• Title/Summary/Keyword: 시료전처리

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Discontinuous precipitation in Sn-Bi Alloys (Sn-Bi계 합금의 불연속 석출현상)

  • Kim, Jeong-Seok;Kim, Ju-Hyeong;Yu, Chung-Sik
    • Korean Journal of Materials Research
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    • v.8 no.3
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    • pp.238-244
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    • 1998
  • Sn-rich합금의 석출 현상을 조사하였다. 첫째, 대기중과 진공 중에서 용해된 90Sn-o10Bi(wt%)합금을 $140^{\circ}C$에서 용체화 처리한 후 석출반응을 조사하였다. 90Sn-10Bi(wt%)합금은 불연속 석출(DP)현상을 나타냈다. 공기 중에서 용융된 시료의 DP반응이 진공 중에서 용융된 시료보다 빠르게 진행되었다. 이것은 공기 중에서 용융하는 과정에서 시료에 용존된 산소에 의해 입계 에너지가 감소한 것에 기인하는 것으로 판단된다. 둘째, 용융 후 서냉 응고된 Sn-Bi(-In)합금을 $140^{\circ}C$이하의 온도에서 열처리하여 미세조직 변화를 조사하였다. 명확한 고경각 입계가 존재하지 않는 응고조직에서, 편석영역으로부터 DP반응이 진행되어 석출셈이 형성되었다. DP반응선단에는 반응계면이 관찰되었다. 이 현상은, 이제까지 알려진 바와는 다르게, DP반응이 반응 전에 존재하는 고경각 입계뿐만 아니라 재결정현상에 의해 새로운 석출계면이 생성될 수 있음을 의미한다. 이러한 재결정 현상은 확산에 의한 정합변형(coherency strain)으로 설명된다.

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목재 방음벽 주변 토양의 중금속에 의한 오염

  • Song Byeong-Yeol;Ryu Seung-Hye;Park Eun-Ju;Kim Hui-Ja
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.238-241
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    • 2006
  • CCA 처리 방부 목재로부터 용출되는 크롬, 구리 및 비소는 주변의 토양을 오염시키는 것으로 알려져 있다. 이 연구에서는 방부 목재를 사용하여 설치한 방음벽 주변의 토양을 채취하여 분석하였다. 방음벽은 4차선의 자동차 도로와 마을 사이에 1m 높이의 콘크리트 구조물 위에 설치되었다. 수평 및 수직 시료와 더불어 대조 토양 시료를 채취하여 목재 방음벽으로 인한 주변의 토양 오염도를 평가하였다. 방음벽 인접한 곳의 토양이 대조시료에 비해 10-13mg/kg 더 높은 것으로 나타났고, 1년 전에 채취하여 분석한 자료와 비교했을 때, 시설물 인접 토양에서 크롬과 비소의 농도가 더 낮은 것으로 보아, 구성 성분의 용출 속도는 감소하고 토양에 용출된 성분은 강우 등에 의해 주변으로 이동한 것으로 판단된다.

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Estimation of soil Quantity and Environmental Effect on Dredged Soil (준설오니의 토량 산출 및 성분분석)

  • 신은철;오영인
    • Journal of Korea Soil Environment Society
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    • v.5 no.2
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    • pp.13-21
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    • 2000
  • Detention basin is the temporary holding pond of treated water prior to flow out to the sea. It is very common to dredge the soil from the bottom of detention basin to keep up the water holding capacity. In this study, the amount of volume reduction of dredged soil from detention basin was estimated based on the laboratory test results. The percentage of soil particles in dredged organic soil is about 12.5∼21.9% by weight. The content of heavy metal and environmental effect for dredged soil itself and solidified dredged soil were analysed and the results are meet the standards of environmental requirement.

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Effects of Pretense Treatment on Functional Properties of Soymilk Protein (단백분해 효소처리가 두유단백질의 기능성에 미치는 영향)

  • 변진원;황인경
    • Korean journal of food and cookery science
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    • v.11 no.1
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    • pp.26-32
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    • 1995
  • This study was carried out to investigate the effect of protease on the functionality of soymilk protein. The protease from Bacillus polymyxa was selected because of the least production of bitter taste and calcium-aggregation. The results are summarized as follows: 1. Solubility of SMP(soymilk protein) and SPI(soyprotein isolate) were lowest at pH 4.7 and increased as the pH value reached closer to either ends. PT-SMP(pretense treated soymilk protein) showed higher solubility at all pH range, especially at pH 4.7 than SMP, SPI. 2. Emulsion activity of three samples was lowest at pH 4.7 and significantly increased as pH approched higher acidic or alkaline regions. PT-SMP showed similar activity to other samples, but less stability. 3. Foam capacity of PT-SMP was lowest at pH 8 and increased in acidic, alkaline pH. PT-SMP showed higher foam capacity at all pH range, but lower foam stability than SMP and SPI. 4. PT-SMP showed higher heat coagulability than other samples at all pH range except pH 4.7.

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Effect of Some Variation Factors on Dissipation of Tebuconazole in Grape (포도 중 Tebuconazole의 잔류성에 미치는 몇 가지 변동요인의 영향)

  • Han, Seong-Soo;Lo, Seog-Cho;Ma, Sang-Yong
    • Korean Journal of Environmental Agriculture
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    • v.23 no.3
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    • pp.142-147
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    • 2004
  • Dissipation pattern of tebuconazole was evaluated by establishing application methods of the fungicide, paper-bagging of grape during growth and washing of grape after harvest. Application times increased from three to five resulted in high levels of residues in grape. Tebuconazole in grapes was present in different residual patterns with periods after final treatment ranging from 7 to 25 days. Significant differences in the residual patterns were also found when tebuconazole was treated during three different application periods, possibly due to meteorological condition and/or grape growth during each period. At the range from 2.5 g to 7.5 g of grape granules, residues were higher in small-sized grape than in big-sized grape and were mostly distributed on the peel of the grapes. Paper-bagging was a critical factor for reducing the fungicide residue on the peel. flesh of bagged and no-bagged grape had very low level of residues, 0.01 mg/kg and 0.05 mg/kg, respectively. Residues on grape was effectively eliminated with the washing methods suggested, a consecutive sinking-washing system Using of detergent solution during washing showed maximum residue reduction from grape. The washing methods showed effective action on the removal of lower content providing complete elimination, or almost, of the residues.

Browning Inhibition of Paeonia lactiflora Root during Hot Air Dehydration (작약근(芍藥根)의 열풍건조시(熱風乾燥時) 갈변(褐變)의 효과적(效果的) 억제(抑制))

  • You, Oh-Jong;Kim, Jang-Eok;Kim, Ki-Jae;Park, Chun-Hong;Park, So-Deuk;Choi, Boo-Sull
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.4
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    • pp.245-250
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    • 1998
  • This research was carried out to investigate the effective methods of browning inhibition on Paeonia lactiflra Pall during hot air dehydratin. After drying for 36 hrs without pretreatment and with briquet fumigation moisture contents of Paeonia lactiflora Pall. was 16.0% and 16.2%, respectively, while with acidic solution, sulfite salt solution and blanching it was lower of 13.5, 12.9 and 14.8%, respectively. Using freeze drying moisture content was highest of 18.8%. The Hunter values of dried Paeonia lactiflora Pall., L, a, band ${\triangle} E$ showed that non-treatment had the most browning with 61.60, 1.89, 10.20 and 39.78, respectively, while briquet fumigation and sulfite salt solution were excellent in reducing browning. During freeze drying browning didn't occur. Paeoniflorin content was 2.41 and 2.51 %, respectively, in briquet fumigation and sulfite salt solution and was the highest (2.70%) in freeze drying. The content of $SO_2$, was 0.63% both in briquet fumigation and sulfite salts. It was 0.15% and 0.17% higher than nontreatment and freeze drying. The most effective pretreatment to inhibit browning of Paeonia lactiflora Pall. was soaking in sulfite salt solution $(0.5% NaHSO_4-0.5% Na_2S_2O_3)$ considering many things such as manpower, economical efficiency, drying time, commodity, etc. but safety should be evaluated to treat sulfite salts solution on peony roots.

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Enhancement of adhesion between Cu thin film and Polyimide modified by ion assisted reaction (이온보조 반응법에 의하여 표면처리된 Polyimide (PI) 표면과 구리박막의 접착력 향상)

  • 석진우
    • Journal of the Microelectronics and Packaging Society
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    • v.4 no.1
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    • pp.19-30
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    • 1997
  • 고분자 Polyimide (PI) film 표면을 반응성 가스 분위기에서 1KeV의 에너지를 가지 는 여러 종류의 이온빔으로 조사하여 표면을 개질하였다. PI표면의 친수성과 표면에너지를 측정하기 위해 접촉각 측정기를 사용하였으며 개질 된 표면의 화학적 변화를 측정하기 위해 X-ray photoelectron spectroscopy (XPS)를 사용하였다. 표면 개질을 위한 이온조사량은 5 $\times$1014 -1$\times$1017 ions/cm2이며 반응가스는 0-8scm까지 변화시켰다. 아르곤 이온빔으로 표면 개질시에는 67。에서 40。까지 감소하였고 표면에너지는 46 dyne/cm에서 64dyne/cm까지 증가하였다. 산소를 6sccm 주입하면서 산소 이온빔으로 표면 개질시 물과의 접촉각은 67。 에서 최대 12。까지 감소하였으며 표면에너지는 46dyne/cm에서 72dyne/cm까지 증가하였고 이때의 이온조사량은 5$\times$1014 -1$\times$1017 ions/cm2 이였다. 여러 종류의 반응성 가스와 이온을 사용하여 개질하여 본 결과 산소분위기에서 산소 이온을 이용하여 개질 하였을 때 접촉각이 8。인 표면을 얻을수 있었다, 산소분위기에서 아르곤 이온빔으로 1$\times$1017 ions/cm2 의 이온 조사량으로 개질 된 Pi 시료를 대기 중에 보관하였을 때에는 110시간 후 65。로 증가하였고 물속에서 보관하였을 때에는 46。로 증가하였다. 그러나 산소 이온빔에 산소분위기에서 개 질 된 시료의 경우 물속에 보관할 경우 접촉강의 증가없이 일정한 값을 나타내었다. 이온조 사로 개질된 시료의 화학적 변화를 확인하기 위하여 XPS 사용하였다. 표면 개질 전의 PI 시료와 산소 분위기에서 1$\times$1017 ions/cm2의 아르곤 이온빔으로 개질한 XPS peak 결과로 보아 Cls의 spectra를 보면 C-C, C-N 그리고 C=O의 결합들은 intensity가 감소하였고 C-O 의 intensity는 증가하였다. Nls peak로 보아 imide N 성분은 이온빔의 조사로 인하여 감소 하였고 C-O의 intensity는 증가하였다. Nls peakk로 보아 imide N성분은 이온빔의조사로 감소하였고 Ols peak로 보아 C-O는 증가하였고 C=O는 약간의 감소가 나타났다. 또한 이온 보조 반응법을 이용하여 처리한 시료의 경우 접착력이 증가하는데 이는 주로 C-O 결합의 산소와 Cu와의 상호작요에 의한 것임을 알수 있었다.

The Minimum Concentrations of Surfactants Inducing Phytotoxicity and Their Symptoms (계면활성제(界面活性劑)의 약해유발농도(藥害誘發濃度)와 그 증상(症狀))

  • Yu, Ju-Hyun;Koo, Suk-Jin;Cho, Kwang-Yun
    • Korean Journal of Environmental Agriculture
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    • v.8 no.2
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    • pp.119-127
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    • 1989
  • The minimum concentrations of nonionic and anionic surfactants inducing phytotoxicity were investigated after spraying or flooding surfactant solutions to annual plants. Of the sufactants tested, LE, NP, SPSS, LN, PAAS and DBC induced phytotoxicity at the lowest concentrations through all treatments and Tween, Span, SP, SC, STPP and CLIS induced the least phytotoxicity even at high concentration. At flooded paddy field tests, anionic surfactants induced phytotoxicity at the lower concentration than nonionic, but showed similar tendencies with other treatments. In pre-emergence treatments of upland and dry paddy field tests, there was little phytotoxicity induced at over 10 percent, while phytotoxicity was induced at the lowest concentration among 6 treatments in flooded paddy field tests.

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Effects of Tumbling and Immersion on Quality Characteristics of Cured fork Meat with Soy Sauce (텀블링과 침지공정이 간장첨가 돈육의 품질특성에 미치는 영향)

  • 김천제;정종연;최지훈;서우덕;이의수;한현경
    • Food Science of Animal Resources
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    • v.23 no.1
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    • pp.21-27
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    • 2003
  • This study was carried out to investigate the effect of curing method(tumbling and immersion) and curing time (10 min to 48 hrs) on pH, color, product yield, cooking yield, water holding capacity, shear force, and sensory evaluation of cured pork meat with soy sauce. Curing method had an effective on color of cured meat(before cooking), Meats were tumbled for 30 min, followed by 24 hr and 48 hr delay period showed higher lightness than meat immersed for 24 and 48 hrs, respectively. Tumbling processing improved product yield and cooking yield as compared to immersion counterpart. Therefore, tumbled meat had significantly greater product yield(p <0.05) during working time for 30 min. Increasing curing time improved water holding capacity and tenderness. Although curing time had no influence on sensory evaluation, tumbling processing improved sensory evaluation of texture, juiciness, and overall acceptability fer cured pork meat with soy sauce, as compared to immersion counterpart.

Effects of Electron-Beam Irradiation and Storage on Cholesterol 7-derivatives Products of Meat (전자선 조사와 저장기간이 식육의 콜레스테롤 7-유도체 산화물의 발생량에 미치는 영향)

  • Lee, Jeong-Ill;Lee, Moo-Ha
    • Korean Journal of Food Science and Technology
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    • v.31 no.1
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    • pp.74-82
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    • 1999
  • Beef, pork and chicken meat that retailed in market were used as experimental samples. Some samples in raw state were packaged with PVDC as aerobic and vacuum condition. The other samples were cooked until internal temperature arrived at $70^{\circ}C$ using electric oven and then packaged immediately in the same way of raw samples. After these samples were irradiated by electron beam (0, 1, 2 kGy), irradiated samples were stored in refrigerator $(2{\sim}4^{\circ}C)$. Identification and quantification of cholesterol oxides were analysed at 0, 7, 14 days. The results were following. The results indicated that raw-vacuum packaged lower detected than that of other treatments. In raw-vacuum packaged, the amounts of $7{\beta}-hydroxycholesterol$ were detected slightly $(below\;0.5\;{\mu}ug/g)$ during storage, and 7-ketocholesterol were detected during every stored time and amounts of this detection were $8.02{\sim}101.30\;{\mu}g/g$. In cooked-aerobic packaged, total amounts of detection were higher than that of other treatments, total amounts of cholesterol oxides were detected about $51.18{\sim}155.90\;{\mu}g/g$ during storage. In all results, pork and chicken samples were similar to the results of beef samples. In all results, total amounts of cholesterol oxides increased significantly as irradiation dose and storage time increased (P<0.05).

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