• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.107-107
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• 2010

IT 산업의 발달과 더불어 카메라, 휴대폰, 노트북, 캠코더 등 전기전자 응용분야에 복합기능성 실리콘 고무 시트가 사용되고 있다. 본 연구에서는 실리콘 고무의 사용시 발생하는 정전기를 방지하기 위해 습도와 온도 변화에 따른 정전기 대전전압을 측정하였다. 카본양의 증가에 따라서 대전전압이 감소하였으며 습도가 증가됨에 따라 정전기 대전량은 감소하였다. 12Phr카본 첨가시 대전과 동시에 완화가 일어남을 확인했다.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.12
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• pp.1465-1471
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• 2013

The electrical and mechanical properties of room temperature vulcanized (RTV) silicone rubber composites are investigated as functions of multi-walled carbon nanotube (CNT), carbon black (CB), and thinner content. The thinner is used to improve the CNT and CB dispersion in the matrix. The electrical and mechanical properties of the composite with CNT are improved when compared to the composite with CB at the same content. As the thinner content is 80 phr, the electric resistance of the composite decreases significantly with the CNT content and shows contact point saturation of CNT at 2.5 phr. As the thinner content increases, the dispersion of conductive particles improves; however, the critical CB content increases because of the reduction in the CB weight ratio. It is believed that an electrode that needs good flexibility and excellent electrical properties can be manufactured when the amount of CNT and CB are increased with the thinner content.

• Polymer(Korea)
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• v.37 no.6
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• pp.722-729
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• 2013

In order to enhance the thermal conductivity of poly(dimethyl siloxane) (PDMS), boron nitride (BN) and carbon nanotubes (CNTs) were incorporated as the thermally conductive fillers. The amount of BN was increased from 0 to 100 phr (parts per hundred rubber) and the amount of CNTs was increased from 0 to 4 phr at a fixed amount of the boron nitride (100 phr). The thermal conductivity of the composites increased with an increasing concentration of BN, but the incorporation of CNTs had only a slight effect on the enhancement of thermal conductivity. Unexpectedly, the thermal degradation of the composites was accelerated by the addition of CNTs in 100 phr BN filled PDMS. Activation energy for thermal decomposition of the composites was calculated using the Horowitz-Metzger method. The curing behavior, electrical resistivity, and mechanical properties of PDMS filled with BN and CNTs were investigated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05c
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• pp.92-95
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• 2001

고분자 복합체 절연재료는 porcelain 이나 glass 같은 세라믹 소재의 재료와 비교하여 옥외사용 시간의 관점에서 더 뛰어난 특정을 발휘한다. 그러나 노화되었을 때, 이들 옥외용 절연재료의 성질은 발수성이나 흡수성등과 같은 절연재료의 표면특성에 의해 변화한다. 이러한 표면특성의 변화는 누설전류에 의한 트래킹 (tracking), 침식 (erosion) 및 섬락현상(flashover) 등의 유전체 파괴에 이르게 한다. 본 연구에서는 고분자 복합체 절연재료로 널리 이용되고 있는 EPDM의 발수특성을 향상시키기 위해 기존에 이용되던 무기물 첨가제인 alumina hydrate(ATH)이외에 발수성이 뛰어난 실리콘 고무를 상용화제를 이용하여 블렌드하고, 각종 유기 첨가제 및 무기물 보강제를 이용하여 EPDM/Silicone 복합체를 제조하였다. EPDM/Silicone 복합체의 인장강도 및 유전강도는 실리콘의 함량이 증가할수록 낮아졌으며, 촉진 노화시험을 실시한 결과 $120^{\circ}C$까지 인장강도 및 신율을 유지하였다. 유전강도의 측정결과 복합체의 접촉각과 표면에너지 측정결과 Silicone 고무의 함량이 증가할수록 접촉각은 증가하고, 표면에너지는 낮아졌다. 경사평판법에의한 내트래킹성 측정결과 실리콘 함량이 증가할수록 내트래킹성은 우수하였으며, 실리콘 함량이 30%인 복합체에서는 트래킹 및 침식이 진행되지 않았다.

• Elastomers and Composites
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• v.46 no.2
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• pp.164-170
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• 2011

In this study, silicone rubber filled with environmentally-friendly perlite was prepared by mechanical mixing in order to improve thermal properties, such as heat and fire resistances. We found that the properties of silicone rubber composites depended on perlite concentration by various characterization methods. Thermogravimetric analysis(TGA) indicated that the initial degradation temperature of silicone/perlite composite was higher than that of pristine silicone rubber. The gas torch test showed that the opposite side temperature of composite materials was remarkably low as compared to that of pristine silicone rubber. In addition, the composites containing 5 wt% and 10 wt% of perlite showed remarkable thermal stability at elevated temperatures according to the results of both fireproof furnace tests under the RABT condition and carbonization furnace tests. The images from a scanning electron microscope(SEM) showed the degree of dispersion of perlite in silicone rubber. Finally, it was confirmed that limited oxygen index(LOI) was increased with perlite concentration.

• Electrical & Electronic Materials
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• v.9 no.4
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• pp.410-414
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• 1996

기존의 초고압 옥외절연물은 세라믹을 소재로한 porcelain이었지만 최근 신소재기술의 발달로 내열성, 내후성, 내트래킹성 등이 우수한 고분자 재료들이 개발됨에 따라 구미 선진국을 중심으로 이들의 전기절연물분야 적용이 크게 증가하고 있다. 인발(pultrusion)공법으로 glass fiber와 수지를 결합시켜 고강도 무결점의 FRP절연봉이나 tube를 만들 수가 있다. 절연물에서 요구되는 구조재로서의 기계적 특성은 FRP복합재료가 충족시킬 수 있는데 이러한 봉을 core재로 하여 절연물의 표면전기특성을 만족하도록 고무로 된 shed를 씌우고 양쪽 끝에 금구류를 부착하여 composite insulator를 만들 수가 있다. composite insulator는 여러개의 shed를 한번에 진공사출하거나 shed를 금형에서 찍어 조립하여 제작할 수가 있는데 지금까지 검토되어 온 어떤 고분자 절연물보다 특성이 우수하고 장점이 많기 때문에 상업적 가치를 인정받고 있다. 본 고에서는 옥외용 절연물의 절연성능과 섬락사고기구를 요약하고 고분자신소재 절연물인 composite insulator의 장점, 국내외 개발현황, 평가방법등을 정리하였다.

• Journal of the Korean Magnetics Society
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• v.18 no.3
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• pp.115-119
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• 2008

The raw materials of permalloy were processed the ball-mill for 30 hours and the shape of permalloy particles was changed from sphere to flake type, which was observed using scanning electron microscope. The complex permittivity and permeability spectra and reflection loss of permalloy-rubber composite was measured using Network Analyzer in order to investigate the relationship between the microwave absorption and the material constants. The flake type permalloy-rubber composite showed high reflection loss, which was due to the high complex permittivity and permeability. Also, the matching frequency shifted toward lower frequency range with microwave absorber thickness, and the maximum reflection loss of -6.1 dB was observed in $1.65\;GHz{\sim}1.86\;GHz$ for a 1.3 mm thickness.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1670-1672
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• 1996

Silicone rubber composite is very suitable for insulation materials because of it's hydrophobicity, mass productivity, and design flexibility. A study of the diffusion of silicone fluid from the bulk to the surface of the silicone rubber composite using dynamic contact angle meter and scanning electron microscopy(SEM) is reported. A study of the mechanical strength of the silicone rubber composite having various silicone fluids and fluid contents is also reported. It has been found that the kind of silicone fluid affects the diffusion rate of the silicone fluid from the bulk to the surface of the silicone rubber composite after artificial pollution.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.7
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• pp.310-315
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• 2017

Automotive waterproof connectors are highly functional parts that must be air-tight in a complex environment. In the LSR multi-cavity injection molding process for manufacturing waterproof connectors, it is important to maintain a uniform curing temperature between the cavities in order to obtain a quality product. For this purpose, we designed the capacity of the cartridge heater differently for each position, and then linked the heat transfer analysis and optimization module to obtain the optimal cartridge heater capacity. As a result of the optimization analysis, the temperature deviation between cavities was decreased from $13.1^{\circ}C$ to $8.1^{\circ}C$ compared with the case in which constant heater capacity was applied, so that the design criterion could be satisfied within a temperature deviation of $10^{\circ}C$ for uniform curing. This study suggests that this method can be applied efficiently to the design of a large area multi-cavity LSR mold heater.

• Resources Recycling
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• v.9 no.6
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• pp.31-35
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• 2000

The complex permeability, the complex permittivity and the reflection loss are investigated in the composite microwave absorbers which are mixed with the wasted Mn-Zn ferrite and the industrial cement. The cement has larger the complex permittivity than that of the rubber. The complex permittivity is decreasing with the increment of the mixing ratio of Mn-Zn ferrite to cement (F/C in weight) and the complex permeability is increasing with the increment of F/C. The maximum reflection loss is above -40 dB at all samples. The matching frequency is in the range of 1.3 GHz to 2.9 GHz and is decreasing with the increment of F/C from 1 to 3. The matching thickness is increasing with the increment of F/C. The wasted Mn-Zn ferrite and the cement is very useful material for the composite microwave absorber.