• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.401-401
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• 2022

우리나라 대규모 하수처리장에 상용화되어있는 응집공정의 운영상 난점을 극복하고자 대체공정으로 고안된 인 결정여과공정(HCF, Hydroxyapatite Crystallization-Filtration process)의 pilot plant를 구축하고 부산슬러지의 자원화를 위해 그 특성을 검토하였다. 기존의 hydroxyapatite(HAP) 결정화공정 내 탈탄산(decarbonation) 단계를 생략하는 HCF공정의 경우에 고농도의 Ca²⁺ 주입과 처리수내 탄산염으로 인해 HAP을 포함하는 석회계 슬러지가 발생하는데, 이는 산성화된 토양의 개량제(중화제)로 널리 사용될 수 있다. 본 연구를 위해 경기도 I하수처리장 2차침전지 후단에 구축된 처리용량 27.1 - 135.6 m³/day HCF pilot plant의 전처리 조건은 pH 10.0 - 11.0, Ca²⁺ 농도 80 mg/L이었다. 결정여과조는 선속도 1.0 - 5.0 m/hr, 상향류로 운전되며, 여재는 2.0 - 3.0 mm의 석회석 모래를 충전하였다. 역세척은 중앙에 Air lifting pipe를 설치하여 역세척수가 처리수와 분리배출되도록 설계하였고, 침전시켜 역세척 슬러지를 회수하였다. 처리수의 평균 T-P, PO₄-P 및 SS는 각각 0.05, 0.04, 1.1 mg/L으로 모든 항목에서 방류수 수질기준 이하로 안정적으로 유출되었다. 회수된 HCF 슬러지는 SEM-EDX, XRD, FT-IR을 활용하여 그 특성을 분석하였다. SEM-EDX로 분석된 슬러지의 원자분율은 CaCO₃ 또는 HAP으로 추측되었다. 또한, XRD spectrum 분석결과, 슬러지의 주요 구성성분은 calcite, HAP, phosphoric acid(H₃PO₄) 및 brusite로 나타났다. FT-IR 분석결과, 슬러지는 대부분 인산염 및 탄산염의 무기물로 구성되어 있으며, 유입수의 인 농도가 높을수록 슬러지 내 HAP의 함량이 calcite보다 높은 것으로 나타났다. 고농도의 Ca²⁺을 주입하여 탈탄산단계를 생략한 HCF의 부산슬러지는 HAP 이외에도 CaCO₃와 칼슘-인 화합물로 구성되어 있는 것으로 나타났다. 하수 인 고도처리를 위한 HCF공정의 하수처리시설 인 고도처리 적용이 검증되었으며, 부산슬러지를 산성화된 토양의 개량제(중화제) 또는 비료로서의 재활용 및 자원화 가능성이 시사되었다.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.476-481
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• 2005

2004년말 현재 국내에서 발생되는 음식물쓰레기의 재활용량은 전체 발생량의 $87.7\%$인 10,015톤/일이며, 전체 재활용량의 $6.47\%$인 640톤/일 정도가 혐기성소화 방법에 의해 처리 및 자원화 되고 있다. 국내에서 적용되고 있는 음식물쓰레기 혐기성소화 기술의 대부분은 습식소화(Wet digestion) 공법이며, 처리 방법별로 2상 혐기성소화(Two-phase anaerobic digestion)와 하수슬러지 흑은 축산분뇨와 함께 혼합처리 하는 통합소화(Co-digestion) 공정으로 구분되고 있다. 음식물쓰레기의 자원화 방법에 있어 혐기성소화는 사료화, 퇴비화에 비하여 폐기물의 효과적인 감량화와 자원화 효과뿐만 아니라 유용 에너지원인 메탄가스의 회수가 가능하기에 최근에 주목을 받는 biotechnology중의 하나로 자리매김 하고 있으며, 또한 유기성폐기물의 자원순환형 관리 시스템 구현에 있어 적절한 대안으로 고려되고 있다.

• Journal of The Korean Society of Grassland and Forage Science
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• v.31 no.4
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• pp.395-408
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• 2011

The study which it sees exclusions the copper and the zinc which contain in pig sludge, It study pig sludge resources fertilizer production which are rational, pig sludge resources fertilizers after seeding, silage corn it investigates growth characteristics and forage value, the result which investigates pig sludge resources fertilizers effectiveness with afterwards is same. With fertilizer ingredients in pig sludge chemical qualities, the content of the nitrogen and the phosphoric acid comes 4.4% to be 6.29%, pH 7.02 and content of the copper and the zinc which is a heavy metal which contains in pig sludge with 805 mg/kg and 1,704 mg/kg, it is a restrictive standard of the fertilizer, 300 mg/kg and 900 mg/kg it sees to be high, it manufactures citric acid 1 hydrate with the organic acid solution, heavy metals of pig sludge where it is a mixture ratio of the organic acid solution, it divides to 25%, 50%, 75% and 100% 4 kind levels, the result which measures the heavy metal exclusion ratio of the copper and the zinc, the mixture ratio of the organic acid solution to be many exclusion ratio of the copper and the zinc is showing a just interrelation, from organic acid solution 100% level content of pig sludge remains copper and zinc 330.03 mg/kg and 41.28 mg/kg, it shows the exclusion ratio of copper 59% zinc 97%. 'Cheonganok' growth characteristics with citric acid 1 hydrate, Treatment 2 and control growth characteristics etc, it exclusion the copper and the zinc it doesn't appear on significant difference statistically but, treatment 3 after only pig sludge in resources disposal where it seeding, growth characteristics of leaf area etc. is badness, it compares in control and treatment 2 the growth characteristics badness, it is appearing, it is caused by with disease and insects occurrence of $Ostrinia$ $furnacalis$ and brown spot, the damage was many. From forage value, Treatment 2 where it exclusion the heavy metal with the citric acid 1 hydrate with control it compares and there are not significant difference from crude protein and ADF and NDF contents etc., seeding only Pig Sludge in resources disposal treatment 3, it is caused by with $Ostrinia$ $furnacalis$ etc., trunk and aging of the leaf to be high ADF content is low. but from crude protein, the nitrogen ingredient which pig sludge has and interrelation it seemed and high numerical value were confirmed.

• 수도
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• s.68
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• pp.33-49
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• 1994

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.367-369
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• 2005

방사선 처리에 의한 슬러지의 기초 물성 변화 및 탈수율 증진에 대한 실험을 수행하였다. 또한 슬러지의 자원화를 위하여 슬러지 이용 퇴비를 제조하여 품질을 평가하였다. 방사선을 조사한 슬러지는 입자 내부에 존재하는 일부 수분이 유출되어 최종 탈수 케이크의 함유 수분이 약 7% 정도 감소하였으며, 이는 방사선 조사가 최종 슬러지 발생량을 저감시킬 수 있는 한 가지 방법임을 시사 하여준다. 슬러지를 이용한 퇴비화 실험을 통하여 방사선 처리를 한 퇴비의 품질이 비조사 퇴비에 비하여 퇴비 품질이 향상되었음을 입증하였다.

• Journal of the Korea Organic Resources Recycling Association
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• v.6 no.1
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• pp.67-73
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• 1998

This study was to experiment, through sewage sludge treatment by Vacuum Drying Method, variation of water content with reaction pressure, reaction time, reaction temperature. The result are as follows; The water content decreased with the same reaction temperature and reaction time at lower pressure and 360~40 mmHg (a close vacuum) showed lower water content at low reaction temperature and short reaction time. The water content rapidly decreased with the same reaction pressure and time at low reaction temperature (above $120^{\circ}C$).

• Journal of the Korea Organic Resources Recycling Association
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• v.13 no.1
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• pp.100-114
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• 2005

Organic waste, which is defined as wastes derived from various biological organisms that contain more than 40% of organic materials, is generated about 100 million tons per year in Korea. These organic wastes are now controlled by several governmental entities, under different rules and regulations, leading to the improper management and inefficient treatment. Therefore, integrated management system is primarily needed for the efficient recycling of organic waste. In this study, six kinds of organic wastes, which are food waste, sludges(sewage, waste water, night soil), animal excreta, animals and plants residues, and three kinds of recycling by-products(compost, feed, anaerobic digestion by-products) made of organic wastes, were analyzed for their physical and chemical characteristics. On the basis of this result, a possibility for the efficient recycling of organic waste was investigated.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.1
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• pp.13-24
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• 2013

• Journal of the Korea Organic Resources Recycling Association
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• v.4 no.2
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• pp.47-53
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• 1996

This study was carried out to estimate the amount and the characteristics of sewage sludge disposed of in the Nanjido sludge landfill site. Boring test was conducted to estimated the landfill volume and to get sludge samples to be analyzed. Total analysis and leaching test were performed to find the characteristics of sewage sludge. The Nanjido sludge landfill site had the surface area of $50,000m^2$ and the average depth of 15m. The estimated sludge volume was 600,000ton. Sewage sludge in Nanjido sludge landfill site was very stable. Results of total analysis of heavy metals indicated that the sludge could be classified as a non-hazardous waste according to the California state regulation. The sludge also could be used as compost based on compost quality criteria of foreign countries. Results of Korea Extraction Procedure showed that sewage sludge in Nanjido sludge landfill site was not a hazardous waste.

• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.4
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• pp.69-76
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• 2010

After feeding mixed samples, VS ranged from 60 to 80% of total costs in 15 days. EC ranged from1.21 to 2.45, 1.25 to 2.1 and 1.2 to 1.88mS/cm when worms were fed with a mixture of by-products of tidal current and sewage sludge, a mixture of by-products of algae producy, and food wastes and a mixture of by-products of algae producy, sewage sludge and food wastes. That means the kinds of mixture don't have any negative impacts on worms survival. With the feed with a mixture of by-products of algae producy and food wastes and a mixture of by-products of algae producy, sewage sludge and food wastes, pH shows stable 5.4 to 6.7, and 6.2 to 7.4 where is suitable for worms. But a mixture of by-products of algae producy and sewage sludge is out of proper scope for raising worms, in other words, extra care will be necessary. In case of Eh, a mixture of by-products of algae producy and sewage sludge make eh negative (-) in early stage so also when feeding worms, also extra care will be needed. NaCl ranged from 0.32 to 0.82% or form 0.23 to 0.61% when a mixture of by-products of algae producy and food wastes and a mixture of by-products of algae producy, sewage sludge and food wastes were fed. So taking care of salts will be essential whenever feeding.