• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.340-343
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• 2005

광촉매 효율을 높이기 위해 WO$_{3}$를 첨가하여 제주에 산재해 있는 스코리아를 지지체로 하여 TiO$_{2}$ 및 WO$_{3}$/TiO$_{2}$ 광촉매를 이용하여 humic acid를 분해시킬 경우 반응영향인자에 따른 분해효율을 구한 결과 다음과 같은 결론을 얻었다. Humic acid의 분해시 Ca$^{2+}$를 첨가하였을 때가 첨가하지 않았을 때 보다 효율이 증대한 것은 이온강도가 증가하여 반발력을 감소하여 분해효율이 증대된 것이다. HCO$_{3}\;^-$를 첨가시 분해효율이 감소하는 것은 HCO$_{3}\;^-$이온이 OH radical scavenger로 작용했기 때문이다.

• Journal of Environmental Science International
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• v.20 no.11
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• pp.1437-1445
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• 2011

The adsorption performance of lead ion was studied using five zeolites (Na-P1, sodalite (SOD), analcime (ANA), nepheline hydrate (JBW), cancrinite (CAN)) synthesized from Jeju scoria. The adsorption performances of lead ion decreased in the order of Na-P1 > SOD > ANA > JBW > CAN. These results showed that the synthetic zeolite with a higher cationic exchange capacity showed a higher adsorption performance. The uptake of lead ion by synthetic zeolites were described by Freundlich model better than Langmuir model. The adsorption kinetics of lead ion by synthetic zeolites fitted the pseudo 2nd order kinetics better than pseudo 1st order kinetics. The effective diffusion coefficients of lead ion by synthetic zeolites were ten times higher than the zeolite A synthesized from coal fly ash.

• Korean Journal of Materials Research
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• v.18 no.3
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• pp.143-147
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• 2008

Fe compounds in scoria as distributed in the south-western area of Jeju Island were investigated using X-ray fluorescence spectroscopy, X-ray diffractometry, and $^{57}Fe$ $M{\ddot{o}}ssbauer$ spectroscopy. The samples were prepared from four parasite volcanoes. It was found that these samples are typical basalt comprised of $SiO_2$, $Al_2O_3$, Fe, and silicate minerals. The $M{\ddot{o}}ssbauer$ spectra showed doublets for olivine, pyroxene, and ilmenite as well as sextets for hematite and magnetite. The valence state of Fe is chiefly a 3+ charge state with a slight 2+ charge state. It is expected that these results will add to the body of information related to the formation mechanisms of Jeju Island.

• The Journal of Engineering Geology
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• v.19 no.2
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• pp.153-163
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• 2009

In this study, a series of triaxial tests on Jeju basalt were carried out and then rock strength parameters were estimated by the Mohr-Coulomb failure criterion and the Hoek-Brown failure criterion using the test results. The characteristics of both failure criterions were investigated through comparing the estimated rock strength parameters. As the result of the Mohr-Coulomb criterion, the cohesions and the internal friction angles are determined as 5.35 MPa and $50.25^{\circ}$ of Pyoseonri basalt, 16.99 MPa and $60.66^{\circ}$ of Trachy-basalt, and 2.33 MPa and $37.05^{\circ}$ of Scoria, respectively. The cohesions and internal friction angles were estimated by the Hoek-Brown failure criterion in the basis of the results of regression analysis. The cohesions and the internal friction angles are determined as 4.77 MPa and $52.47^{\circ}$ of Pyoseonri basalt, 14.69 MPa and $60.70^{\circ}$ of Trachy-basalt, and 2.22 MPa and $47.60^{\circ}$ of Scoria, respectively. As the result of comparison between the Mohr-Coulomb failure criterion and the failure envelope predicted by the Hoek-Brown criterion, the cohesion estimated by the Hoek-Brown criterion is usually lower than that obtained from the Mohr-Coulomb criterion, whereas the friction angle estimated by the Hoek-Brown criterion is higher than that obtained from the Mohr-Coulomb criterion.

• Journal of the Korean Geosynthetics Society
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• v.9 no.3
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• pp.19-27
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• 2010

In this study, a series of triaxial tests to Jeju basalt were carried out and then shear strength parameters of rock were estimated by the Lade's three-dimensional failure criterion. Also, the characteristics of shear strength parameters and failure plane which were estimated by the three-dimensional failure criterion were analyzed and this failure criterion was compared with the Mohr-Coulomb failure criterion. The variables of ${\eta}_1$ and m are derived from the relationship between ($I_1^3/I_3-27$) and ($P_a/I_1$) during the failure period using the Lade's three-dimensional failure criterion. The failure plane size of Tracy-basalt has the largest plane and that of Scoria has the smallest plane among other octahedral planes which is the three-dimensional failure plane. Also, the failure plane of Tracy-basalt is formed as a triangle and that of Scoria is formed as a circle among other octahedral planes. As the result of comparison with the triaxial test results and the Lade's failure envelope and the Mohr-Coulomb failure envelope, the Lade's failure envelope matched up under higher stress, while the Mohr-Coulomb failure envelope matched up under lower stress. Also, the Lade's three-dimensional failure plane is larger than the Mohr-Coulomb three-dimensional failure plane. It means that the shear strength parameters estimated by the Lade's failure criterion is larger than that of the Mohr-Coulomb failure criterion.

• Journal of the Korean Geotechnical Society
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• v.38 no.5
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• pp.47-59
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• 2022

A series of experiments were performed to investigate the design and application of a rubble-ground modification method with grout injection. A small-sized injection machine was designed, and the grouts with various mix proportions were injected into 25 mm aggregate using the designed small-sized injection machine. With the compressive strength of the grout ranging from 20 to 80 MPa, the uniaxial compressive strength of the grout-filling bodies with clean gravels was higher than 1/6th of the strength of grouts themselves. However, this fraction may reduce depending on the interface conditions. The erosion resistance of the hardened grout was evaluated, and it was determined that the grout with a strength greater than 15 MPa did not require erosion consideration. Moreover, a full-scale injection test was performed for 25 cm-sized rubbles in cages with a diameter greater than 1 m and a height of 1.2 m to evaluate the filling characteristics of the grout. Results from this test indicated that the grout flowability sensitively influenced the filling characteristics.

• Journal of Environmental Science International
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• v.11 no.1
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• pp.75-83
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• 2002

The removal performance of copper ion was studied using Na-P1 zeolites synthesized from Jeju scoria. The scoria which is found in large amounts in Jeju Island, was sampled at four regions, Jeju-shi Bonggae-dong(A). Pukcheju-gun Hanlim-eup Sangmyong-ri Mangoreum(B), Pukcheju-gun Hanlim-eup Keumag-ri(C) and Namcheju-gun Andeok-myun Dongkwang-ri(D). Synthetic Na-P1 zeolites used in this study were more effective than natural zeolite and scoria for the removal of copper ion. The removal performances of copper ion decreased in the order of Na-P1(D) > Na-P1(C) > Na-P1(B) > Na-P1(A) among Na-P1 synthesized from the scoria according to region. These results showed the same trend with cation exchange capacity(CEC) for each synthetic zeolite, i.e., the synthetic Na-P1 zeolite with a higher CEC showed a higher removal performance. The effective diffusion coefficients of copper ion by synthetic Na-P1 zeolites were one hundred and ten times higher than those by a pure zeolite 4A and the zeolite A synthesized from coal fly ash, respectively.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.585-588
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• 2006

The environment-friendly building material, photocatalyst/scoria/loess concrete, was prepared using scoria and loess (which have merits as building materials) and photocatalyst (which has the functions to compose the environmental contaminants and of self cleaning). In order to apply this material as a building material, the compressive and flexible strengths, and water absorptivity (which have been set by Korea Industrial Standard) were measured. The optimum mixing ratio of photocatalyst/scoria/loess concrete was obtained at the condition of $393kg/m^3$ of coarse aggregate, $802kg/m^3$ of fine aggregate in case of scoria, $80kg/m^3$ of loess, $12kg/m^3$ of photocatalyst, $400kg/m^3$ of cement, and $2kg/m^3$ of AE water reducing agent. The photocatalyst/scoria/loess concrete prepared by above mixing ratio of raw materials showed 25 MPa of compressive strength, $3.8{\sim}4.6$ MPa of flexible strength and $11.4{\sim}12.0%$ of water absorptivity, indicating that the quality of this material was suitable for Korea Industrial Standard (more than 21 MPa for compressive strength, more than 2.0 MPa for flexible strength in case of lightweight aggregate, and less than 15 % for water absorptivity in case of clay brick) for using as a building material.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.593-596
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• 2006

The environment-friendly building material, photocatalyst/scoria/loess concrete, was prepared using scoria and loess (which have merits as building materials) and photocatalyst (which has the functions to compose the environmental contaminants and of self cleaning). In order to apply this material as a building material, the compressive and flexible strengths, and water absorptivity (which have been set by Korea Industrial Standard) were measured. In order to know the environment-friendly characteristics of this material, several tests, such as, the tests of emissivity and emission power of far infrared ray and acoustic absorptivity, antibacterial test for Escherichia coli and Pseudomonas aeruginosa, antifungal test for mixed fungal strains, and deodorization test of ammonia were carried out. Moreover, the removal characteristics of NOx, and formaldehyde (HCHO) by photocatalyst/scoria/loess concrete were examined as the following different parameters: the removal characteristics of these contaminants with the substitution ratio and the kind of photocatalyst, light source, UV intensity of sunlight, relative humidity, intial NOx concentration.

• Journal of Environmental Science International
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• v.32 no.8
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• pp.563-572
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• 2023

Scoria from Jeju-island (Jeju scoria) was converted into zeolitic material (Z-SA) via zeolitification using the fusion/hydrothermal method. Jeju scoria could be synthesized into Z-SA to from a surface covered with Na-A zeolite crystals, which was confirmed through an analysis of X-ray diffraction peak patterns and scanning electron microscopy images. Jeju scoria and Z-SA were employed as adsorbents to evaluate the adsorption rate and adsorption capacities for Cu²⁺ and Zn²⁺ ions. The adsorption rates and isothermal adsorption capacities could be well fitted by the pseudo-quadratic adsorption kinetics and Langmuir adsorption isotherm, respectively. The maximum adsorption capacities (q_m) of Z-SA for Cu²⁺ and Zn²⁺ ions were found to be 163.36 mg/g and 120.51 mg/g, respectively, using the Langmuir adsorption isotherm. When Z-SA is synthesized from Jeju scoria via zeolitification using the fusion/hydrothermal method, Z-SA exhibits an adsorption capacity that is more than approximately 100 times the value exhibited by Jeju scoria. As a result, the synthesized Z-SA was regarded as an effective, economic adsorbent.