• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.4
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• pp.57-65
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• 2013

The development of the oil refining industry has resulted in an annual 120 million tons of sulphur, which is a by-product of the desulphurization process. To exploit this abundance, the applications of sulphur must be expanded. as excellent durability of reuse of leftover sulphur which has high potential for utilization in construction materials, the study is actively in progress. Meanwhile, there has been active research on semi-rigid pavements that draw on the strengths and overcome the weaknesses of asphalt and concrete pavements. Acrylate is used to prevent cracking but involves a high cost, thus, an alternative material is required. As such, this study presents methods on the reuse of leftover sulphur and examines the engineering performance of grout containing sulfur polymer emulsion (SPE) for use in semi-rigid pavements. Our analysis shows that grout in which 30% of acrylate is replaced with SPE has superior properties in terms of time of flow and strength compared to regular grout. However, performance declined when more than 50% of acrylate was replaced by SPE, indicating that the optimum replacement level is 30%. Through SEM analysis, we found that grout with utra harding cement in this study at three hours had similar hydration properties to that of Type 1 Ordinary Portland Cement (OPC) at seven days, and maintained the properties regardless of grout containing SPE. OPC and grout with a replacement level of 30% displayed similar levels of chloride invasion resistance, whereas grout without SPE was far less resistant. Within the scope of this paper, the optimum replacement level of acrylate with SPE was found to be 30% in consideration of various properties such as time of flow, strength, and chloride invasion resistance.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.255-257
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• 2012

Epoxy resin without any hardener can harden in the presence of hydroxide ions in cement mortars and concretes at ambient temperature. The purpose of present study is to examine the hardening properties of hardener-free epoxy-modified mortars by curing conditions. The hardener-free epoxy-modified mortars using diglycidyl ether of A epoxy resin are prepared with various polymer-cement ratios, and subjected to initial moist/dry curing, initial steam(90℃) curing, initial steam/heat(80℃, 100℃) curing.As a result, degree of hardening of epoxy resin in initial moist/dry cured, initial steam cured and initial steam/heat(80℃) cured hardener-free epoxy-modified mortars is decreased with increasing polymer-cement ratio. However, it is markedly improved with additional dry-curing periods. On the other hand, regardless of the polymer-cement ratio and dry curing periods, degree of hardening of hardener-free epoxy-modified mortars with initial steam/heat(100℃) cure is over 95%.

• Magazine of the Korean Society of Agricultural Engineers
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• v.44 no.1
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• pp.93-102
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• 2002

Steel fiber and polymer are used widely for reinforcement material of RC structures because of its excellences of the durability, serviceability as well as mechanical properties. The purpose of this study is to investigate the shear behavior of polymer cement high strength concrete beams mixed with steel fiber. The compressive strength of concrete was based on the 100$\times$200 mm cylinder specimens. The compressive strength of concrete are 320$kgf/cm^2$, 436 $kgf/cm^2$ and 520 $kgf/cm^2$ in the 28 days. The static test was carried out to measure the ultimate load, the initial load of flexural and diagonal cracking, crack patterns and fracture modes. Also, load-strain and load-deflection examined. During the test cracks were sketched against the load values according to the growth of crack. result are as follows; (1) The failure modes of the specimens are increased in rigidity and durability with mixing steel fiber and polymer. (2) The load of initial crack was similar a theory of shear-crack strength. (3) The deflection and strain at failure load of Polymer-steel fiber high strength concrete beams were increased, improving the brittleness of the high strength concrete.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.55-59
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• 2009

The epoxy resin without hardener can harden by a ring-opening reaction in the presence of the alkalies produced by the hydration of cement in epoxy-modified mortars and concretes. This paper investigates the effect of curing conditions on the strength improvement of polymer-modified mortars using bisphenol A-type epoxy resin without hardener. The polymer-modified mortars using epoxy resin are prepared with various polymer-cement ratios, and subjected to ideal, water, dry and heat cures. In the heat cure, the epoxy-modified mortars are sealed or unsealed with a PVDC (polyvinylidene chloride) film. The epoxy-modified mortars are tested for flexural and compressive strengths at desired curing methods. The microstructures of the epoxy-modified mortars are also observed by scanning electron microscope. The effects of curing conditions on the strength development of the epoxy-modified mortars are examined. From the test results, the marked effectiveness of the heat cure under the PVDC film sealing against the development of the strength of the epoxy-modified mortar without the hardener is recognized. The flexural and compressive strengths of 7-day-90℃ heat-cured, PVDC film-sealed epoxy-modified mortars without hardener reach 7 to 17MPa and 24 to 44MPa respectively, and are two to three times of Unmodified mortar. Such high strength development of the epoxy-modified mortars may be achieved by the dense microstructure formation by cement hydrates and the hardening of the epoxy resin in the mortars.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.235-242
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• 2019

The objective of this study is to modify the mixture proportions of concrete that were developed for section enlargement strengthening elements using a specially designed binder composed of 5% ultra-rapid hardening cement, 10% polymer, and 85% ordinary portland cement in order to assign the self-compaction property to such concrete. The self-compaction abilities of concrete were estimated by the performance criteria specified in JSCE and EFNARC provions. Test results showed that the increase in the unit binder content at the consistent water-to-bider ratio led to increase in viscosity of fresh concrete but did not exhibit the decrease in the fluidity due to a greater viscosity. The mixture proportioning of self-compaction section enlargement concrete could be considered at the following conditions: unit binder contents of $430kg/m^3{\sim}470kg/m^3$ and fine aggregate-to-total aggregate ratios of 40%~46% at the water-to-binder ratio of 38%.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.12
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• pp.258-264
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• 2018

In this study, the improved performance of sprayed green soil was evaluated by incorporating functional additives. The optimal mixing ratio of the thickener and super-absorbent polymer, as an additive for moisture supply to the growth of plants within the range of mixing ratios that gives sufficient strength of green soil, was 5% and 1%, respectively. Using Portland cement as a main binder, the pH of the green soil was 9.1. To solve this alkali problem, the mixing proportion was improved so that the pH of the green soil was approximately 7.2 by mixing more than 10% of the chelate resin. The soil conductivity was measured to be 280 ~ 350mS/m under all the mixing conditions. This satisfied the criterion of less than 1000mS/m on the slope surface. As a result of measuring the soil hardness of the green soil prepared under the optimal mixing conditions of functional additives, it satisfied the criteria of 18 ~ 23mm when sprayed under a 1 bar pressure. The rebound rate was less than 15% when spraying green soil on a 75 % slope, and the hardness of the sprayed green soil was more than 18 mm.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.695-702
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• 2005

It is known that latex-modified concretes were increased their durability and permeability by added latex. The purpose of this study was to analysis the air void systems in latex-modified concretes using a reasonable and objective image analysis method with main experimental variables such as water-cement ratios, latex contents(0%, 15%) and cement types(ordinary portland cement, high-early strength cement and very-early strength cement). The results are analyzed spacing factor, air volume after hardened, air distribution and structure. Also, air void systems and permeability of latex-modified concretes were compared with correlation. The results are as follows; The same w/c ratio LMC showed better air entraining effect than OPC with AE water reducer. The VES-LMC showed that the number of entrained air below $100{\mu}m$ increased more than four times. In the HES-LMC, micro entraining air having range from 50 to $500{\mu}m$ increased above 7 times without antifoamer. Though spacing factor was measured low, latex-modified concretes were showed that permeability was good. It is considered that air void system does not have an effect on the property of latex-modified concretes but latex film is more influenced in the their durability.

• International Journal of Highway Engineering
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• v.3 no.4 s.10
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• pp.117-126
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• 2001

In this research, evaluation of adhesion in tension property of SBR-modified concrete to ordinary portland cement concrete was conducted with uniaxial direct tensile bond test which was proposed by Kuhlmann. A test set-up was fabricated in order to minimize the eccentric force by introducing a joint which might fully rotate. The main experimental variables were cement-latex ratios, surface preparations and moisture levels. The results obtained were as follows: The LMC specimen at 15% latex-cement ratio increased the adhesion in tension by range of 37% compared to that of conventional cement concrete. This might be due to latex film formed between cement paste and aggregate. The effects of surface preparation on bond of latex modified concrete to conventional concrete were significant at the conditions by sand paper and wire brush. A better bond could be achieved by rough surface rather than smooth. The saturated and surface dry (SSD) condition were considered to be the most appropriate moisture level followed by wet, finally by dry. Thus, a proper surface preparation and moisture level are quite necessity in order to obtain better bonding at LMC overlay.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.289-298
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• 2023

In this study, the development of a self-healing concrete waterproofing agent was examined, focusing on its manufacturing and waterproofing properties. The optimal ratio using microcapsules for the concrete waterproofing agent was determined through assessments of flow, compressive strength, and permeability conducted during the mortar stage. These findings aimed to provide fundamental data for evaluating the self-healing properties of the concrete waterproofing agent designed for use in concrete structures. The self-healing concrete waterproofing agent was comprised of three types of inorganic materials commonly used for repair purposes. From experimental results, a composition ratio with a high potassium silicate content, referred to as SIM-2, was found suitable. A surfactant mixing ratio of 0.03 % was identified to enhance the dispersibility of the concrete waterproofing agent, while a mixing ratio of 0.2 % distilled water was deemed suitable for viscosity adjustment. For the magnetic self-healing concrete waterproofing agent's healing agent, using microcapsules in the range of 0.5 % to 0.7 % met the KS F 4949 and KS F 4926 standards.