
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• pp.179-189
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• 2021

In this study, the research objects are gilt plated silver-iron nails excavated from the west of the tombs in Neungsan-ri, Buyeo. A gilt plated silver-iron nail was fabricated by combining silver and iron via heating and then gilding amalgam on top of this combination, demonstrating that this ancient artifact that can be replicated using current technology. Since the metal (Au, Ag) surface of these gilt plated artifacts are covered with iron oxide, which slips into the cracks and scratches of the artifacts as well, desalination is essential. Based on the results of the preliminary experiment, the research objects were classified into grades A, B, and C, according to the degree of corrosion and then desalinated using an alkali solution (NaOH, Sodium Sesquicarbonate of 0.1 M) at 60℃. The results demonstrate that the more serious is the degree of corrosion, the more is the amount of Cl^- detected. Further, more Cl^- was released when NaOH was used than when sodium sesquicarbonate was used, for all grades except Grade A. Furthermore, the more serious is the degree of corrosion, the longer is the desalination period and the reaction with NaOH for all grades except Grade A. A comparison of the Fe composition of the surface before and after desalination shows that Fe composition is the use of NaOH resulted in a smaller increase compared with the use of sodium sesquicarbonate, for all grades except Grade B. However, four of the nails were damaged owing to NaOH (Grade B 3ea, Grade C 1ea) during desalination. Thus, Cl^- ions are more stably released when sodium sesquicarbonate is used than when NaOH is used.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.139-139
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• 2018

최근 자동차 산업을 중심으로 한 수송용 기기의 경량화 추세에 따라 대표적인 경량금속 소재인 알루미늄 합금에 대한 수요가 증가하고 있으며 이에 따라 알루미늄 합금 표면에 다양한 특성을 부여할 수 있는 표면개질 기술에 대한 필요성이 부각되고 있다. 알루미늄 합금의 대표적인 표면처리기술인 아노다이징과 유사한 원리로 표면에 세라믹 코팅층을 형성할 수 있는 기술인 플라즈마 전해 산화(Plasma electrolytic oxidation, PEO)가 주목을 받고 있다. PEO 코팅법은 전해액 내에 소재를 침지시키고 400 ~ 600V에 이르는 고전압을 인가시켜 마이크로 방전을 유도하여 표면에 치밀한 세라믹 층을 형성시키는 기술이다. 본 연구에서는 PEO법으로 표면 개질된 Al 합금 표면의 표면 조직 특성과 전기화학 특성을 평가하고, 코팅층 특성에 미치는 공정 변수의 영향을 분석하고자 하였다. PEO 처리를 위해 사용된 소재는 상용 Al 합금 판재(Al 5083-O)로서 $2cm{\times}2cm$로 절단하여, 에머리페이퍼로 1000번까지 연마하여 사용하였다. 시험을 위한 PEO 처리 시스템은 전해액 수조, 일정 온도 유지를 위한 열교환기와 칠러, 전원 발생을 위한 전원공급기(power supply)로 구성되었다. 전해액은 약 알칼리 수용액을 이용하였으며, 전원 공급기를 통해 시험편에 펄스 전류를 인가하였다. PEO 처리 후 시편에 대하여 SEM, EDS, XRD 등을 이용한 표면 특성 평가를 실시하였다. 또한 코팅층의 전기화학적 부식 특성 평가를 위해 해수용액에서 동전위분극실험을 실시하였다. 시험 결과, Al 합금의 PEO 처리 시 내식성은 개선되는 것으로 확인되었으며, 공정변수는 표면의 미세조직 및 전기화학적 특성에 큰 영향을 미치는 것으로 나타났다.