• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.207-213
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• 2018

Nowadays, circulating fluidized bed combustor(CFBC) boilers system that can reduce environmental pollution particles are widely used in electric power plants. But the fly ash generated from CFBC boilers has lower $SiO_2$ and higher MgO and $SO_3$ contents and also has free CaO inducing expansion and abrupt initial setting of concrete. Therefore, revised KSL5405 for CFBC fly-ash as well as pulverized coal combustion(PCC) is introduced in the concrete field. In this study, the chemical properties and mechanical properties of blended cements with PCC and CFBC fly-ash produced in Korea are analyzed. The blended cement with only CFBC fly ash shows a lower length change than OPC but a higher flow change ratio. The compressive strength of blended cement paste with PCC and CFBC fly ash is slightly greater than that of cement paste with only PCC fly-ash. Based on the results, CFBC flyash blended cement products should be used with PCC flyash to ensure the material stability and material properties.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.417-428
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• 2021

The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MW_th Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MW_th Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m³. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO₂ concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.

• Korean Chemical Engineering Research
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• v.57 no.5
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• pp.687-694
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• 2019

In order to investigate the behavior of limestones which have been usually used for in-situ desulfurization reaction in circulating fluidized bed combustors, the attrition characteristics and calcination reactions of domestic limestones were analyzed in this study by using a thermogravimetric analyzer and an ASTM D5757-95 attrition tester. The average size distribution of limestones in circulating fluidized bed boilers have to be changed due to the attrition of particle-particle and particle-reactor wall and the calcination reaction. Domestic limestones might be used in commercial circulating fluidized bed boilers, but the attrition behaviors and particle size changes of limestones were varied. In calcination experiments at $850^{\circ}C$, the calcination reaction were varied with limestone samples. The calcination reaction time increased with an increase of particle size. Also, fine particles generated the attrition test of calcined limestone was 20% higher than those generated the attrition test of original limestone.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.400-407
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• 2019

Oxy-combustion with a circulating fluidized bed (Oxy-CFBC) technology has been paid attention to cope with the climate change and fuel supply problem. In addition, Oxy-CFBC technology as one of the methods for carbon dioxide capture is an eco-friendly that can reduce air pollutants, such as $SO_2$, NO and CO through a flue gas recirculation process. The newly developed $100kW_{th}$ pilot-scale Oxy-CFBC system used for this research has been continuously utilizing to investigate oxy-combustion characteristics for various fuels, coals and biomasses to verify the possibility of fuel diversification. The anthracite is known as a low reactivity fuel due to a lot of fixed carbon and ash. Therefore, this study aims not only to improve combustion efficiency of an anthracite, but also to capture carbon dioxide. As a result, compared to air-combustion of sub-bituminous coal, oxy-combustion of anthracite could improve 2% combustion efficiency and emissions of $SO_2$, CO and NO were reduced 15%, 60% and 99%, respectively. In addition, stable operating of Oxy-CFBC could capture above 94 vol.% $CO_2$.

• Magazine of RCR
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• v.12 no.2
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• pp.20-25
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• 2017

• Magazine of RCR
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• v.12 no.2
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• pp.26-32
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• 2017

• Magazine of RCR
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• v.12 no.2
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• pp.40-49
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• 2017

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.614-619
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• 2015

A plasma surface modification of powders has been carried out in a circulating fluidized bed reactor under reduced pressure. Polystyrene (PS) particles treated by plasma are grafted with polyethylene glycol (PEG) on the surface. The virgin, plasma-treated and grafted powders were characterized by DPPH method, FTIR, SEM and contact angle meter. The plasma-treated PS powders have well formed peroxide on the surface, By PEG grafting polymerization, PEG is well grafted and dispersed on the surface of the plasma-treated PS powders. The PEG-g-PS particle was successfully synthesized using the plasma circulating fluidized bed reactor under reduced pressure.

• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.846-853
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• 2017

Cold bed and $30kW_{th}$ pilot bed tests using circulating fluidized bed (CFB) were conducted to apply oxy-fuel technology for waste sludge combustion as a carbon capture and storage technology. In cold bed test, the minimum fluidization velocity ($u_{mf}$) and superficial velocity for fast fluidization was determined as 0.120 m/s and 2.5 m/s, respectively. In the pilot test, air and oxy-fuel combustion experiments for waste sludge were conducted using CFB unit. The flue-gas temperature in 21~25% oxy-fuel combustion was higher than that of air and up to 30% oxy-fuel combustion. In addition, the concentration of carbon dioxide was more than 80% with the oxygen injection range from 21% to 25% in oxy-fuel CFB waste sludge combustion.

• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 1999.11a
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• pp.109-113
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• 1999

겨울철 난방에너지와 여름철 냉방에너지 절감을 위한 자갈축열 태양열 온실의 설계자료를 얻고자 모형 자갈축열층과 이론적 해석을 통하여 축열층의 공기유동성 및 자갈축열층의 축열성능을 분석한 결과를 요약하면 다음과 같다. 1. 압출식으로 공기를 유동시켰을 경우 축열층내 풍속은 0.09-l.50㎧(평균 0.60㎧)범위였으며, 흡인식으로 공기를 유동시켰을 경우 축열층내 풍속은 0.15-0.90㎧(평균 0.46㎧)범위로 평균풍속은 압출식이 높게 나타났으나 축열층 가운데에서는 흠인식이 약 0.06㎧정도 높게 나타났다. 이러한 결과로 볼 때 자갈축열층내 공기순환을 위한 별도의 파이프 매설은 불필요한 것으로 판단된다. 2. 자갈축열층의 공극율이 증가할수록 축열량은 감소하였으며 순환팬 용량과 공극율에 따라 평균 2,133㎉/h-3,243㎉/h 정도 축열량 차이가 있는 것으로 나타났다. 3. 공극율이 0.45인 경우 축열층의 높이가 높을수록 자갈축열층의 온도는 서서히 증가하였으며, 축열층 높이 60cm이하에서는 축열 7시간이후부터는 축열량 변화를 거의 없는 것으로 나타났다. 4. 이러한 결과를 모형축열층에 있어 실험적으로 구해지는 축열 자갈층의 온도 및 축열량과의 비교 검증단계를 거쳐 온실규모에 필요한 적정 축열시스템을 산정할 수 있는 시뮬레이션 프로그램의 기초자료로 활용하고자 한다.