• Title/Summary/Keyword: 승온폭

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The influence of heating rate on the carbonization of sulfuric acid-impregnated cellulose (황산첨가 셀룰로오스의 탄화에서 승온속도의 영향)

  • 김대영
    • Journal of Korea Foresty Energy
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    • v.22 no.1
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    • pp.37-43
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    • 2003
  • The influence factors for char yield in the carbonization process of natural cellulose are the carbonization temperature, the heating rate and the atmosphere in the furnace. In general, it is well known that the improvement of char yield is expected under the conditions of the lower carbonization temperature, the slower heating rate and the presence of inert gas in the furnace. In this study, it has been investigated the effect of the heating rate control with sulfuric acid as a dehydrating agent for the improvement of char yield in the carbonization process of natural cellulose. The cellulose treated with sulfuric acid has shown the weak dependency of heating rate in char yield, whereas the untreated cellulose has shown the strong dependency. These findings clearly suggest that it can be useful to control heating rate with appropriate dehydrating agent in the carbonization process to improve the char yield and shortening the carbonization time.

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Themodynamic Characteristics of a Two-Stage Binary Absorption Cycle (2단(段) 2원(元) 흡수(吸收)사이클의 특성(特性)에 관(關)한 연구(硏究))

  • Lee, Y.H.;Rie, D.H.;Kashiwagi, T.;Seo, J.Y.
    • Solar Energy
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    • v.15 no.1
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    • pp.29-38
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    • 1995
  • This paper concerns the study of a two-stage binary absorption cycle employing the refrigerant/absorbent combinations of $LiBr/H_2O$ and $NH_3/H_2O$. This cycle consists of coupling two single-effect absorption cycles so that the first stage absorber and condenser produces heating water to evaporate refrigerant in the evaporator of the second stage. The effect of operating variables such as evaporator temperature, condenser and absorber temperature, and generator temperature on the coefficient of performance and temperature lift have been studied for two-stage binary absorption heat pump systems. It is found that this cycle has a large temperature lift at $105^{\circ}C$ of optimum generator temperature to obtain $50^{\circ}C$ of condenser temperature.

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Piezoelectric Properties of PMN-PT Relaxor Ferroelectrics with $MnO_2$Addition ($MnO_2$첨가에 따른 PMN-PT계 완화형 강유전체에서의 압전특성)

  • 박재환;박주영;박재관;김병국;김윤호
    • Journal of the Korean Ceramic Society
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    • v.37 no.10
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    • pp.1021-1024
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    • 2000
  • PMN-PT계 완화형 강유전체에서 MnO$_2$첨가가 압전물성에 미치는 영향을 -40~10$0^{\circ}C$의 온도범위에 걸쳐 조사하였다. 각각의 시편들은 -4$0^{\circ}C$에서 1.0kV/mm의 전계를 10분간 가하여 분극처리를 한 후 승온하면서 공진 반공진법에 의해 압전물성을 측정하였다. 0.9MN-0.1PT계의 경우 MnO$_2$를 첨가하였을 때 $K_{p}$ 는 거의 유지되면서도 Q$_{m}$ 값이 큰 폭으로 상승하였는데, 0.5wt% MnO$_2$첨가의 경우 -4$0^{\circ}C$에서 95로부터 480으로 증가하였다. 일반 강유전체인 PZT계에 대한 MnO$_2$의 첨가효과와 비교할 때 PMN계 완화형 강유전체에서도 동일한 경향성을 보임을 확인하였다.

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Urbanization Effect on the Observed Warming in Korea during the Recent Half Century (우리나라의 기온상승-도시효과인가 지구온난화인가)

  • 윤진일
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.4 no.1
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    • pp.58-63
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    • 2002
  • Since the rapid urbanization period coincides with the start of global warming, climate data might be contaminated with urbanization effect in Korea. Monthly normals of daily minimum, maximum, and mean temperature of 14 stations were calculated for 1951-1980 and 1971-2000 periods. Differences in two temperature normals were regressed to the natural logarithms of population increase at corresponding 14 cities from 1966 to 1990. The regression models were used to remove potential effects of urbanization from the apparent warming, and to determine the net contribution of global warming to the temperature change in Korea during the recent half century. According to the model calculation, there was little evidence of global warming in the warm season (May through November), while urbanization effect was common in all season except April. Up to 0.5$^{\circ}C$ warming of nighttime temperature was found to be induced by urbanization. Cool season temperature was increased by up to 0.6$^{\circ}C$ due mainly to the global warming of daytime temperature.

Development of ultrafine grained silicon carbide by spark plasma sintering (스파크 플라즈마 소결에 의한 초미세 결정립 탄화규소의 개발)

  • 조경식;이광순;백성호;이상진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.4
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    • pp.176-181
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    • 2003
  • Rapid densification of a SiC powder with additive 0.5 wt% $B_4$C was conducted by spark plasma sintering (SPS). The unique features of the process are the possibilities of using very fast heating rate and short holding time to obtain fully dense materials. The heating rate and applied pressure were kept to be $100^{\circ}C$/min and 40 MPa, while sintering temperature and soaking time varied to 1800, 1850, 1900 and $1950^{\circ}C$ and 10, 20 and 30 min, respectively. All of the SPS-sintered specimens at $1950^{\circ}C$ reached near-theoretical density. The XRD found that 3C-to-6H transformation at $1850^{\circ}C$. The microstructures of the rapidly densified SiC ceramics consisted of duplex microstructure with ultrafine equiaxed grains under 2 $\mu\textrm{m}$ and elongated grains of 0.5∼2 $\mu\textrm{m}$ wide, length 3∼10 $\mu\textrm{m}$. The biaxial strength increased with the increase of sintering time. Strength of 392.7 MPa was obtained with the fully densified specimen sintered at $1950^{\circ}C$ for 30 min, in agreement with the general tendency that strength increases with decreases pore. On the other hand, the fracture toughness shows the value of 2.17∼2.34 MPa$.$$m^{1/2}$ which might be due to the transgranular fracture mode.

Preparation of a axis oriented $YBa_2Cu_3O_{7-\delta}$ thin films by RF magnetron sputtering (RF 마그네트론 스퍼터링법에 의한 a-축 배향 $YBa_2Cu_3O_{7-\delta}$박막의 제조)

  • Lee, J.J.;Kim, Y.H.;Shin, J.;Lee, K.H.;Choi, S.S.;Hahn, T.S.
    • Korean Journal of Materials Research
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    • v.4 no.4
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    • pp.459-465
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    • 1994
  • A-axis oriened YBCO thin flims were grown on $LaAIO_{3}$ single crystal substrate by off-axis rf magnetron sputtering method. We used two kinds of process to get a-axis oriented fi1ms;one-step process and two-step process. In one-step process, films are grown in single step in which substrate temperature( $T_s$) is in the range of $590^{\circ}C$ to $680^{\circ}C$. On the other hand, in two step process a-axis oriented thin film templates i f about 30nm thickness is deposited at low temperature first, and subsequently films are grown at elevated temperature to the final thickness of about 100nm. In the case of one step process($T_s$ ~)$600^{\circ}C$), prefered a-axis orientation is dominant and Cu-rich phases segregate at the surface. Segregations decrease and ($00 \ell$) peaks increase upon increasing $T_s$. The films prepared by two step method appeared to have strong(h00) peaks as the deposition rate increased. Microstructure shows pin holes resulted from mixed phases of a-axis and c-axis oriented films. In both cases of one step and two step process, as TS decreases, prepared films show stronger a-axis orientation. However electrical properties of the films are depressed with lower $T_c$ and wider $\Delta T$ as $T_s$ decreases.

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Potential of HAZ Property Improvement through Control of Grain Boundary Character in a Wrought Ni-based Superalloy (단련용 Ni기 초내열합금의 입계구조 제어를 통한 HAZ 특성 향상 가능성 고찰)

  • Hong, H.U.;Kim, I.S.;Choi, B.G.;Jeong, H.W.;Yoo, Y.S.;Jo, C.Y.
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.43-43
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    • 2009
  • 단련용 다결정 Ni기 초내열합금은 우수한 가공성, 내산화성, 고온특성 등으로 가스터빈 연소기, 디스크, 증기발생기 전열관 등 발전용 고온부품 소재에 널리 적용되고 있다. 최근 발전설비의 고효율화를 꾀하기 위해 작동 온도를 현격히 증가시키는 기술방향으로 발전하고 있고, 소재측면에서는 기존의 초내열합금 대비 고기능성을 확보할 수 있는 차세대 Ni기 초내열합금 개발이 유럽, 미국, 일본, 중국 등을 중심으로 활발히 이루어지고 있다. 이러한 소재의 고온강도 (온도수용성)를 향상시키기 위해서는 통상 규칙격자 금속간화합물인 $Ni_3(Al,Ti)-{\gamma}'$상의 분율을 증가시킬 수 있지만, ${\gamma}'$상분율이 증가할 경우 용접 및 후열처리 동안 용접열영향부 (HAZ)에서 액화균열이 발생할 가능성이 높아진다. 결정립계를 따라 발생하는 HAZ 액화균열은 입계특성에 의해 크게 영향을 받을 것으로 판단된다. 한편, 본 연구자들은 최근 입계 serration 현상을 단련용 합금에 도입시키는 특별한 열처리를 이론적 접근법을 통해 개발하였다. 형성된 파형입계는 결정학적인 관점에서 조밀 {111} 입계면을 갖도록 분해 (dissociation)되어 낮은 계면에너지를 갖게 됨을 확인하였으며, 입계형상 변화뿐만 아니라 탄화물 특성변화까지 유도하여 크리프 수명을 기존대비 약 40% 정도 향상시킴을 확인하였다. 이러한 직선형 입계 대비 'special boundary'로 간주되는 파형입계가 도입될 경우, HAZ 결정립크기 변화 및 액화거동에 미치는 영향을 고찰하고, 아울러 입계특성 제어가 용접성/용접부 품질 향상에 기여할 수 있는 가능성도 토의하고자 하였다. 본 연구에서는 재현 HAZ 열사이클 시험을 통해 미세구조를 정량적으로 비교하였다. 상대적으로 입계구조가 안정된 파형입계의 이동속도가 高계면 에너지를 갖는 직선형 입계보다 느려 HAZ 결정립 성장이 효과적으로 억제됨을 확인할 수 있었다. 입계 액화거동을 살펴보면, 두 시편 모두 $M_{23}C_6$, MC 등 입계탄화물 계면이 빠른 승온중 액화반응 (constitutional liquation)에 의해 입계가 액화되었으며, 이후 급냉에 의해 입계에 액상막이 존재한 흔적이 발견되었다. 최고온도별로 입계액화 폭/비율을 정량적으로 비교한 결과, 파형입계가 직선입계 대비 대체로 낮음을 확인할 수 있었으며, 때때로 액화되지 않고 잔존하는 입계 탄화물이 관찰되었다. 재현 HAZ 미세조직을 통해 Hot ductility 시험 결과를 유추하자면, 파형입계가 직선입계 보다 좁은 취성온도영역 (Brittle Temperature Range)을 나타낼 것으로 예상되어, 입계특성제어에 의해 Ni기 초내열합금의 용접성을 향상 가능성을 확인하였다.

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