• Journal of the Korean Society of Combustion
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• v.13 no.3
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• pp.24-32
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• 2008

Steady Laminar Flamelet Model (SLFM) calculation is performed to compare the turbulent combustion characteristics of air combustion and oxy-combustion with $CO_2$ recirculation. Radiative heat loss is considered by the optically thin limit assumption. For more realistic simulation the first-order conditional moment closure(CMC) model is applied to SANDIA PILOTED FLAME D again for the oxidants of air and mixture of $O_2$ and $CO_2$. The chemical kinetic machanism for methane is GRI Mech 3.0. Results show that oxy flames are much more stable than air flames, while comparable stability is maintained with 65% $CO_2$ recirculation. The comparable peak temperature is maintained with 80% $CO_2$ recirculation. Higher the temperature, higher the fractions of intermediate species, CO and OH, due to dissociation.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.71-73
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• 2012

With numerical simulations, this study investigated the combustion and heat transfer of three different coals under air- and oxy-fuel combustion in a 100 MWe boiler. The boiler is retrofitted to an opposed-firing type while maintain the original furnace shape of downshot firing. The boiler achieved good combustion in both combustion modes for three coals tested. However, the contribution of gasification reactions by $CO_2$ and $H_2O$ significantly increased due to the lack of gaseous mixing. This was different from a typical front-wall firing boiler, which showed larger contribution of char oxidation during air-coal combustion. The wall heat flux was lower in oxy-coal mode at a $O_2$ level of 27%, which has to be considered in further development of the process.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.337-339
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• 2012

This study investigates the combustion and heat transfer characteristics of a 100MWe pulverized coal boiler retrofitted for demonstration of oxy-coal combustion. By computational fluid dynamics (CFD), the flame temperature and wall heat flux were compared for air-fuel and oxy-fuel combustion with different $O_2$ concentration in the oxidizers. It was found that the oxy-fuel combustion requires an $O_2$ concentration higher than 27 vol.% for the boiler to achieve the similar value of wall heat flux with air-fuel combustion.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.65-68
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• 2015

Agreeable to the latest enviromental problem, CCS(Carbon Capture&Storage) technology is more significant. As these issues, Oxy-Combustion is one of the technology that realize the CCS technology and large scale field test proceeding at other places. The aims of this research were to evaluate the combustion characteristics of pressurized oxy-combusition that is attract attention as the next generation power plant. The experiments were conducted using a laboratory-scale pressuized oxy-combustor. The fuel used was low calorific value syn-gas that is mainly composed of CO(60%), $H_2$(27%). The burner was used co-axial burner, to investigate combustion characteristics, temperature in the reactor and the flue gas compositions were measured.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.5
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• pp.481-488
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• 2013

Nitric oxide ($NO_x$) formation characteristics in non-premixed diffusion flames of methane fuels have been investigated experimentally and numerically by adding 10% ammonia to the fuel stream, according to the variation of the oxygen ratio in the oxidizer with oxygen/carbon dioxide and oxygen/nitrogen mixtures. In an experiment of coflow jet flames, in the case of an oxidizer with oxygen/carbon dioxide, the $NO_x$ emission increased slightly as the oxygen ratio increased. On the other hand, in case of an oxygen/nitrogen oxidizer, the $NO_x$ emission was the maximum at an oxygen ratio of 0.7, and it exhibited non-monotonic behavior according to the oxygen ratio. Consequently, the $NO_x$ emission in the condition of oxyfuel combustion was overestimated as compared to that in the condition of conventional air combustion. To elucidate the characteristics of $NO_x$ formation for various oxidizer compositions, 1D and 2D numerical simulations have been conducted by adopting one kinetic mechanism. The result of 2D simulation for an oxidizer with oxygen/nitrogen well predicted the trend of experimentally measured $NO_x$ emissions.

• Journal of the Korean Institute of Gas
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• v.23 no.1
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• pp.27-35
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• 2019

In order to solve the global warming and reduce greenhouse gas emissions, $CO_2$ capture technology was developed by applying oxy-fuel combustion. But there has been such a problem that its economic efficiency is low due to the high price of oxygen gases. ASU is known to be most suitable method to produce large quantity of oxygen, to reduce the oxygen production cost, the efficiency of ASU need to be improved. To improve the efficiency of ASU, exergy analysis can be used. The exergy analysis provides the information of used energy in the process, the location and size of exergy destruction. In this study, the exergy analysis was used for process developing and optimization of large scale ASU. The process simulation of ASU was conducted, the results were used to calculate the exergy. As a result, to reduce the exergy loss in the cold box of ASU, a lower operating pressure process was suggested. It was confirmed the importance of heat leak and heat loss reduction of cold box. Also, the unit process of ASU which requires thermal integration was confirmed.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.1
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• pp.30-39
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• 2017

Interests in fuel cell based power generation systems are on the steady rise owing to various advantages such as high efficiency, ultra low emission, and potential to achieve a very high efficiency by a synergistic combination with conventional heat engines. In this study, the performance of a hybrid system which combined a molten carbonate fuel cell (MCFC) and an indirectly fired micro gas turbine adopting carbon dioxide capture technologies was predicted. Commercialized 2.5 MW class MCFC system was used as the based system so that the result of this study could reflect practicality. Three types of ambient pressure hybrid systems were devised: one adopting post-combustion capture and two adopting oxy-combustion capture. One of the oxy-combustion based system is configured as a semi-closed type, while the other is an open cycle type. The post-combustion based system exhibited higher net power output and efficiency than the oxy-combustion based systems. However, the semi-closed system using oxy-combustion has the advantage of capturing almost all carbon dioxide.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.6
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• pp.647-653
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• 2007

The ultimate objective of this study is to develop a reliable oxygen-enriched combustion techniques especially for the case of the flue gas recycling in order to reduce the $CO_2$ emissions from practical industrial boilers. To this end a systematic numerical investigation has been performed, as a first step, for the resolution of the combusting flame characteristics of lab-scale LNG combustor. One of the important parameters considered in this study is the level of flue gas recycling calculated in oxygen enriched environment. As a summary of flame characteristics, for the condition of 100% pure $O_2$ as oxidizer without any flue gas recycling, the flame appears as long and thin laminar-like shape with relatively high flame temperature. The feature of high peak of flame temperature is explained by the absence of dilution and heat loss effects due to the presence of $N_2$ inert gas. The same reasoning is also applicable to the laminarized thin flame one, which is attributed to the decrease of the turbulent mixing. These results are physically acceptable and consistent and further generally in good agreement with experimental results appeared in open literature. As the level of $CO_2$ recycling increases in the mixture of $O_2/CO_2$, the peak flame temperature moves near the burner region due to the enhanced turbulent mixing by the increased amount of flow rate of oxidizer stream. However, as might be expected, the flue gas temperature decreases due to presence of $CO_2$ gas together with the inherent feature of large specific heat of this gas. If the recycling ratio more than 80%, gas temperatures drop so significantly that a steady combustion flame can no longer sustain within the furnace. However, combustion in the condition of 30% $O_2/70% $ $CO_2$ can produce similar gas temperature profiles to those of conventional combustion in air oxidizer. An indepth analyses have been made for the change of flame characteristics in the aspect of turbulent intensity and heat balance.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.05a
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• pp.551-556
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• 2003

이산화탄소를 줄이기 위한 대책으로 국가 간 기후변화협약이 1992년 6월에 유엔환경개발회의에서 채택되었고 그 후속조치로 1997년 12월 교토에서 OECD 국가들에 대한 선진국 의무를 강화하는 교토의전서가 채택되기에 이르렀다. 국내의 의무부담 적용이 예상되는 2012년에는 국내 이산화탄소 예상 발생량 189백만 탄소톤 중 상당량의 탄소톤을 감축해야 할 것으로 추정된다.(중략)

• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.60-66
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• 2001

Combustion using pure oxygen instead of air is an energy saving technology that can increase thermal efficiency by the improvement of burning rate and ultra high temperature flame, being used on the industrial spot. But information about it is not so enough yet. Flame figure, temperature distribution and emission concentration were measured with oxygen excess ratio and swirl number in a turbulent diffusion flame to investigate the combustion characteristics using pure oxygen. The results showed that flame figure became different as long as oxygen excess ratio varied and that concentration of NO and CO increased suddenly around ${\lambda}$=1.5.