• Title/Summary/Keyword: 슬래그시멘트

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시멘트/슬래그/Fe(II) 시스템에 의한 NAPL TCE의 분해 특성

  • 박정현;강완협;황인성;박주양
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.218-222
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    • 2004
  • Batch slurry experiments were conducted to develop cement/slag/Fe(II) system that could treat hazardous liquid wastes containing halogenated organic solvents. Portland cement in combination with Fe(II) was reported to reductively dechlorinate chlorinated organics in a modified solidification/stabilization process. TCE (trichloroethylene) was used a model halogenated organic solvent. The objectives of this study were to assess the feasibility of using cement and steel converter slag amended with Fe(II) as a low cost abiotic reductive dechlorination and to investigate the kinetics of TCE dechlorination over a wide range of TCE concentration. From the result of screening experiments, cement/slag/Fe(II) system was identified as a potentially effective system to treat halogenated organic solvent. Kinetic studies were carried out to further investigate degradation reaction of TCE NAPL (Non Aqueous Phase Liquids) in cement/slag/Fe(II) systems by using batch slurry reactors. Degradation rate of TCE solution in this system can be explained by pseudo-first-order rate law because the prediction with the rate law is in good agreement with the observed data.

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A fundamental Study on the properties of Concrete by using the Rapid Hardening Blast Furnace Slag Cement (조강슬래그시멘트를 이용한 콘크리트의 기초물성에 관한 연구)

  • 김진춘;최광일
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.04a
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    • pp.72-77
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    • 1995
  • Blast-furnace slag cement has been used widely as a structural material due to the latent hydraulicity of granulated ground blast furnace slag(GGBS)for a long time as The wall as ordinary portland cement. In this study, based on the fundamental investigation on the high strength and high durable concrete using the high fineness GGBS the following remarks can be made. 1) The average desired strenth of concrete is Or=600~800kg/$\textrm{cm}^2$. 2) The above high strength concrete using the high fineness GGBS is more workable than those using only OPC. 3) The adiabatic temperature and drying shringkage decrease, so the density and resistance to sea water attack increase as results. 4)The unit cement content and unit air entrained admixture at the same desired strength of concrete decrease, so the economical high strength concrete can be manufactured from using the high fineness GGBS.

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Properties of the Modified Belite Cement with Slag (슬래그를 혼합한 개량형 벨라이트 시멘트의 특성)

  • 안태호;박원기;박동철;심광보;최상홀
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.685-690
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    • 1999
  • Modified belite cement clinker containing $\alpha$'-C2S and C4A3 were syntehsized form the mixture of raw materials. $\alpha$'-C2S was stabilized at room temperature by adding borax. Properties of the clinker were charaterized with a XRD, SEM, TEM The additive effects of slag on the hydration properties were also estimated by measurement of compressive strength fluidity and heat evolution. The experimental results exhibited that the addition of slag to the belite cement improves the fluidity and early compressive strength due to the formation of ettringite and C-S-H. The compressive strengths of the mortar with 20% slag after 7, 90 days hydration were 212, 355 kgf/cm2 respectively.

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An Effect of $Ca(OH)_2$ on Development of an Early Age Strength of GGBFS Cement (고로슬래그 시멘트의 초기강도 발현에 있어서 수산화칼슘의 영향)

  • 이제방;김재신;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.64-69
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    • 1999
  • Slags are by-products of the metallurgical industry. The most important slag from the standpoint of the quantity used as building material is iron blastfurnace slag. Slags are either crystalline stable solid used as aggregates or glassy material used as hydraulic binder. Slag cements are low heat of hydration cements. Slags react more slowly with than portland cement but they can be activated chemically. Activatiors can be either alkaline activators such as soda, lime, sodium carbonate, sodium silicate or sulphate activators such as calcium sulphate or phosphogypsum. So, in this study slaked lime was used as an activator that the compressive strength of this modified cement(M1 type) is high range in early age. And initial setting time of M1 type cement was shorter than conventional cements.

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Experimental Study on the Development of High-Performance Concrete (고성능 콘크리트 개발에 관한 실험적 연구 제 1보 : 고미분말 슬래그 혼합시멘트의 물성)

  • 구자술;이영진;김남호;정재동
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.45-50
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    • 1993
  • This paper describes some results of various tests which were carried out with varying the fineness of salg from 6000 to 10000$\textrm{cm}^2$/g and the slag content in cement from 30 to 50wt% for the perpose of utilizing finely ground blast-furnace slag as an ingredient for high-performance concrete. Test for heat of hydration, microstructural and hydration characteristics in paste, and fluidity and compressive strength in mortar were carried out. From these test results, it was found that, by properly determining the content and fineness of the slag, it is possible to manufacture high-performance concrete that has low heat of hydration, high early strength development, fine pore size and a highly densified microstructure.

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A Study of Concrete Mix Proportioning Design using Blast-furnace Slag Cement (고로슬래그시멘트를 사용한 콘크리트 배합설계에 관한 연구)

  • 백광섭;차태환;노재호;박연동;윤재환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.113-118
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    • 1995
  • The purpose of this study is to suggest concrete mix proportioning design using Blast-furnace slag cement. The mix conditions are specified by concrete strength(180~400kg/$\textrm{cm}^2$), slump$(15\pm2cm)$m and air volume$(4.5\pm1%)$. From the result of concrete mix proportioning design using Blast-furnace slag cement, unit water content can be reduced by 3~8% comparing with OPC. The relationship between strength at 28days and cement water ratio is as follow. when blast-furnace slag cement is used: $\sigma_{28}$=304.OC/W-296.8. Super-plasticizer have to be used to get a slump of 15cm when water/cement ratio is less than 45%.

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A Study on the Properties of Inter-Locking Block Using Blast-Furnace Slag Cement (고로슬래그 시멘트를 사용한 인터로킹 블록의 특성에 관한 연구)

  • 이상태;이대주;신병철;김진선;권상준;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.203-206
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    • 1997
  • In this paper, the properties of Interlocking block contained blast furnace slag cement are compared with that with O.P.C.(ordinary portland cement) and are analyzed under various mix proportions and the dosage of AE agent. According to the experimental results, compressive strength and flexural strength of interlocking block with blast furnace slag cement are lower than that with OPC. Also the strength and the ratio of absorption decrease with higher dosage of AE agent. although interlocking block with OPC has better performance than that of blast furnace slag in the side of quality, it is worth while to use the blast furnace slag as materials of interlocking block considered the side of recycling of resources and economy.

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Rheological Properties of Cement Pastes Blended Finex-Slag Powder (파이넥스 슬래그 미분말을 혼합한 시멘트 페이스트의 유동특성)

  • Lee, Keun-Jae;Byun, Seung-Ho;Song, Jong-Taek
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.657-661
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    • 2009
  • In this study, rheological properties of cement pastes containing ground Finex-slag (4000, 6000, 7000 c$m^2$/g) were investigated bymini-flow test and coaxial cylinder viscometer. And also blast furnace slag(4000, 6000, 7000 c$m^2$/g) were used for comparison. According to the experimental results, Finex-slag and blast furnace slag showed very similar trend in the rheological properties of the cement pastes. The fluidity of cement pastes blended Finex-slag and blast furnace slag powder were improved by high replacement ratio. In the relationship of plastic viscosity and yield stress appeared the tendency of the proportion greatly. And in the relationship of plastic viscosity, yield stress and mini-flow appeared the tendency of the inverse proportion.

A Study on the Properties of Mixture Proportion and Compressive Strength of Concrete with the Kind of Mineral Admixtures (혼화재 종류에 따른 콘크리트의 배합 및 압축강도 특성에 관한 연구)

  • Lee Eun-Hi;Shon Myeong-Soo;Han Min-Cheoi;Cha Cheon-Soo;Kim Seong-Soo;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.51-54
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    • 2004
  • This paper investigated the results of mixture proportion and compressive strength of concrete incorporating mineral admixtures. W/B and contents of mineral admixtures were selected as test parameters. According to test results, use of mineral admixtures resulted in a reduction of fluidity and air contents caused by increased fine particles and absorption effect of FA on reduction of AE agent. Thus, increase of SP and AE agent was needed to maintain the same fluidity and air content as plain concrete. At early stage, use of CKD was beneficial to the compressive strength while at 28days. incorporation of FA and BS had favorable effect on the compressive strength.

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