• 제목/요약/키워드: 시간-온도곡선

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Studies on Press Drying of Fire-Retardant Treated Plywood (내화처리합판(耐火處理合板)의 열판건조(熱板乾燥)에 관(關)한 연구(硏究))

  • Kim, Jong Man
    • Journal of Korean Society of Forest Science
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    • v.56 no.1
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    • pp.1-25
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    • 1982
  • Plywood used for construction as a decorative inner material is inflammable and can cause fire accidents. causing destruction of human life and property. To diminish the fire disaster, fire retardant plywood is indeed required. In the methods of manufacturing the fire retardant plywood, a soaking method is occasionally used. However after soaking plywood into fire retardant chemical solutions redrying of soaked plywood is of the utmost importance. In this study 3.5mm and 5.0mm thickness plywoods were selected for fire retardant treatment. Treating solutions were prepared for 20% dilute solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, borax-boric acid minalith, and water solution, 1-, 3-, 6-, and 9 hour-soaking treatments in borax-boric acid and minalith, and 6- and 9 hours in the other chemicals were applied and after the treatment hot drying was applied to treated plywoods at $90^{\circ}C$, $120^{\circ}C$ and $150^{\circ}C$ of press temperature. Drying rates, drying curves, water absorption rates of fire retardant chemicals, weight per volume and fire retardant degree of plywood were investigated. The results may be summarized as follows: 1) In the 9 hours-soaking treatment of fire retardants by hot and cold bath method, the chemical retentions of 3.5mm thickness plywood could be attained within the range ($1.125-2.25kg/(30cm)^3$) of minimum retention specification as follows: $1.353kg/(30cm)^3$ in monoammonium phosphate, $1.331kg/(30cm)^3$ in diammonium phosphate, $1.263kg/(30cm)^3$ in ammonium sulfate, $1.226kg/(30cm)^3$ in borax-boric acid. But the chemical retention, $0.906kg/(30cm)^3$, in minalith could not be attained within the range of minimum retention specification. And also in case of 5.0mm thickness plywood, chemical retentions, as $1.356kg/(30cm)^3$ and $1.166kg/(30cm)^3$ respectively, of ammonium sulfate and diammonium phosphate could be attained within the range minimum retention specification, but the other fire retardant chemicals could not. 2) In the 6- and - hours-soaking treatments of 3.5mm and 5.0mm thickness plywood, the drying curve sloped of chemical treated plywood was smaller than that of water treated. The drying rate related to thickness of treated plywood, was about three times as fast in 3.5mm thickness plywood compared with 5.0mm thickness plywood. 3) In the treatment at $120^{\circ}C$ of hot platen temperature, the drying rates of chemical-treated plywood showed the highest quantity in diammonium phosphate of 3.5mm and 5.0mm thickness plywood. But the drying rate of water treated plywood was highest during the 6- and 9 hours-soaking treatments. 4) The drying rate remarkably increased with proportion to increase of the platen temperature, and the values were respectively 1.23%/min., 6.54%/min., 25.75%/min. in hot platen temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in 3.5mm thickness plywood and 0.55%.min., 2.49%/min., 8.19%/min. in hot platen temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in 5.0mm thickness plywood. 5) In the fire retardant degree of chemical treated plywood, the loss in weight was the smallest in diammonium phosphate, next was in monoammonium phosphate and ammonium sulfate, and the greatest was in borax-boric acid and minalith. And the fire-retardant effect in burning time, flame-exhausted time and carbonized area were greatest in diammouniun phosphate, next were in monoammonium phosphate and ammonium sulfate, and the weakest were in borax-boric acid and minalith.

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Alumimium Titanate-Mullite Composites : Part1,Thermal Durability (Alumimium Titanate-Mullite 복합체: Part1, 열적 내구성)

  • Kim, Ik-Jin;Gang, Won-Ho;Go, Yeong-Sin
    • Korean Journal of Materials Research
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    • v.3 no.6
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    • pp.624-631
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    • 1993
  • The composites in the system aluminium titanate-mullite were synthesized by stepwise alkoxide hydrolysis of tetraethylorthosilicate, Si(OCLH5), and titaniumtetraethoxide, $Ti(OC_{2}H_{5})_4$ in $Al_{2}O_{3}$ ethanolic colloidal solution. All particles produced by sol-gel-process were amorphous, monodispesed and had a narrow particle size distribution. Sintered bodies at $1600 ^{\circ}C$ for 2h were subjected to prolonged durability tests-on the one hand annealing at the critical decomposition temperature of $1100 ^{\circ}C$ for lOOh and on the other cyclic thermal shock between 750 and $1400 ^{\circ}C$ for 100h. The best thermal durability was achieved by a composition containing 70 and 80 vol% aluminium titanate, which showed little change in microstructure and thermal expansion cycles during the tests. The microstructural degradation of samples studied using scanning electron microscopy, X-ray diffraction, and dilatometry, was presented here. The study was conducted in order to predict the service life of aluminium titanate-mullite ceramics formed by this processing route.

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Design of Supersonic Wind Tunnel for Analysis of Flow over a Backward Facing Step with Slot Injection (슬롯 분사가 있는 후향계단 유동장 분석을 위한 초음속풍동 설계)

  • Kim, Ick-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.11
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    • pp.363-367
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    • 2016
  • A test section of a supersonic wind tunnel was designed for the analysis of flow characteristics over a backward-facing step with Mach 1.0 slot injection in a supersonic flow of Mach 2.5. The cavity flow of a high-speed vehicle is very complex at supersonic speed, so it is necessary to do experiments using supersonic wind tunnels to verify numerical analysis methods. The previous 2D symmetrical nozzle was replaced with an asymmetrical nozzle. The inviscid nozzle contour was designed using Method of Characteristics (MOC), and the boundary layer thickness correction was reflected by experimental data from the wind tunnel. The results were compared with a CFD analysis. The PID control system was changed to be based on the change of tank pressure. This improved the control efficiency, and the run times of supersonic flow increased by about 1 second. The flow characteristics over a backward facing step with slot injection were visualized by a Schlieren device. This equipment will be used for an experimental study of the film cooling effectiveness over a cavity with various velocities, mass flows, and temperatures.

Microporous Polystyrene Membranes Produced via Thermally Induced Phase Separation (열적으로 유도된 상 분리에 의해 제조된 폴리스티렌 미세 다공성 막)

  • Song, Seung-Won;Torkelson, John M.
    • Membrane Journal
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    • v.5 no.3
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    • pp.119-128
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    • 1995
  • The effects of coarsening on microstructure formation in polystyrene-cyclohexane solutions and membranes made from them were studied by scanning electron miccoscopy(SEM). Thermal analysis of the polymer solutions was carried out with a differential scanning calorimeter and the binodal curve was determined from the onset temperature of the heat of demixing peak. Using thermally induced phase separation(TIPS) and a freeze drying technique, it was demonstrated that polymer membrane microstructure can be changed significantly by controlling coarsening time and quench route. For systems undergoing phase separation by spinodal decomposition, resulting in a well interconnecmd, microporous structure with nearly uniform pore sizes, it was found that extending the phase separation time prior m freezing and solvent removal can result in a significant increase in pore or cell size which is highly dependent on both quench depth and coarsening time. Also this study has revealed the important role of polymer concentration in dictating the material continuity of the membranes.

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Eire-induced Damage to Shield TBM Concrete Segment (터널 화재로 인한 콘크리트 세그먼트의 손상특성 규명)

  • Choi Soon-Wook;Chang Soo-Ho;Lee Gyu-Phil;Bae Gyu-Jin
    • Journal of the Korean Geotechnical Society
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    • v.21 no.5
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    • pp.171-177
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    • 2005
  • Fire in underground space may induce severe structural damage as well as heavy casualties. To protect underground structure and passengers from fire, it is very essential to characterize fire-induced damage on construction materials of underground structures. In this study, the high-temperature furnace was manufactured to evaluate fire-induced damage on underground structure materials. Especially, this study aimed at the evaluation of fire-induced damage on the shield TBM concrete segment. In the fire tests, furnace temperature was set to reach 1,200 degrees at five minutes after Ignition. The temperature of 1,200 degrees was kept during one hour, and the fire was extinguished after two hours elapsed. From the temperature measurement by thermocouples embedded in test specimens, the spatting was estimated to reach approximately 20 cm from the surface exposed to fire. After the fire tests, the alteration of physico-mechanical properties and microstructures of concrete segment was investigated from core specimens. The results showed that apart from spatting, the deterioration depth of the remaining concrete material amounted to approximately 10 cm from the spatting surface.

A Study on the Local Boiling of the Consolidated Spent Fuel Storage Pool (조밀화된 사용후 핵연료 저장조에서의 국부 비등에 관한 연구)

  • Lee, Chang-Ju;Lee, Kun-Jai
    • Nuclear Engineering and Technology
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    • v.25 no.1
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    • pp.8-19
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    • 1993
  • The natural convection model of the consolidated system has been developed to make sure the removal of decay heat generated in the spent fuel for the loss of forced cooling accident. The numerical technique employed was based on the ADI scheme. The calculation of heat generation rate in the spent fuel was peformed by the ANS-79 decay heat model, and the nonuniform surface heat flux is assumed with a chopped sine curve for the conservative decay heat generation input. The sensitivity study was performed to examine the possibility of the pool bulk boiling by varying the various parameters, i.e. inter-fuel spacing ratio, heat generation power, and radius of the fuel rod. The application results of this model show that the natural circulation flow through compacted spent fuel bundles enables the pool temperature to control in a safe and effective manner, after the required cooling time. The corresponding acceptance criteria of the cooling time for rearranging the spent fuel rods were also found.

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Study on the Promotion Effect of Ionic Liquid on CH4 Hydrate Formation (이온성 액체를 이용한 메탄 하이드레이트 생성 촉진효과 연구)

  • Shin, Ju-Young;Kim, Kisub;Kang, Seong-Pil;Mun, Sungyong
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.500-505
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    • 2013
  • In this study, we investigated the kinetics of gas hydrate formation in the presence of ionic liquid (IL). Hydroxyethyl-methyl-morpholinium chloride (HEMM-Cl) was chosen as a material for the promotion effect test. Phase equilibrium curve for $CH_4$ hydrate with aqueous IL solution was obtained and its induction time and consumed amount of $CH_4$ gas were also measured. Aqueous solutions containing 20~20,000 ppm of HEMM-Cl was prepared and studied at 70 bar and 274.15 K. To compare the measured results to those of the conventional promoter, sodium dodecyl sulfate was also tested at the same condition. Result showed that the hydrate equilibrium curve was shifted toward higher pressure and lower temperature region. In addition, the induction time on $CH_4$ hydrate formation in the presence of IL was not shown. The amount of consumed $CH_4$ was increased with the whole range of tested concentration of IL and the highest consumption of $CH_4$ happened at 1,000 ppm of HEMM-Cl. HEMM-Cl induced and enhanced the $CH_4$ hydrate formation with a small amount of addition. Obtained result is expected to be applied for the development of technologies such as gas storage and transport using gas hydrates.

Performance Based Evaluation of Concrete Carbonation from Climate Change Effect on Curing Conditions of Wind Speed and Sunlight Exposure Time (기후변화의 풍속과 일조시간 양생조건에 따른 콘크리트 탄산화 성능중심평가)

  • Kim, Tae-Kyun;Shin, Jae-Ho;Choi, Seung-Jai;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.45-55
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    • 2015
  • Currently, extreme weather events such as super typhoon, extreme snowfall, and heat wave are frequently occurring all over the world by natural and human caused factors. After industrial growth in the 1970s, earth's temperature has risen sharply. due to greenhouse effect. Global warming can be attributed to gases emitted from using fossil fuel such as average carbon dioxide, perfluorocarbons, nitrous oxide, and methane. Especially, carbon dioxide has the highest composition of about 90%. in the fossile fuel usage emitted gas. Concrete has excellent durability as a building material climate change. However, due to various of physical and chemical environmental effect such as conditions during its curing process, the performance degradation may occur. Carbon dioxide in the atmosphere causes steel corrosion and durability decreases by lowering the alkalinity of concrete. Therefore, in this study, concrete durability performance with respect to carbonation from curing conditions change due to wind speed and sunshine exposure time. Concrete carbonation experiment are performed. using wind speed (0, 2, 4, 6) m/s and sunlight exposure time (2, 4, 6, 8) hrs. Also, performance based evaluation through the satisfaction curve based on the carbonation depth and carbonation rate test results are performed.

Craniofacial morphologic alteration induced by bone-targeted mutants of FGFR2 causing Apert and Crouzon syndrome (어퍼트 및 크루즌 증후군을 유발하는 골조직 특이성 FGFR2 돌연변이에 의한 두개안면 형태의 변화)

  • Lee, Kee-Joon;Nah, Hyun-Duck;Tjoa, Stephen T. J.;Park, Young-Chel;Baik, Hyoung-Seon;Yun, Tae-Min;Song, Jin-Wook
    • The korean journal of orthodontics
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    • v.36 no.4
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    • pp.284-294
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    • 2006
  • Objective: Activating mutations in the fibroblast growth factor receptor-2 (FGFR2) have been shown to cause syndromic craniosynostosis such as Apert and Crouzon syndromes. The purpose of this pilot study was to investigate the resultant phenotypes induced by the two distinctive bone-targeted gene constructs of FGFR2, Pro253Arg and Cys278Phe, corresponding to human Apert and Crouzon syndromes respectively. Methods: Wild type and a transgenic mouse model with normal FGFR2 were used as controls to examine the validity of the microinjection. Micro-CT and morphometric analysis on the skull revealed the following results. Results: Both Apert and Crouzon mutants of FGFR2 induced fusion of calvarial sutures and anteroposteriorly constricted facial dimension, with anterior crossbite present only in Apert mice. Apert mice differed from Crouzon mice and transgenic mice with normal FGFR2 in the anterior cranial base flexure and calvarial flexure angle which implies a possible difference in the pathogenesis of the two mutations. In contrast, the transgenic mice with normal FGFR2 displayed normal craniofacial phenotype. Conclusion: Apert and Crouzon mutations appear to lead to genotype-specific phenotypes, possibly causing the distinctive sites and sequence of synostosis in the calvaria and cranial base. The exact function of the altered FGFR2 at each suture needs further investigation.

Preparation of Noodle with Laver Powder and its Characteristics (김분말을 이용한 국수의 제조 및 특성)

  • Lee, Jang-Wook;Kee, Hae-Jin;Park, Yang-Kyun;Rhim, Jong-Whan;Jung, Soon-Teck;Ham, Kyung-Sik;Kim, In-Chul;Kang, Seong-Gook
    • Korean Journal of Food Science and Technology
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    • v.32 no.2
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    • pp.298-305
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    • 2000
  • Laver noodles were prepared with composite flour containing various ratios of laver powder sifted through 100-mesh sieve and their cooking characteristics were evaluated. Farinograph test results with the composite flour showed that water absorption rate increased linearly as the content of laver powder increased from 2% to 8%, while dough stability decreased linearly with the laver content. Dough development time increased 2.65-3.75 times by adding laver powder. DSC endotherms indicated that onset temperature $(T_o)$, peak temperature $(T_p)$, and conclusion tempearture $(T_c)$ of composite flour starch gelatinization shifted to a higher temperatures as the laver powder content increased. Difference in laver species (e.g., Porphyra dentata and Porphyra tenera) did not affect dough characteristics and surface color of doughs and noodles made with composite flours. From the sensory evaluation test for noodles, a laver noodle containing 4% roasted Porphyra dentata was the most preferred among the noodles tested.

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