• Journal of odor and indoor environment
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• v.17 no.4
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• pp.381-388
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• 2018

In this study, various conditions and phenomena that occur in the process of removing odorous VOCs by using electrolyzed oxidant were examined. The formation of hypochlorous acid, which is an oxidant produced by electrolysis, was investigated and the properties of the oxidizing agent used to decompose toluene, xylene, and cyclohexane were investigated. As a result, it was found that the production rate and the final concentration of the oxidizing agent increased with the current density. It was found that the degree of removal varies depending on the property of each pollutant. Interestingly, in the batch experiments in which the pH of the produced oxidant was controlled, it was found that the degree of elimination varied depending on the pH of the substance. These results suggest that the difference in the concentration and distribution of hypochlorous acid (HOCl) and hypochlorite ($OCl^-$) due to the pH change leads to the difference in oxidizing power on the oxidation characteristics of each substance. Styrene and terpineol showed better degradation characteristics than toluene and xylene in odorous VOC removal experiments by spraying electrolytic oxidant using a lab-scale continuous reactor. In conclusion, the removal of odorous VOCs by the electrolytic oxidant can have various applications in that it can oxidize pollutants of various spectra.

• Textile Coloration and Finishing
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• v.32 no.4
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• pp.232-238
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• 2020

Duck down is a feather of waterfowl and is used as an accessory for bedding products such as evil, pillow and outdoor sleeping bags due to its soft and bulky characteristics. Down is used mainly for winter outdoor such as padding and jumpers because of its excellent thermal insulation effect. Down wear is known as a product with high added value. Down is processed and sanitized because a large amount of oil and fat, bacteria, dust, insects, and soil are mixed. In particular, if the proper amount of oil and fat is not removed, it may cause odor or bacteria, and since the fishy smell peculiar to down and harmful VOCs (toluene, benzene, etc.) are released, there is a need to suppress the occurrence of bacteria through the provision of antibacterial function. In this study, we investigated the substances that cause the fishy odor of down, and confirmed the effect on the deodorization and antibacterial properties of down according to processing agents and processing conditions in order to impart deodorant and antibacterial properties to down.

• Journal of Korea Soil Environment Society
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• v.4 no.3
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• pp.57-65
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• 1999

Generation of gaseous ammonia has been a major problem in composting facilities. Microbial inocula. KMT-199(brand name: CompoBac$^{TM}$). was developed in INBI0NET CORPORATION and tested in the field for its ammonia reducing capability. When KMT-199 was applied. a ten-fold increase of mesophilic and thermophilic microorganisms was observed during the early stage of composting process. Also. the temperature and pH of early stage compost increased at a higher rate when compared to control. KMT-199 treated compost reached highest temperature of $75^{\circ}C$at day 9, indicating treatment could shift the maximum composting temperature to 3 days earlier The highest temperature also reached $3^{\circ}C$ higher than the control. The pH of compost gradually increased during composting. KMT-199 treated compost reached a plateau of pH 9.32 at day 15 after treatment, and then slowly decreased thereafter. On the other hand. pH of the control steadily increased until day 38 of composting. 29% reduction of gaseous ammonia generation during composting was observed compared to that of the control. KMT-199 amended compost resulted in a higher germination rate of radish seeds than the control. These results indicate that application of microbial inocula facilitates degradation of organic materials, including ammonia during the composting process.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.63-63
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• 2003

플라즈마 공정은 DRAM, 이종접합 양극성 트랜지스터(HBTs), 레이저, 평면도파로(planar lightwave circuit)와 같은 전자소자 및 광조자 제작에 있어서 핵심 공정중의 하나이다. 최근 미세 구조의 크기가 극도로 감소하게 됨에 따라 실제 소작 제작에 있어서 미세한 모양을 식각하는 공정이 매우 중요하게 되었다. 그 중에서 고밀도 유도결합 플라즈마(high density inductively coupled plasma)를 이용한 기술은 빠르고 정확한 식각률, 우수한 식각 균일도와 높은 재현성 때문에 습식식각 기술보다 선호되고 있다. 본 연구는 평판형(planar) 고밀도 유도결합 플라즈마 식각장치를 이용하여 BCl$_3$와 BCl$_3$/Ar 플라즈마에 따른 AlGaAs/GaAs의 식각결과를 비교 분석하였다. 공정 변수는 ICP 소스(source power)파워, RIE 척(chuck) 파워, 공정 압력, 그리고 Ar 조성비(0-100%)이었다. BCl$_3$에 Ar을 첨가하게 되면 순수한 BCl$_3$ 플라즈마에서의 AlGaAs/GaAs 식각률(> 3000 $\AA$/min) 보다 분당 약 1000$\AA$ 이상 높은 식각률(>4000 $\AA$/min)을 나타내었다. 이 결과는 Ar 플라즈마의 이온보조(ion-assisted)가 식각률 증가에 기인한다고 예측된다. 그리고 전자주사 현미경(SEM)과 원자력간 현미경(AFM)을 사용하여 식각 후 표면 거칠기 및 수직 측벽도 둥을 분석하였다. 마지막으로 XPS를 이용하여 식각된 후에 표면에 남아 있는 잔류 성분 분석을 연구하였다. 본 결과를 종합하면 BCl$_3$에 기초한 평판형 유도결합 플라즈마는 AlGaAs/GaAs 구조의 식각시 많은 우수한 특성을 보여주었다.79$\ell/\textrm{cm}^3$, 0.016$\ell/\textrm{cm}^3$, 혼합재료 2는 0.045$\ell/\textrm{cm}^3$, 0.014$\ell/\textrm{cm}^3$, 혼합재료 3은 0.123$\ell/\textrm{cm}^3$, 0.017$\ell/\textrm{cm}^3$, 혼합재료 4는 0.055$\ell/\textrm{cm}^3$, 0.016$\ell/\textrm{cm}^3$, 혼합재료 5는 0.031$\ell/\textrm{cm}^3$, 0.015$\ell/\textrm{cm}^3$, 혼합재료 6은 0.111$\ell/\textrm{cm}^3$, 0.020$\ell/\textrm{cm}^3$로 나타났다. 3. 단일재료의 악취흡착성능 실험결과 암모니아는 코코넛, 소나무수피, 왕겨에서 흡착능력이 우수하게 나타났으며, 황화수소는 펄라이트, 왕겨, 소나무수피에서 다른 재료에 비하여 상대적으로 우수한 것으로 나타났으며, 혼합충진재는 암모니아의 경우 코코넛과 펄라이트의 비율이 70%:30%인 혼합재료 3번과 소나무수피와 펄라이트의 비율이 70%:30%인 혼합재료 6번에서 다른 혼합재료에 비하여 우수한 것으로 나타났으며, 황화수소의 경우 혼합재료에 따라 약간의 차이를 보였다. 4. 코코넛과 소나무수피의 경우 암모니아가스에 대한 흡착성능은 거의 비슷한 것으로 사료되며, 코코넛의 경우 전량을 수입에 의존하고 있다는 점에서 국내 조달이 용이하며, 구입 비용도 적게 소요되는 소나무수피를 사용하는 것이 경제적이라고 사료된다. 5. 마지막으로 악취제거 미생물균주를 접종한 소나무수피 70%와 펄라이트 30%의 혼합재료를 24시간동안 장기간 운전

• Journal of the Korea Academia-Industrial cooperation Society
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• v.7 no.3
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• pp.431-439
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• 2006

A lot of particulate matter and an offensive odor are emitted during the operations of an industrial waste incinerator (IWI), especially pre_treatment and waste input processes. These pollutants affect the labor efficiency of an operator. Therefore, in this study. we have studied the improvement of working surroundings in the industrial waste incinerator by designing a new control system. A computational fluid dynamics has been used to find the diffusion flows of air pollutants (mainly particles and odor) to the working surroundings of the waste treatment complexes. The results obtained from the simulation analysis applied to the basic design on the points (and/or site) and types of pollution control devices. When pollutant control devices are constructed, the concentration of each pollutant at site 1 and 2 decreased about 83-97% for toluene, 48-72% for styrene, 75-87% for xylene, and 23-36% for ammonia, respectively. In addition, the PM-10 and TSP were decreased about 87% and 86% at site 3 (lower part of the waste input), 87% and 85% at site 4 (side part of the waste input), respectively. These indicated that the new control system had an excellent performance of particulate matter and odor removal and it could be applied to other waste treatment plant in place of an industrial waste incinerator.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.11
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• pp.965-974
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• 2009

This study evaluated the degradation efficiency of malodorous sulfurized-organic compounds by utilizing N- and Sdoped titanium dioxide under visible-light irradiation, and examined the catalyst deactivation and regeneration. Catalyst surface was characterized by employing Fourier-Transform-Infrared-Red (FTIR) spectra. The visible-light-driven photocatalysis techniques were able to efficiently degrade low-level dimethyl sulfide (DMS) and dimethyl disulfide (DMDS) with degradation efficiencies exceeding 97%, whereas they were not effective regarding the removal of high-level DMS and DMDS, with degradation efficiencies of 84 and 23% within 5 hrs of photocatalytic processes. As compared with DMS, DMDS which containes one more sulfur element revealed quick catalyst deactivation. Catalyst deactivation was confirmed by the equality between input and output concentrations of DMD or DMDS, the obsevation of no $CO_2$ generation during a photocatalytic process, and the FTIR spectrum peaks related with sulfur ion compounds, which are major byproducts formed on catalyst surfaces. The mineralization efficiency of DMS at 8 ppm, which was a peak value during a photocatalytic process, was calculated as 144%, exceeding 100%. The catalyst regenerated by high-temperature calcination exhibited higher catalyst recovery efficiency (53 and 58% for DMDS and DMS, respectively) as compared with dry-air and humid-air regeneration processes. However, even the calcined method was unable to totally regenerate deactivated catalysts.

• Journal of Animal Environmental Science
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• v.11 no.1
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• pp.1-10
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• 2005

This study was carried out to measure the environmental related parameters from two types of swine houses. Indoor temperature, relative humidity, carbon dioxide level, ammonia concentration and emission were measures every 2 minutes from each house with portable monitoring units. Carbon dioxide concentration balance was used to estimate the ventilation rates of the different houses. Daily ammonia concentrations in the growing-finishing and farrowing houses ranged from 2 to 17 ppm and 6 to 15 ppm respectively. The daily ammonia emission rate from the manure averaged 4.37 g/h$\cdot$500 kg from growing-finishing house and 4.82 g/h$\cdot$500 kg from the farrowing house. The above findings proved that summer season was associated with higher ammonia emission rates due to higher ventilation rate and ambient air temperature.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.431-431
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• 2016

J 호소는 1942년도에 충청남도 아산시 선장면에 설치된 농업용 저수지로서, 현재 COD, TN, TP 모두 등급외의 수질상태를 보이고 있다. J 호소 상류 유역은 축산농가가 다수 위치하고 있으며, 설치된 지 70년이 지난 노후화된 저수지로 고농도의 오염물질 유입뿐만 아니라 호소 바닥의 오염 퇴적물에 의한 내부 부하가 중요한 수질오염원이 되고 있다. 호소의 수질은 현재 COD 10.6~16.5 mg/L, Chl-a $75mg/m^3$ 이상으로 수질오염도가 매우 높으며, 특히 늦봄에서 초가을까지 외기온도 상승 및 저수율 저하와 함께 부영양화 증가, 녹조 대발생 등으로 호 내 물고기 대량 폐사 및 악취발생 등으로 민원이 다수 발생하고 있다. 이러한 현상의 직접적인 원인은 수중의 DO 농도 결핍이며, 따라서 수중의 DO 농도를 일정수준 이상으로 유지시켜 주는 것은 호소 수질관리를 위해 매우 필요하다고 판단된다. 본 연구에서는 공기 중의 산소를 호소 수체에 포기시켜 주는 마이크로버블 발생장치를 J 저수지에 설치하여 수체의 DO 농도 변화 등을 분석하였고, 본 연구결과는 농업용 호소의 수질개선을 위한 기술개발 및 계획수립의 기초자료로 활용하고자 하였다. 마이크로버블 포기장치는 수심이 약 4m 되는 저수지 제방 근처에 100m 간격으로 총 3지점에 설치하였다. 버블 발생기는 기액 2상류 선회형 마이크로 버블 발생장치로 3지점에 각 1set(1set에 3기로 구성)씩 구성하여 저수지 바닥 층에서 상부로 1m 떨어진 지점에 고정식으로 설치하였다. 총 공기흡입량은 380 LPM이며, 사용동력은 12.2kW를 사용하였다. 마이크로 버블 포기장치 설치 후 호 내 DO 농도 변화를 평가하기 위하여 호소 전체에 18개 지점을 선정하여 수심 50cm 간격으로 DO 농도를 측정하였다. 가동 전에는 DO 평균농도가 표층에서는 약 7.7mg/L로 나타났고, 수심에 따라 거의 수직적으로 감소하여 바닥층에서는 약 0.2mg/L로 거의 무산소 상태를 보이고 있었다. 마이크로 버블 가동 2주 후에는 수심 3m까지의 모든 수층에서 DO 농도가 약 6.0mg/L 이상을 보였고, 바닥층에서는 DO 약 3.4mg/의 농도를 나타내었다. 가동 3주 후에도 2주 후와 비슷한 수치를 보이고 있었으나 가동 4주가 지나면서부터는 호소 바닥층(수심 3.5m)에서도 DO 농도가 7.0mg/L 이상의 높은 농도를 유지하는 것으로 조사되었다. 호소 저층에서 호기성 상태의 지속적 유지는 퇴적 오염물질이 수층으로 용출되는 것을 예방할 수 있으므로 마이크로버블을 잘 활용하면 호소의 악취제거 및 수질개선에 많은 도움이 될 것으로 판단된다.

• Environmental and Resource Economics Review
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• v.30 no.3
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• pp.365-393
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• 2021

Using the Choice Experiment Method, this paper identified whether subsidy to the household around landfil in Seoul metropolitan area is being provided corresponding to the scale of the environmental damage. Since 2001, the subsidy program has been operating for nearly 20 years to compensate for various environmental damage (foul odor, noise, air pollution, water pollution, etc.) from landfill site in the metropolitan area, but it is not clear on what ground the subsidy is allocated. This paper estimated the marginal WTP by attribute (odor, noise, air pollution, and water pollution) based on mixed logit model and compared them with current subsidy level per household in each town. As a result of the comparison, it was found that the subsidy for each town was not allocated in proportion to the amount of the marginal WTP for each household in the corresponding town. In addition, this paper constructs a level-by-level scenario for environmental improvement attributes and compares economic benefits and current subsidy levels. As a result, the current subsidy level is insufficient compared to the level at which environmental damage is completely eliminated, but excessive subsidy is allocated compared to partial improvement levels.

• Applied Biological Chemistry
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• v.37 no.4
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• pp.303-309
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• 1994

To develop the treatment process of swine wastewater using Rhodopseudomonas palustris KK14 with high utilizable ability of organic acids, some operating conditions were investigated and optimized in flask-scale and laboratory-scale reactors. The optimal operating conditions in photosynthetic bacteria (PSB) reactor of semi-continuous type were obtained at HRT 6 day, 5% (v/v/day) seeding rate of PSB sludge and 10% (v/v/day) returning rate of PSB return sludge. Under the above operating condition, COD level of the wastewater (initial COD: 10 g/l) was reduced to about 1.7 g/l after 4 days treatment and MLSS was held constant at $4{\sim}5\;g$ per liter. In laboratory-scale process consisted of 5.2 l anaearobic digestion reactor and 15 l PSB reactor, the total removal rates of COD and BOD were increased to 95% and 96% by the continuous operation for 5.36 days, respectively, showing $3kg\;COD/m^3/day$ COD loading rate and 1.1 Kg COD/Kg MLSS/day sludge loading rate in PSB reactor. The offensive odor was considerably removed through the treatment process of swine wastewater.