• Title/Summary/Keyword: 슬래그계

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Environmentally Adaptive Stabilization of the Hazardous Heavy Metal Waste by Cementious Materials(II) (산업폐기물 중의 유해중금속의 환경친화적 안정화 처리(II))

  • Won, Jong-Han;Choi, Kwang-Hui;Choi, Sang-Hul;Lee, Hun-Ha;Sohn, Jin-Gun;Shim, Kwang-Bo
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1138-1142
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    • 2002
  • Slag cement and supersulfated slag cement were fabricated by mixing blast furnace slag and ordinary portland cement and adapted to solidify/stabilize heavy metal contained hazardous waste sludge. In case of slag cement, it showed continuous increase of their compressive strengths, which is attributed to the formation of the C-S-H, ettringite and monosulfate with STS sludge. However, BF and COREX sludge has a different shape and composition. therefore, adequate compressive strength could not be achieved with this slag cement. In case of the mixture of the each sludge like the STS-BF or the STS-COREX, the compressive strength over the standard level for disposing the wastes could be obtained with slag cement. The supersulfated slag cement that contain accelerators was very effective in solidifying the COREX sludge, which was difficult to solidify using different cement and obtained high compressive strength only for 3 days.

A Study on Chloride Attack Resistibility of Quaternary Concrete (4성분계 콘크리트의 염해 저항성능에 관한 연구)

  • Lee, Dong-Un;Park, Hyun-Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.2
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    • pp.1188-1194
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    • 2014
  • The purpose of this study is to estimate Chloride Attack Resistibility and mechanical properties of quaternary concrete adding fly ash, blast-furnace slag, and silica fume. Compressive strength, modulus of elasticity, chloride migration coefficient, charge passed from Rapid chloride penetration test(RCPT), and immersion testing in 3% NaCl are tested. Chloride migration coefficient and charge passed of quaternary concrete measured $0.032{\times}10^{-12}m^2/sec$ and 650 coulomb at 17 weeks, which are in a permitted limit. Also in immersion test, depth of chloride penetration and maximum chloride ion of quaternary concrete measured 3.7 mm and $10.211kg/m^3$ respectively. From the results, quaternary concrete adding fly ash, blast-furnace slag, and silica fume denotes improvement of mechanical properties and chloride attack resistibility.

Setting Properties of GGBS Powder According to Replacement of Ratio of CaO-Al2O3 Based Inorganic Binder (CaO-Al2O3계 무기결합재 사용량에 따른 고로슬래그 미분말의 응결특성)

  • Choi, Duck-Jin;Lee, Young-Jae;Choi, Se-Jin;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.78-79
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    • 2013
  • As a part of study to maximize the amount used of the ground granulated blast-furnace slag, the study deals with setting properties of paste that is mixed the ground granulated blast-furnace slag with CaO-Al2O3 based inorganic blinder. The results of the experiment show that the setting time is most fast in the mix of 25% rate of CaO-Al2O3 based inorganic blinder. It is generally needed 2 hours for work time in precast concrete products. In this study, this requirement is achieved when using the retarder of 0.5%.

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A Study on the Applicability of Estimation of Apparent Activation Energy of Blast Furnace Slag Contained Cement Using Calorimeter (열량계를 이용한 고로슬래그 혼입 페이스트의 겉보기 활성화 에너지 산정에 관한 연구)

  • Kim, Han-Sol;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.78-79
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    • 2021
  • It is necessary to calculate Apparent Activation Energy(Ea) in order to apply the equivalent age formula to predict compressive strength using the maturity method. For carbon reduction, it is necessary to consider the change of Ea by condition of GGBFS concrete, which is widely used today. In this study, as a basic study for the design of the compressive strength model of GGBFS concrete, the apparent activation energy of the GGBFS mixed paste was calculated through a calorimeter. The experiment was carried out at a hydration temperature of 10 to 30℃ with a paste test specimen having a GGBFS content of 0 to 80%. As a result, the GGBFS replacement rate of the paste increased, and Ea tended to increase as the temperature decreased.

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Pyro-metallurgical Treatment of used OA Parts for the Recovery of Valuable Metals (유가금속(有價金屬) 회수(回收)를 위한 PCB 스크랩의 건식처리기술(乾式處理技術))

  • Shin, Dong-Yeop;Lee, Sang-Dong;Jeong, Hyeon-Bu;You, Byung-Don;Han, Jeong-Whan;Jung, Jin-Ki
    • Resources Recycling
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    • v.17 no.2
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    • pp.46-54
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    • 2008
  • It is well known that PCB (Printed Circuit Board) is a complex mixture of various metals. In this study, pyro-metallurgical process was investigated to extract valuable metallic components from the PCB scrap. PCB scrap was shredded and oxidized to remove plastic materials, and then, quantitative analysis were made. 15 mass %$Al_2O_3-45$ mass %CaO-40 mass %$SiO_2$ and 32 mass %$SiO_2-20$ mass %$Al_2O_3-38$ mass %CaO-10 mass %MgO, were chosen as basic slag compositions which are determined based on the quantitative analysis of PCB scrap. During experiments a super kanthal rotating furnace was used to melt and separate metallic components. Moreover the revolution effect on was the recovery of valuable metals from PCB scrap also investigated.

Utilization of Ready-mixed Concrete Recycling Water Mixed with Hot-rolled Slag Containing C12A7 and Application Characteristics of Cement Mortar (C12A7을 함유한 열연슬래그를 혼입한 레미콘 회수수 활용 및 시멘트 모르타르의 적용 특성)

  • Kim, Young-Yeop;Lee, Han-Seung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.92-99
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    • 2021
  • CaO-based by-products composed of CaO, SO3, Al2O3, etc. are generally used as raw materials for CaO compounds. When applied to the recovered water of ready-mixed concrete, the hydration reaction of the powder material is accelerated and concrete performance can be improved. In this study, activated sludge was prepared to apply to the recovered water of ready-mixed concrete by mixing CaO-based hot-rolled slag(C12A7) in the recycling water of ready-m ixed concrete. Cem ent paste setting time and mortar compressive strength performance tests confirmed the effect on the hydration reaction. Therefore, the possibility of concrete application using activated sludge was confirmed.

Basic Characteristics of Slag Cement using CO2 Fixed Desulfurized Gypsum (CO2 고정 탈황석고를 사용한 슬래그 시멘트의 기초적 특성)

  • Chun-Jin Park;Jong-Ho Park;Sung-Kwan Seo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.25-31
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    • 2023
  • In this study, the basic properties of CO2 immobilized desulfurized gypsum (CFBG) and the possibility of being used as a stimulus for slag cement were reviewed, and performance evaluation was conducted through a concrete mixing test. The main components of CFBG were CaO and SO3, and CaO and SO3 increased as the drying temperature increased. The moisture content of undried CFBG was 15.7 %, the drying temperature was 1.7 % and the drying temperature was 0.03 % at 105 ℃. Mortar using CFBG tended to have a lower flow value as the drying temperature increased, and the compressive strength was equivalent to that of the FGB use mixture. As a result of the concrete experiment using CFBG SC, both slump and air volume satisfied the target range after 60 minutes, and the compressive strength tended to increase overall compared to the ternary binder mixture.

Grouting Properties using Thixotropic Material and Vibration Impact Method (가소성 그라우트 재료와 진동 및 충격을 부여하는 공법에 의한 지반개량 특성)

  • Keeseok Kim;Haseog Kim;Bong-hyun Baek;Simhun Yuk
    • Resources Recycling
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    • v.33 no.1
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    • pp.37-47
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    • 2024
  • In grouting, the LW method is commonly employed to induce the gelation of cementitious material using water glass, thereby restricting the extent of material injection. Nevertheless, challenges manifest when materials are lost before gelation, particularly in regions with high groundwater flow rates or significant subsurface voids. This study developed a thixotropic grout material using LFS and GGBFS to mitigate material loss during injection, with an assessment of its flow characteristics, durability in marine exposure, strength, and injection properties. The outcomes revealed that the thixotropic grout material exhibited flow ranging from 105 to 143 mm and enhanced strength and durability compared to the LW method. Furthermore, field tests substantiated that applying vibration and impact improved impermeability.

Properties of Mixing Proportions with Compressive Strength Level of High Flowing Self-Compacting Concrete (고유동 자기충전 콘크리트의 압축 강도수준별 배합특성)

  • Choi, Yun Wang;Jung, Jea Gwone;Jung, Woo Yong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.2A
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    • pp.163-169
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    • 2009
  • The research performed a test concerning the fluidity and strength of concrete manufactured by combining lime stone power, fly ash, and blast furnace slag into two and three component systems, aiming at evaluating rheological and dynamic properties of concrete by manufacturing High Flowing Self-Compacting according to the strength changes of three levels. As a result of the research, for High Flowing Self-Compacting of 30 MPa, the combination of lime stone power 20% and fly ash 30% for securing quality and strength and adjusting viscosity satisfied the required performance. For High Flowing Self-Compacting of 50 MPa, the combination of blast furnace slag 10% and fly ash 20% satisfied the fluidity and strength of the requirement performance. Also, for 70 MPa that has many power contents, the combination of blast furnace slag 20% and fly ash 10% for the increase of fluidity and the reduction of viscosity satisfied the required performance. It is judged that fly ash in all combinations can be used to secure viscosity and reduce concrete amount. In addition, it is judged that for High Flowing Self-Compacting according to the levels of compressive strength the combination of three component system including fly ash is more appropriate than the combination of two component system.

Investigation of Physical Properties and Self Healing of Hardener-Free Epoxy-Modified Mortars with GGBFS (고로슬래그미분말을 혼입한 경화제 무첨가 에폭시수지 모르타르의 물리적 성질 및 자기치유 검토)

  • Jo, Young-Kug;Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.80-87
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    • 2020
  • The purpose of this study is to investigate the physical properties and self-healing effects of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS). The EMMs with GGBFS were prepared with various polymer-binder ratios and GGBFS contents, and tested for strengths, adhesion in tension, water permeation and self-healing effects. The conclusions obtained from the test results are summarized as follows. The compressive strength of the EMMs with GGBFS is reduced with increasing polymer-binder ratios because of reduction of the degree of hardening in the EMMs, and is somewhat inferior to that of unmodified mortars. In the flexural and tensile strengths, the flexural strength of the EMMs is almost constant with increasing polymer-binder ratios. However, the tensile strength of the EMMs is gradually increased with increasing polymer-binder ratios. Regardless of the GGBFS contents, the adhesion in tension of the EMMs increases sharply with increasing polymer-binder ratios. The water permeation of the EMMs is remarkably reduced with increasing polymer-binder ratios and GGBFS contents. The self-healing effect of the hardener-free EMMs with GGBFS is improved with increasing water immersion period at a GGBFS content of 20%.