• Journal of Korea Soil Environment Society
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• v.2 no.2
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• pp.95-103
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• 1997

Solvent extraction using aqueous solutions is presumed as one of the most effective methods applicable to in situ conditions without excavation of contaminated soils. Laboratory permeameter soil flushing test is performed to describe the process of solvent extraction of contaminants absorbed on soil particles. When the permeameter tests conducted, diffusion of contaminants through the permeameter flexible-wall was considered for adjusting the remediation percentage. Input and output balance for concentration was well matched in the permeameter tests. Nitrobenzene diffused so excessively (approximately 75%) that it was not suitable for the permeameter desorption tests. No biodegradation was detected in the soil samples.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.86-86
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• 2017

고효율의 에너지 변환 및 친환경적인 이점들을 이유로, 고분자전해질 연료전지(PEMFC)는 차세대 에너지 장치로 이목을 끌어왔다. 반면, 값비싼 백금 촉매의 이용은 연료전지의 상업적 이용에 주요한 결점으로 작용했다. 최근, Zelenay와 연구팀은 폴리아닐린-철-탄소 복합체구조에서 산소환원활성이 백금과 견주어 비슷한 성능을 낼 수 있음을 보고 하였다. Dodelet은 이러한 높은 성능이 전이금속의 영향에 의한 것일 수 있다는 주장을 하였다. 본 연구팀은 지난 연구에서 제일원리전산모사를 통해 니켈, 코발트, 구리등과 같은 전이금속이 질소가 도핑된 탄소 그래핀층에 미치는 거동을 밝혔다. 결론적으로, 금속들은 질소가 도핑된 그래핀의 전자구조를 바꿀 수 있고, 이러한 전자구조의 변화는 산소 환원반응에서 긍정적으로 작용할 수 있음을 확인하였다. 이러한 이론적 연구에 기반하여, 탄소층으로 감싼 금속은 내구성과 활성을 동시에 보유한 향후 전망있는 촉매 물질로 예상되어진다. 특히, 질소가 도핑된 탄소층으로 코팅된 철-코발트 합금은 계산을 통해 산소환원반응에서 우수할 것으로 예측되었다. 본 연구팀은 FeCo@N-C 나노입자를 직접 합성하였고, 이 촉매의 우수한 활성을 전기화학적, 구조적 관점에서 1) 질소의 도핑 효과, 2) 탄소의 두께 효과, 3) 합금효과에 집중하여 분석하였다.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.05a
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• pp.316-322
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• 2002

This paper presents the temperature-dependent hysteresis identification of an electro-rheological (ER) fluid under various operating temperatures using the Preisach model. As a first step, polymethylaniline (PMA) particles are prepared and mixed with silicone oil to make an ER fluid. A couette type electroviscometer is then employed to obtain the field-dependent shear stress. In order to show the suitability of the Preisach model to predict a physical hysteresis phenomenon of the ER fluid, two significant properties; the minor loop property and the wiping-out property are experimentally examined under three dominant temperature conditions. Subsequently, the Preisach model fur the PMA-based ER fluid is identified using experimental first order descending (FOD) curves. The effectiveness of the identified hysteresis model is verified in the time domain by comparing the predicted field-dependent shear stress with the measured one under the both specified and unspecified temperatures. In addition, the hysteresis model proposed in this work is compared to Bingham model.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.9 s.102
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• pp.1077-1083
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• 2005

Electro-Active Paper (EAPap) is one of attractive electro-active polymer (EAP) materials for artificial muscles due to its many advantages such as light weight, biologically degradable, low cost, large displacement output, low actuation voltage and low power consumption. However, drawbacks of EAPap actuators include low force output and humidity dependence. To enhance the performance of EAPap, conductive polymer (PPy) and SWNT/conductive polymer (PANI) are coated on EAPap PPy as conductive polymer is coated on cellulose EAPap by means of electrochemical deposition. Two different dopants are used in PPy through conducting polymer processing. SWNTS are mixed with PANI in emeraldine base along with different dopants. The compound materials are coated on cellulose EAPap using spin coating system. The performance of PPy/EAPap and SWNT/PANI/EAPap are evaluated in terms of bending displacement, blocked force, and the effects of dopants, humidity, coaling time, voltage and frequency are investigated. Comparing with EAPap actuators, SWNT/PANI/EAPap actuators show $200\%$ improvement of bending displacement and $300\%$ increment of blocked force.

• Korean Journal of Materials Research
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• v.17 no.8
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• pp.433-436
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• 2007

Nano-structured polyaniline have been synthesized by interfacial polymerization method at room temperature. An aqueous solution of aniline in chloroform and another solution of ammonium peroxydisulfate in doping acid were prepared at different times terminated with methanol at room temperature. SEM, UV-vis were used to characterize the polyaniline with regard to their morphology and structure. The diameter and length of polyaniline can be controlled by the reaction time. Nano-structured polyaniline were found to have superior sensitivity for volatile organic compounds(VOCs). As the reaction time to increase from 30minute to 2hours the sensitivity were decreased to VOCs vapors. The sensitivity of Nano-structured polyaniline sensor appeared to VOCs better than the sensitivity of chemical synthesis sensors. The sensitivity of Nano-structured polyaniline sensor improved benzene vapors.

• Journal of the Korean Chemical Society
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• v.45 no.3
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• pp.201-207
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• 2001

The dielectric relaxation study for aniline-dimethylsulphoxide (DMSO) and aniline-dim.ethylformamide(DMF) has been carried out using the Time domain reflectometry (TDR) technique, at different temperature and concentrations, in the frequency range of 10 MHz to 10 GHz. The dielectric parameters viz. static permittivity, relaxation time, the Kirkwood correlation factor, excess permittivity, excess inverse relaxation time and thermodynamic parameters have been obtained. The calibration method based on least squares fit method has been used. The dielectric parameters show systematic change with temperature and concentrations.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.8
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• pp.648-656
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• 2002

This paper presents the identification of temperature-dependent hysteresis of an electro-rheological (ER) fluid under various operating temperatures using the Preisach model. As a first step, polymethylaniline (PMA) particles are prepared and mixed with silicone oil to make an ER fluid. A couette type electroviscometer is then employed to obtain the field-dependent shear stress. In order to show the suitability of the Preisach model to predict a physical hysteresis phenomenon of the ER fluid, two significant properties; the minor loop property and the wiping-out property are experimentally examined under three dominant temperature conditions. Subsequently, the Preisach model for the PMA-based ER fluid is identified using experimental multiple first order descending (FOD) curves. The effectiveness of the identified hysteresis model is verified in the time domain by comparing the predicted field-dependent shear stress with the measured one under the both specified and unspecified temperatures. In addition, the hysteresis model proposed in this work is compared to Bingham model.

• Korean Journal of Materials Research
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• v.16 no.6
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• pp.386-393
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• 2006

Increasing environmental concerns require to solve the problem produced due to the use of heavy metals in coating formulations. Therefore, it is necessary to develop new coating strategy employing inherently conducting polymers such as polyaniline. Polyaniline is a conductive polymer that is synthesized by oxidation polymerization, and the electrochemical and chemical polymerization are possible for the oxidation of aniline. Electrochemical oxidation polymerization produces a fine surface and although voltage control is more convenient, it require electrolytic cells, and elaborate thin film can be acquired with the polymerization. Polyaniline films were electro-polymerized on cold rolled sheets using the galvanostat mode in the oxalic acidaniline-sodium molybdate electrolyte. The structure and properties of polyaniline film were studied using Potentiostat/Galvanostat 263A, FE-SEM,, AFM, SST, Colorimetry. A high corrosion resistance of polyaniline film was observed with an increase of corrosion potential by $500{\sim}600$ mV for the substrate covered with polyaniline.

• Electrical & Electronic Materials
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• v.10 no.1
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• pp.54-60
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• 1997

The electrical and electromagnetic shielding properties have been investigated in polyaniline free standing films with different degrees of elongation cast from N-methyl 2-pyrrolidone(NMP) solution and camphorsulfonic acid(HCSA) doped polyaniline film. The degree of crystallinity of the crosslinked films increased with increasing the draw ratio. For the case of the oriented films doped with hydrochloric acid, we have the values of conductivities up to 173 S/cm. It is considered that the physical micro-crystalline crosslinking domains act as nucleation sites for the increase of relative crystallinity during stretching. We have obtained the value of conductivity 210 S/cm in the HCSA doped polyaniline film cast from the solvent of m-cresol, which is higher than that of the crosslinking oriented films. The electromagnetic shielding efficiency of HCSA doped polyaniline film obtained 37-41 dB in the frequency range of 10MHz-1GHlz, which is higher than that of the crosslinking oriented films. The higher value of electromagnetic shielding efficiency of HCSA doped polyaniline film suggests strong possibility of electromagnetic shielding material.

• Textile Coloration and Finishing
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• v.8 no.5
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• pp.25-48
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• 1996

이 연구의 목적은 에틸렌이민 유도체를 갖는 아조계 분산 염료의 폴리에스테르 섬유에의 응용과 최적화된 폴리에스테르 염색 조건의 확립이다. 이들 아지리디닐 염료는 구조가 유사하며 말단에 하이드록시기를 갖는 염료(아지리디닐 염료의 가수분해 형태)와 비교하여 최대 흡수 파장의 천색적으로 천이 됨을 알 수 있었다. 세가지 아지리디닐 모노 아조 염료와 이들 염료의 가수분해 된 형태 그리고 디메틸아니린계 아조 염료의 폴리에스테르 섬유에 대한 염색 및 견뢰도 성질이 조사되었다. 아지리디닐 아조 염료는 산성 조건에서보다 염기성 조건하에서 보다 안정하였고, 뛰어난 build-up이 높은 pH조건에서 얻어졌으며, 폴리에스테르 염색 시 130$^{\circ}C$, pH 10의 조건에서 최적화된 색상 강도를 얻었다. 아지리디닐 염료는 이 염료의 가수분해 형태와 디메틸아닐린 염료와 비교하여 개선된 세탁 견뢰도를나타내었고 이는 용매 추출을 이용하여 확인 하였다. 아지리디닐 아조 염료는 역시 광 련뢰도에서도 또한 상용화된 분산 염료에 비교하여 높은 결과를 나타내었다.