• Title/Summary/Keyword: 아연볼

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A Study on the Removal of Nitrate Nitrogens by Redox Reaction of Zinc Ball (아연볼의 산화·환원 반응을 통한 연속식 질산성질소 처리에 관한 연구)

  • Kim, Joon Hwan;Kim, Jong Hwa;Song, Ju Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.487-494
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    • 2017
  • Since nitrate nitrogen is quite stable in aqueous solution, considerable skill is required to remove it. Low concentrations of nitrate nitrogen are easily removed, while high concentrations of nitrate nitrogen are difficult to remove. This study is to show that nitrate nitrogen in the form of gaseous nitrogen can be removed by using zinc ball with a diameter of about 3mm and to test the removal characteristics of nitrate nitrogen under various reaction conditions. As a result of this study, the treatment efficiency of nitrate nitrogen by continuous treatment with zinc ball was about 80%. However, there is a problem that the wastewater must be maintained in an acidic atmosphere of about pH 2, and the treated wastewater must be neutralized and discharged.

The studies on synthesis of aluminum oxide and boron oxide co-doped zinc oxide(AZOB) powder by spray pyrolysis (분무열분해법(Spray Pyrolysis)에 의한 알루미늄 산화물과 보론 산화물이 함께 도핑된 산화아연(AZOB: $Al_2O_3$ and $B_2O_3$ Co-doped Zinc Oxide)의 분말 제조에 대한 연구)

  • Kim, Sang Hern
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.731-739
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    • 2014
  • Aluminum and boron co-doped zinc-oxide(AZOB) powders as transparent conducting oxide(TCO) were prepared by spray pyrolysis at $900^{\circ}C$. The micron-sized AZOB particles were prepared by spray pyrolysis from aqueous precursor solutions for aluminium, boron, and zinc. The micron-sized AZOB particle after the spray pyrloysis underwent post-heat treatment at $700^{\circ}C$ for 2 hours and it was changed fully to nano-sized AZOB particle by ball milling for 24 hours. The size of primary AZOB particle by Debye-Scherrer Equation and surface resistance of AZOB pellet were measured.

Relationship of Low Blood Cadmium and Zinc to Blood Pressure (저농도 혈중 카드뮴과 아연이 혈압에 미치는 영향)

  • Lee, Duk-Hee;Kim, Doo-Hie
    • Journal of Preventive Medicine and Public Health
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    • v.25 no.2 s.38
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    • pp.148-156
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    • 1992
  • A case-control study was conducted to investigate the relationship between blood cadmium, blood zinc and cadmium/zinc ratio and hypertension. Eighty-three hypertensive and seventy-seven normotensive study subjects matched for age and sex were selected from the workers who had no history of job-related cadmium exposure, in Ulsan city and it's vincinity, Korea. The blood cadmium in hypertensive group was $2.90{\eta}g/mL$, which was significantly higher than that of control group, $1.99{\eta}g/mL$(P<0.01). After stratifing for smoking and age variables, the relationship was still remained. The blood cadmium/zinc ratio in hypertensive group was 2.46, which was significantly higher than that of control group, 1.65(P<0.01), After stratifing for smoking and age variables, the relationship was still remained. There was no significant differance in blood zinc between hypertensive and control group. On multiple logistic regression analysis, the blood cadmium/zinc ratio is highly significant than blood cadmium. In conclusion, there is the possible relationship between blood cadmium level which has been known to be within normal limits and hypertension. But, futrher cohort studies to define the effect of cadmium on human hypertension are required.

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Feasibility Study on Acid-enhanced Electrokintic Remediation of Zn and Ni-contaminated Soil (Zn와 Ni로 오염된 토양의 산을 이용한 전처리 및 산순환 동전기 정화의 타당성 연구)

  • Park, Sung-Woo;Cho, Jung-Min;Ryu, Byung-Gon;Kim, Kyung-Jo;Baek, Ki-Tae;Yang, Jung-Seok
    • Journal of Soil and Groundwater Environment
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    • v.13 no.6
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    • pp.17-22
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    • 2008
  • The feasibility of acid-enhanced electrokinetic remediation on zinc and nickel-contaminated soil was investigated in the laboratory. Simple extraction efficiency using 1M HCl was 24% for Zn and 9% for Ni, as a result, the acid washing is not effective to remove Zn and Ni from the soil. The effiencey of normal electrokinetic treatment during 28 days was less than simple soil washing. Catholyte circulation with a strong acid enhanced dramatically the removal of Zn and Ni and pretreatment of soil with acid increased more the removal. Based on the result, acid-enhanced electrokinetic remediation is effective to remove Zn and Ni from the contaminated soil.

Effects of Dietary Protein and Calcium Levels on Iron and Zine Balance in Young Korean Women (한국 젊은 여성의 단백질 및 칼슘 섭취 수준이 체내 철분 및 아연 평형에 미치는 영향)

  • 남기선;김경원;구재옥;최혜미
    • Korean Journal of Community Nutrition
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    • v.3 no.2
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    • pp.218-227
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    • 1998
  • This study was performed to investigate the effects of dietary protein and calcium levels on iron and zinc balance in eight healthy Korean young women. The 20-day metabolic study consisted of a 2-day adaptation period followed by three 6-day experimental periods. Three experimental diets were the low protein-low calcium(LProLCa ; protein 44g, Ca 422mg), the high protein-low calcium(HProLCa ; 'protein 85g, Ca 365mg) and the high protein-high calcium (HProHCa ; protein 84g, Ca 727mg). Apparent absorption and balance of iron and zinc were significantly higher when subjects were fed high protein-low calcium diet than low protein-low calcium diet. The elevation of dietary calcium significantly depressed the apparent absorption of iron and zinc. The levels of serum iron and zinc were likely to be increased with a high protein diet, but the differences were not significant. There was a strong correlation(r=O.99) between the iron intake and serum iron concentration. Serum zinc concentration was not correlated with hair zinc. Study results revealed that the levels of dietary protein and calcium influence iron and zinc balance in Koreans. This study suggests that dietary recommendations for trace minerals, such as iron and zinc, should be carefully examined. In addition, there is a need to evaluate the bioavailability of milk or beverage products enriched with calcium and iron.

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Increase of Visual sensitivity by Zinc, Taurine, and Hypothermic-effect in Bullfrog's Eye (황소개구리 안구에서의 아연, 타우린, 저온효과에 의한 시각 감수성 증진)

  • Kim, Hyun Jung
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.1
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    • pp.23-33
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    • 2007
  • It has been reported high concentrations of zinc and taurine in ocular tissue, especially the retina-choroid, and the presence of physiological levels of zinc and taurine in these tissues seem essential for their normal function. In addition, several studies have reported temperature as another effector to the visual sensitivity. But, in spite of many studies, there are still remained many questions about their function and correlation in visual adaptation system. The purpose of present study was to clarify these points using electroretinogram(ERG) recording and absorption spectra scanning, before and after zinc and taurine treatments and hypothermic-effect in bullfrog(Rana catesbeiana) which is one of the poikilothermal animal. The optimal zinc concentration used in this study was determined $10^{-4}M$ while the optimal taurine concentration was 10-5 M, and temperature change for hypothermic-effect went through '$25^{\circ}C {\rightarrow}0^{\circ}C{\rightarrow}25^{\circ}C$'. In ERG recording, it is obtained that dark-adapted threshold became elevated and b-wave amplitudes was increased with zinc and taurine treatment and hypothermic-effect. In absorption spectra scanning, there is distinct absorbance increment over the whole spectral range(400~750 nm) after zinc and taurine treatment and hypothermic-effect. Furthermore there are some synergism effects between zinc and taurine as well as between zinc and hypothermic-effect as a result of co-treatment, respectively.

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Cathodic Protection Characteristics and Effective Length of Protection Current of Concrete Pile using Zn-mesh Sacrificial Anode (아연 메쉬 희생양극을 이용한 콘크리트 파일의 음극방식 특성 및 방식전류 유효거리)

  • Kim, Ki-Joon;Jeong, Jin-A;Lee, Woo-Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.773-776
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    • 2008
  • The corrosion of steel in concrete is significant in marine environment. Marine bridges are readily deteriorated due to the exposure to marine environment. Salt damage is one of the most detrimental causes to concrete bridges and port structures. Especially, the splash and tidal zones around water line are comparatively important in terms of safety and life-time point of view. During the last several decades, cathodic protection (cp) has been commonly accepted as an effective technique for corrosion control in concrete structures. Zn-mesh sacrificial anode has been recently developed and started to apply to the bridge column cp in marine condition. The detailed parameters regarding Zn-mesh cp technique, however, have not well understood. This study is to investigate how much Zn-mesh cp influences along the concrete column at elevated temperature. About 100cm column specimens with eight of 10cm segment rebars have been used to measure the variation of cp potential with the distance from Zn-mesh anode at both 10$^{\circ}$C and 40$^{\circ}$C in natural seawater. The cp potential change and current diminishment along the column specimens have been discussed for the optimum design of cp by Zn-mesh sacrificial anode

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Dietary zinc supplementation in high-fat diet-induced obese mice: Effects on the skeletal muscle ZIP7 expression and blood glucose regulation (고지방식이 유도 비만 마우스에서 아연 보충이 골격 근육의 아연 수송체 ZIP7 수준과 혈당 조절에 미치는 영향)

  • Zhu, Qianjing;Chung, Jayong
    • Journal of Nutrition and Health
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    • v.54 no.6
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    • pp.594-602
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    • 2021
  • Purpose: The zinc transporter ZIP7 is known to regulate glucose metabolism in skeletal muscles, and skeletal muscles are known to play a critical role in glycemic control. The present study examines the effects of dietary zinc supplementation on the blood glucose concentration and expression of ZIP7 in skeletal muscle obtained from obese mice fed a high-fat diet (HF). Methods: C57BL/6J male mice were divided into three groups and were administered either a HF (60% of total calories from fat), HF supplemented with zinc (HF+Zn, 60% calories from fat + 300 mg zinc/kg diet), or low-fat diet (CON, 10% calories from fat), for 15 weeks. Results: Compared to CON group mice, the final body weights and adipose tissue weights were significantly increased, while the skeletal muscle weights were significantly decreased in mice belonging to the HF and HF+Zn groups. The HF+Zn group had significantly lower levels of fasting blood glucose concentrations than the HF group. Similarly, zinc supplementation significantly decreased the HF-elevated area under the curve values obtained from the oral glucose tolerance test. Skeletal muscle protein levels of ZIP7 in samples obtained from the HF group were significantly decreased as compared to the CON group. Conversely, the skeletal ZIP7 protein levels in the HF+Zn group were significantly increased as compared to the HF group. Moreover, the protein levels of phosphorylated-AKT and glucose transporter 4 in the skeletal muscle were significantly increased subsequent to zinc supplementation. Conclusion: Our data demonstrates that zinc supplementation up-regulates the skeletal muscle ZIP7 expression, which is associated with improved glucose tolerance in the obesity.

Composting Methods for Pig Sludge and the Stabilized Investigation of Crop Cultivation (돈분의 자원화 퇴비 제조 방법 및 작물 재배 안전성 검정)

  • Oh, Tae-Seok;Kim, Chang-Ho
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.29 no.1
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    • pp.51-62
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    • 2009
  • This study was carried out development a new composting system to lower copper and zinc concentration in plg sludge compost and conduct an inquiry into the possibility of crop cultivation. The concentrations of nitrogen, phosphorus and pH averaged 4.4%, 6.3% and 7.57, respectively, which were higher concentrations than in commercial organic fertilizers, and the concentrations of copper and zinc averaged 805 and 1,704 mg/kg, respectively, which were beyond the heavy metal concentration limit in byproduct compost. Hydrated citric acid I lowered the concentrations of copper and zinc by 58% and 97%, respectively and hydrated oxalic acid II lowered the concentrations of copper and zinc by 48% and 56%, respectively in pig sludge compost. Lower concentrations of copper and zinc in pig sludge resulted from the enhanced hydrated-citric acid concentration in organic acid solution mixed with distilled water. The concentrations of copper and zinc were 330, and 41 mg/kg in the pig sludge treated with 100% hydrated citric acid. Agitation composting system stabilized the compost earlier than the stationary composting system, in which the stabilization condition was confirmed by higher temperature by $4^{\circ}C$ at highest temperature and 7 days earlier cooling down after highest temperature. The levels of germination index (G.I) 80 were obtained 15 and 20 days after composting in agitation and stationary composting system, respectively. The concentrations of copper and zinc were 2.4 and 4.26 mg/kg respectively in soils amended with pig sludge compost after removing process of heavy metals by citric acid, but 8.0 and 22.37 mg/kg, respectively in soils amended with Pig Sludge. The concentrations of heavy metals was highest in com cultivated in soils amended with pig sludge. The copper and zinc concentrations In corn leaves were 75.2 and 50.56 mg/kg respectively, which were 4 and 2 fold higher than the com cultivated in soils amended with pig sludge compost after heavy metal removing process by hydrated citric acid.

Use of Chinese Bleak, Aphyocypris chinensis, in Embryo and Sac-Fry Stages Toxicity Test (왜몰개 (Aphyocypris chinensis)를 이용한 Embyo, Sac-fry stages Toxicity Test)

  • Yeom, Dong-Hyuk;Seo, Jin-Won;Lee, Sung-Kyu
    • Environmental Analysis Health and Toxicology
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    • v.20 no.4 s.51
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    • pp.359-363
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    • 2005
  • ESS (Embryo and sac-try stage) 독성 시험에서 시험어종으로서의 국내토착종인 왜몰개 (Aphyocypris chinensis)의 적용성을 평가하기 위하여 아연(Zn)을 사용하여 국제적인 추천시험 어종인 송사리(Oryzais latipes)와 감수성을 비교하였다. 시험기간은 대조군에서 아사가 관찰되는 시기 즉, 왜몰개는 수정 후 8일, 송사리는 수정 후 16일로 하였으며, 시험기간 동안 수정란의 부화율, 수정란 및 난황단계의 치어(sar-fry)의 사망률, 형태적인 발달, 치어의 성장 등을 관찰 및 측정하였다. 두 종 모두 수정란의 생존율에 아연의 영향을 받았으며, LOEC는 모두 14.5 mg/L이었다 난황단계 치어의 사망률을 관찰한 결과, 왜몰개는 1.4mg/L부터 급격히 증가된 반면에 송사리는 14.5mg/L에서 $100\%$사망률이 관찰되었다. 시험물질에 노출된 왜몰개와 송사리 모두 척추변형이 관찰되었으며, 체장을 측정한 결과는 왜몰개가 송사리에 비해 민감하게 반응하는 것으로 나타났다. 위와 같은 결과들은 종합해 볼 때, ESS독성시험에서 왜몰개가 대체 시험어종으로서 사용될 수 있는 가능성을 보여주었다