• Title/Summary/Keyword: 신율

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The Thermal and Mechanical Properties of Recycled PP/EVOH/PP Scrap with Compatibilizers (재활용 PP/EVOH/PP 스크랩의 상용화제별 열적/기계적 특성연구)

  • Chun, Yong-Jin;Ahn, Tae-Kwang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.1
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    • pp.176-181
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    • 2008
  • This paper was studied the possibility on the recycling of the scrap used as the food packaging materials, PP/EVOH/PP multilayer. Recycling study was investigated into thermal and mechanical properties of samples which were mixed PP/EVOH waste plastics scrap with two kinds of compatibilizers. Melt behaviors as thermal property and tensile strength, % strain at break point, and tensile modulus as mechanical properties were investigated into kinds of and the weight ratio of compatibilizers. Mixed PP/EVOH waste plastics shows compatibity when Minanto-s and GMS as compatibilizers are mixed 0.5wt.% over.

Cooperative Routing of Wireless Ad-hoc Networks in Rayleigh Fading Channel (레일레이 페이딩 채널에서 무선 애드 혹 네트워크의 협동라우팅)

  • Kim, Nam-Soo;An, Beong-Ku;Kim, Do-Hyeon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.3A
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    • pp.290-296
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    • 2007
  • We propose new routing scheme, Cooperative Diversity-based Routing (CDR) which utilizes the cooperative space diversity for power saving and performance enhancement of wireless ad-hoc networks. The improved performance is compared with Multi-hop Relay Routing (NRR) by analytical methods. When the required outage probability is $1\times10^{-3}$ at the destination node in ad-hoc networks with 7 nodes, we noticed that each node can save power consumption by 15.5 dB in average, by using our proposed CDR compared to MRR.

Mechanical Properties of in Recyclate HIPS with Concentration of Fly Ash (再生 HIPS에 石炭灰 첨가에 따른 기계적 특성)

  • 안태광;김덕현
    • Resources Recycling
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    • v.10 no.2
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    • pp.34-40
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    • 2001
  • Post-consumer dairy HIPS bottles were gathered and recycled by the following processes; crushing into flakes, chemical treatment for the purpose of elimination aluminium caps, washing, and separation from other plastics, such as PP, PE, plasticized PVC These HIPS flakes were extruded into the chips using a single screw extruder. Recyclate HIPS chips were mixed with fly ash as an additive in the range of 5-50 wt%, which were formed from coal power plant. Recyclate HIPS chips mixed with fly ash were molded to investigate thermal and mechanical properties. Their samples, thermal and mechanical properties were measured via DSC, TGA, UTM, and impact strength analysis. The probable mechanical properties exhibited the range of 5∼30% fly ash contents for their applications.

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Studies on Incombustibility Improvement of EPDM Rubber with $Al(OH)_3$ and $Sb_2O_3$ ($Al(OH)_3$$Sb_2O_3$의 첨가에 따른 EPDM계 고무의 난연성 향상 연구)

  • Kim, Jin-Yong;Lee, Won-Bok;Lim, Dae-Hyun;Suh, Hyuk;Rhee, Young-Woo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.449-452
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    • 2009
  • In order to improve incombustibility of EPDM(Ethylene propylene diene monomer)-based rubber, inorganic materials as $Al(OH)_3$ and $Sb_2O_3$ were added. The mechanical and thermal properties have been measured for vulcanized rubber loaded with different concentrations of $Al(OH)_3$ and $Sb_2O_3$. As inorganic material contents increases from 5phr to 30phr, the specific gravity and hardness increase while elongation at break decreases. This study performed incombustibility test and thermal analysis through TGA(Thermogravimetric Analyzer). As a results, incombustible and thermal properties of EPDM-based rubber were improved as $Al(OH)_3$ and $Sb_2O_3$ contents increase.

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Effect of Type of Rubber and Carbon Black Addition on ABS/PMMA Blends (ABS/PMMA 블렌드에 미치는 고무형태와 카본블랙 첨가에 따른 영향)

  • Choi, C.H.;Lee, S.M.;Yoon, L.K.;Shon, K.H.;Kim, B.K.
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.935-942
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    • 1994
  • Two types of ABS were prepared from diffrent types of rubber, and blends of the ABS and PMMA were compounded and evaluated in terms of morphology, mechaincal and rheological properties. In addition, the effect of carbon black in the ABS/PMMA blends were studied. With increasing PMMA content, flexural modulus, tensile yield strength, and surface gloss of the blends increased, but elongation at break and Izod Impact strength decreased. With carbon black addition, mechanical properties were generally decreased. Effects of the type of ABS, and carbon black on melt properties were also studied.

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Effect of Soft Segment Length on the Dispersion and Physical Properties of Polyurethane Ionomer (Soft Segment 길이가 Polyurethane Ionomer의 분산특성 및 물리적 특성에 미치는 영향)

  • Kim, Byung Kyu
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.60-66
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    • 1993
  • Aqueous polyurethane(PU) anionomer dispersions were prepared from isophorone diisocyanate (IPDI), polytetramethylene adipate glycol(PTAd) and dimethylol propionic acid(DMPA) as potential anionic centers. The effects of polyol molecular weight(Mn) on the state of dispersion, thermal, mechanical, and viscoelastic properties and swelling of emulsion cast film were determined. With increasing Mn of PTAd, particle size of emulsion and soft segment T$_{g}$ decreased, and solvent swell, emulsion viscosity, and hard segment $T_{g}$ increased. Tensile strength showed minimum with PTAd 1000, and elongation at break generally increased with the Mn of PTAd. These results were possibly nterpreted in terms of soft segment-hard segment phase separation and crystallization of high molecular weight PTAd.

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Optimization of Polymer Composite Properties Using a Red Clay (황토를 이용한 고분자 복합수지 물성 최적화)

  • Seo, Kyoung-Won;Ji, Ju-Hyeon;Peng, Mei-Mei;Lee, Joo-Bo;Jang, Hyun-Tae
    • Proceedings of the KAIS Fall Conference
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    • 2011.05a
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    • pp.332-335
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    • 2011
  • 원적외선, 음이온 방출과 항균, 탈취, 난연등의 효과를 가지는 황토를 합성수지와 혼합하여 복합소재를 연구하여 환경 친화적인 특징과 원적외선, 음이온의 방출을 이룰 수 있는 복합소재 조성을 연구하였다. PP는 MI가 2~60이고, TPE로 Ethylene계을 사용하였으며, 황토와 PP의 혼련을 도와주기 위하여 MA-g-PP를 첨가하였고, 활제, 분산제 및 산화방지제를 첨가하여 compounding 하였다. 또한 황토의 종류에따라 적황토, 호황토, 홍토, 백토, 흑토등으로 구분되고, 각각의 황토 마다 다양한 종류의 입도를 가지고 있으며, 또한 환경 친화적이며 난연성을 부여하기 위하여 다양한 조성으로 compounding 하였다, 황토의 종류에 따른 복합재료의 물성으로부터 기계적 특성치, 원적외선 방사율, 난연성등을 확인하고, 친환경 난연 복합소재 기술을 연구하였다. 적황토의 경우 황토의 함량이 많을수록 인장강도는 작아지는 경향을 나타냈으며, 입도가 작을수록 인장강도가 커지는 경향을 나타냈다. 파단신율의 경우 적황토(#2000)에서 가장 양호하게 나타났으며, 굴곡강도, 충격강도의 경우 적황토(#5000)에서 MI 의 경우 적황토(#325)에서 양호하게 나타났다.

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Surface and Electrical Properties on EPDM/Silicone Composite Insulator (EPDM/Silicone 복합 절연체의 표면특성과 전기적 특성)

  • Shim, Dae-Sup;Park, Sung-Gyun;Kim, Bum-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.92-95
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    • 2001
  • 고분자 복합체 절연재료는 porcelain 이나 glass 같은 세라믹 소재의 재료와 비교하여 옥외사용 시간의 관점에서 더 뛰어난 특정을 발휘한다. 그러나 노화되었을 때, 이들 옥외용 절연재료의 성질은 발수성이나 흡수성등과 같은 절연재료의 표면특성에 의해 변화한다. 이러한 표면특성의 변화는 누설전류에 의한 트래킹 (tracking), 침식 (erosion) 및 섬락현상(flashover) 등의 유전체 파괴에 이르게 한다. 본 연구에서는 고분자 복합체 절연재료로 널리 이용되고 있는 EPDM의 발수특성을 향상시키기 위해 기존에 이용되던 무기물 첨가제인 alumina hydrate(ATH)이외에 발수성이 뛰어난 실리콘 고무를 상용화제를 이용하여 블렌드하고, 각종 유기 첨가제 및 무기물 보강제를 이용하여 EPDM/Silicone 복합체를 제조하였다. EPDM/Silicone 복합체의 인장강도 및 유전강도는 실리콘의 함량이 증가할수록 낮아졌으며, 촉진 노화시험을 실시한 결과 $120^{\circ}C$까지 인장강도 및 신율을 유지하였다. 유전강도의 측정결과 복합체의 접촉각과 표면에너지 측정결과 Silicone 고무의 함량이 증가할수록 접촉각은 증가하고, 표면에너지는 낮아졌다. 경사평판법에의한 내트래킹성 측정결과 실리콘 함량이 증가할수록 내트래킹성은 우수하였으며, 실리콘 함량이 30%인 복합체에서는 트래킹 및 침식이 진행되지 않았다.

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Curing Behaviors and Mechanical Properties of Unsaturated Polyester Hosing with Different Glycol Molar Ratios (글리콜 몰비가 다른 UPE 수지의 경화거동과 물성에 관한 연구)

  • 이상효;이장우
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.599-609
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    • 2000
  • In order to improve the mechanical properties of unsaturated polyester (UPE) resins, the UPE resins with different glycol molar ratios were prepared. The effects of molar ratios of the UPE resins on the curing behaviors and mechanical properties were investigated. The microgel reaction mechanism was employed to characterize the system. It was found that the final conversion increased with increasing NPG molar ratios, and the conversion at the peak of differential scanning calorimetry (DSC) thermogram appeared to decrease with increasing NPG molar ratios. The flexural strength, tensile modulus, water resistance, and infiltration increased with increasing NPG content, but the tensile strength, tensile elongation, and flexural modulus decreased. Among the UPE resins prepared from the glycols with the molar ratios (PG/NPG) of 0.5/0.5, 0.25/0.75, those of laminated composites plates showed better mechanical properties.

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Preparation and Properties of Celluose Diacetate/Starch Composite (Cellulose Diacetate/Starch 복합체의 제조 및 물성)

  • Lee, Sang-Yool;Lee, Seung-Kyung;Lim, Hwan-Kyu;Kye, Hyoung-San;Lee, Young-Kwan
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.532-537
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    • 2006
  • In order to successfully meet the environmental and recycling problems, natural polymer and their derivatives are recognized as a promising biodegradable material. In this study, the biodegradable composites of cellulose diacetate and starch were prepared, and their physical and thermal properties were investigated. For the melting processing, triacetine was added as a plasticizer into the composites. The processability of cellulose diacetate was further enhanced by increasing the amount of starch in the composites. The tensile stress and Young's modulus were decreased and elongation was increased with increasing the amount of starch in them. A $T_g$ value was decreased with increasing the amount of starch in the composites. Also, the morphology of the composites were observed with the SEM.