• Economic and Environmental Geology
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• v.42 no.4
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• pp.301-314
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• 2009

The Taebaeksan mineralized province, which is the most important one in South Korea, is rich in zinc-lead-tungsten-iron-copper-molybdenum-silver-gold mineral resources and has a diversity of deposit styles. These deposits principally coexist in time and space with porphyry-related epigenetic deposit such as skarn, hydrothermal replacement, mesothermal vein, and Carlin-like deposits. The magmatic-hydrothermal systems in the Taebaek fold belt is genetically characterized by the Bulguksa subvolcanic rocks(ca. $110{\sim}50\;Ma$) related to northwestward subduction of the paleo-Pacific Plate. The most important zinc-lead deposits in the area are the Uljin, Yeonhwa II and Shinyemi skarn, the Janggun hydrothermal replacement, and the Yeonhwa I intermediate-mixed (skarn/hydrothermal replacement) ones. In the present study, we present a compilation of metal production and mineral assemblage of the zinc-lead deposits. The metal difference of deposit styles in the area indicates a cooling path from intermediate-sulfidation to low-sulfidation state in the polymetallic hydrothermal system, reflecting spatial proximity to a magmatic source.

• Journal of the Mineralogical Society of Korea
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• v.20 no.1 s.51
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• pp.35-46
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• 2007

Shinyemi skarn deposits occur as Fe-Mo skarn type and Pb-Zn-Cu hydrothermal replacement type along the contact between Cretaceous Shinyemi granitoids and Cambro-Ordovician mixed limestone and dolostone sequence of the Choseon Supergroup. In the lower part of Western Shinyemi ore body two stages of skarn formation have been observed: the early, stage I (magnesian) skarn with Fe mineralization and the late, stage II(calcic) skarn with Mo mineralization. The stage I skarn spatially is overprinted by stage II skarn. The stage I skarn is predominantly composed of olivine, magnetite and diopside whereas, the stage II skarn is dominated by hedenbergite and garnet. The skarnification process occurred in two stages, both prograde and retrograde for stage I and stage II skarns. In stage I, the prograde skarns, mainly composed of anhydrous silicate minerals, were formed at relatively higher temperatures (about $400\;to\;550^{\circ}C$) under low $CO_{2}$ fugacity ($X_{CO2}<0.1$) conditions. On the other hand, the retrograde skarns that consisted of hydrous minerals were formed at lower temperatures (about $300\;to\;400^{\circ}C$).

• Geophysics and Geophysical Exploration
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• v.19 no.4
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• pp.212-219
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• 2016

The development of more advanced geophysical exploration techniques is necessary because the orebodies as yet discovered are increasingly changing in characteristics from shallow/high-grade to deep/low-grade. In this work, laboratory measurement of physical properties of rock samples and a field survey and interpretation of spectral induced polarization (SIP) have been conducted in a skarn metallic deposit, Gagok mine. The purpose of this study is that the applicability of SIP in the exploration of skarn metallic deposits is verified by the comprehensive interpretation between SIP characteristics of rocks obtained from the laboratory measurements and inverted survey results from the field data. In order to understand the SIP characteristics of each lithology, the data of eighty nine rock samples utilized in the previous studies were revaluated. The field survey was carried out using frequency of 0.25 Hz along a survey line designed for intersecting lithological boundaries and evaluating mineralized zones. The mineralized rocks were more conductive (low-resistivity) and capacitive (high-chargeability or strong-phase) than other rocks. Thus, SIP can be one of the very useful tools for the mineral exploration of the skarn deposits.

• Journal of the Mineralogical Society of Korea
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• v.27 no.3
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• pp.135-147
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• 2014

This study analyzed spectroscopic methods for characterization of skarn minerals and sphalerite occurring in Dangdu ore deposit, and effectiveness of portable spectrometer in skarn mineral resources exploration is discussed. The spectroscopic analyses identified clinopyroxene, garnet, epidote, calcite, chlorite and sphalerite where spectral curves of clinopyroxene, garnet, epidote, and sphalerite show single mineral spectral characteristics and those of chlorite are in a mixed form with calcite and clinopyroxene. The assessment of spectroscopic analyses based on XRD analysis and microscopic observation reveals that clinopyroxene, garnet, epidote correspond well with more than 80% of detection, but sphalerite, chlorite, and calcite showed below 50% of detection rate. It is expected that skarn deposit exploration using a portable spectrometer is more effective in detection of clinopyroxene, garnet, and epidote whereas spectroscopic data of sphalerite, chlorite, and calcite needs to be utilized as a supplementary data. For the effective detection of chlorite and calcite, their content in the samples needs to be sufficient.

• Journal of the Mineralogical Society of Korea
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• v.29 no.3
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• pp.141-153
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• 2016

The Manjang deposit is emplaced in Hwajeonri formation comprising limestone that is interbeded with slate and phyllite in the central Okcheon Group. It consists of the Main and the Central orebody of Cu-bearing hydrothermal vein deposit and the Western orebody of iron skarn deposit. Based on coexisting mineral assemblage the skarnization can be divided into prograde skarnization (stage I : clinopyroxene ${\pm}$ magnetite ${\pm}$ quartz, stage II : garnet + clinopyroxene ${\pm}$ magnetite ${\pm}$ quartz) and retrograde hydrothermal alteration (stage III: magnetite + amphibole + quartz ${\pm}$ garnet ${\pm}$ clinopyroxene ${\pm}$ chlorite ${\pm}$ epidote ${\pm}$ fluorite ${\pm}$ calcite, stage IV: fluorite ${\pm}$ pyrrhotite ${\pm}$ chalcopyrite ${\pm}$ amphibole ${\pm}$ quartz ${\pm}$ calcite). Diopside is abundant in stage I, and hedenbergite was produced in stage II and III. Garnet compositions change from grandite to andradite, which suggests a redox transition from relatively reduced to oxidized condition during the skarn formation. Magnetite in stage I and II has relatively constant Fe contents, while in the stage III it has increased Si and Ca concentrations. This variation could indicate that magnetite was more strongly affected by host rocks during the retrograde stage. Sulfur isotope compositions of pyrrhotite and chalcopyrite produced in stage IV are within the range of + 5.9~6.9 ‰, corresponding to igneous origin, but slightly high sulfur isotope values could be attributed to an interaction with host rocks, limestone.

• Economic and Environmental Geology
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• v.51 no.6
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• pp.493-507
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• 2018

The Wooseok deposit in Jecheon belongs to the Hwanggangri Mineralized Distict of the northeastern Ogcheon Metamorphic Belt. Its geology consists mostly of limestone of the Choseon Supergroup and the Cretaceous Muamsa granite intruded at the eastern area of the deposit. The deposit shows vertical occurrence of skarn and hydrothermal vein ores with W-Mo-Fe and Cu-Pb-Zn mineralization and skarn is developed only at lower levels of the deposit. Skarn minerals are replaced or cut by ore minerals in paragenetic sequence of magnetite-hematite, molybdenite-scheelite-wollframite, and higher abundances of pyrrhotite-chalcopyrite-pyrite-sphalerite-galena. Garnet has chemical compositions of $Ad_{65.9-97.8}Gr_{0.3-32.0}Pyr_{0.9-3.0}$, corresponding to andradite series, and pyroxene compositions are $Hd_{4.5-49.7}Di_{42.3-93.9}Jo_{0.5-7.9}$, prevailing in diopside compositions, both of which suggest oxidized conditions of skarnization. On the FeS-MnS-CdS ternary diagram, FeS contents of sphalerite in vein ores decrease with increasing MnS contents from bottom to top levels, possibly relating to W mineralization in deep and Pb-Zn mineralization in shallow level. Sulfur isotope values of sulfide minerals range from 5.1 to 6.8‰, reflecting magmatic sulfur affected by host rocks. W-Mo skarn and Pb-Zn vein mineralization in the Wooseok deposit were established by spatio-temporal variation of decreasing temperature and oxygen fugacity with increasing sulfur fugacity from bottom to top levels.

• Economic and Environmental Geology
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• v.40 no.1 s.182
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• pp.1-14
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• 2007

The Guemseong mine is located near the southern margin of the Jurassic Jecheon granitoids collectively with the Cambro-Ordovician mixed dolostone-limestone series of the Yeongweol Group, Choseon Supergroup. Here, two spatially distinct types of skarn formation have been observed. The upper transitional skarn is the calcic Mo skarn which has the mineral assemblage of $garnet+hedenbergite+epidote{\pm}wollastonite{\pm}magnetite{\pm}hematite{\pm}amphibole{\pm}chlorite{\pm}vesuvianite$ within the calcite marble. On the other hand, the lower proximal skarn occurs as a discordant magnesian Fe skarn at the contact of Mo-bearing aplitic cupolas with unidirectional solidification texture(UST) within the dolomitic marble. The magnesian Fe skarn has the mineral assemlage $olivine+diopside+magnetite+tremolite+serpentine+talc+chlorite{\pm}phlogopite$. The formation of two different types of skarn and ore mineralization in Geumseong mine have been attributed to multistage and complex metasomatic replacements that ultimately resulted in silicate-oxide-sulfide sequence of metasomatism. An early prograde stage with anhydrous skarn minerals such as olivine, clinopyroxene and/or garnet with magnetite, formed from high temperature (about $500^{\circ}\;to\;400^{\circ}C$) at an environmental condition of low $CO_2$ fugacity ($XCO_2<0.1$) and 0.5 kbar. The later retrograde stage with hydrous silicates such as amphibole, serpentine, phlogopite, epidote and chlorite with molybdenite or hematite, termed from relatively lower temperature (about $400^{\circ}\;to\;300^{\circ}C$).

• Economic and Environmental Geology
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• v.44 no.2
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• pp.109-122
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• 2011

The major Mo deposits in South Korea were formed during the Jurassic Daebo orogeny, the Late Cretaceous and the Tertiary post-orogenic igneous activities, and are characterized by a variety of genetic types such as pegmatite, greisen, skarn, porphyry and vein types. The Jangsu mine is a pegmatite-style deposit which is genetically related to the Jurassic ilmenite-series two-mica granite with the Mo mineralization age of $159.6{\pm}4.5$ Ma. The Geumseong mine occurs as a skarn/porphyry-style deposit associated with highly fractionated granite. Its age of Mo mineralization within aplitic cupola is about 96.5~l07.5 Ma. The Yeonil mine is a porphyry-style deposit, and the Geumeum mine is a veinlet-style deposit along the fracture zone with their mineralization ages of $58.4{\pm}1.6$ and $54.4{\pm}1.2$ Ma, respectively. The contrasts in the style of Mo mineralization in Korea reflect the different environment of the related magmatism. The Jurassic mineralization, being related to deep-seated granitoids, occurs as a pegmatite-style deposit, whereas the Cretaceous one, being related to subvolcanic granitoids, occurs as skarn/porphyry/vein-type ore deposits. The Tertiary Mo mineralization has a close relationship with the igneous activities associated with the Tertiary basin formation along the east coast, Korean peninsular.

• Economic and Environmental Geology
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• v.26 no.1
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• pp.41-54
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• 1993

The Ulsan Fe-W deposit, which can be classified as a calcareous skarn deposit, is represented by ore pipe consisting principally of magnetite and lesser amounts of scheelite with minor sulphides, sulphosaits, arsenides, sulpharsenides, etc. At Ulsan mine, metasomatic processes of skarn growth may be divided broadly into two stages based on the paragenetic sequence of calc-silicate minerals and their chemical composition; early and late skarn stages. Early stage has started with the formation of highly calcic assemblages of wollastonite, diopsidic clinopyroxene and nearly pure grossular, which are followed by the formation of clinopyroxenes with salite to ferrosalite composition and grandite garnets with intermediate composition. Based on these calc-silicate assemblages, the temperatures of early skarn formations have been in the ranges of $550^{\circ}$ to $450^{\circ}$. The calc-silicate assemblages formed during the earlier half period of late skarn stage show the enrichment of notable iron and slight manganese, and the depletion of magnesium; clinopyroxenes are hedenbergitic, and grandite garnets are andraditic. The formation temperatures during this skarn stage are inferred to have been in the range of $430^{\circ}$ to $470^{\circ}C$ at low $X_{CO_2}$ by data from fluid inclusions of late andraditic garnets. The later half period of late skarn stage is characterized by the hydrous alteration of pre-existing minerals and the formation of hydrous silicates. The main iron-tungsten mineralization representing prominent deposition of magnetite immediately followed by minor scheelite impregnation has taken place at the middle of early skarn stage, while complex polymetallic mineralization has proceeded during and after the late skarn stage. Various metals and semimetals of Fe, Ni, Co, Cu, Zn, As, Mo, Ag, In, Sn, Sb, Te, Pb and Bi have been in various states such as native metal, sulphides, arsenides, sulphosaits, sulpharsenides and tellurides.

• The Science & Technology
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• v.33 no.12 s.379
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• pp.82-83
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• 2000

최근 새로운 금속광상 발견으로 체계적인 이론의 도입과 탐사의 필요성에 따라 초청된 제임스박사. 그는 세계적으로 그 산출특성이 잘 알려진 칼린형 및 스카른 금광화작용의 모델을 적용하여 한국내 금광상의 잠재력과 광상의 발견에 유용한 재료를 제시할 계획이다.