• Transactions of the Korean hydrogen and new energy society
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• v.21 no.6
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• pp.553-560
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• 2010

The characteristics of syngas-oxyfuel combustion has been investigated experimentally in the present study. Experimental measurements were conducted to aid a fundamental design of a syngas-oxyfuel combustor with a double coaxial burner configuration. To examine the effects of different syngas fuels on combustion characteristics, various fuel types are utilized such as commercial coal gases (Texaco, Shell), COG (cokes oven gas), and $CH_4$ as a main component of natural gas. $CO_2$ was added to the four fuel types as a diluent gas to reduce the flame temperature. The flame images and emission characteristics of NOx and CO were examined for various equivalence ratio and $CO_2$ dilution ratio. The results show that CO emission was rapidly increased as equivalence ratio approached the stoichiometry condition by reducing the amount of oxygen. As the $CO_2$ dilution increased, CO emission increased while NOx emission decreased due to reduced flame temperature. When the syngas-oxyfuel combustor is operated with 20~40% of $CO_2$ dilution ratio, the CO and NOx emission levels were kept below 50 ppm and 25 ppm, respectively, with a high concentration of $CO_2$ over 95 vol.% in exhaust gases.

• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.162-169
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• 2005

The performance of oxygen combustion with $CO_2$ feeding was investigated in a pyrex tube furnace. The inverse type multi-hole burner was used for improving mixing and wide operating range. It introduced oxygen, fuel, and oxygen, respectively, from center tube to outer tubes. Oxygen combustion characteristics with excess oxygen ratio, oxygen feeding ratio, and $CO_2$ feeding flow rate were studied to optimize the operating condition and to apply the oxygen combustion with recirculation of flue gas to a real furnace. This paper presents results on the effect of $CO_2$ feeding flow rate on the structure of the flames and concentrations of NO and CO emissions. The visible flame length was shortest due to well mixing between fuel and oxygen when the oxygen feeding ratio was 0.25. The NO emission was reduced drastically regardless of excess oxygen ratio when the $CO_2$ feeding flow rate was larger than 15 lpm. The CO emission is varied by changing the $CO_2$ feeding flow rate but the CO emission characteristics is highly affected by excess oxygen ratio. When the excess oxygen ratio is below ${\lamda}=1.1$, the CO emission increased as the $CO_2$ feeding flow rate increased.

• Journal of computational fluids engineering
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• v.18 no.3
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• pp.1-7
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• 2013

A pure oxygen combustion technology is crucial in Carbon Capture and Storage (CCS) technology especially in capturing of $CO_2$, where CCS will reduce 9 $GtCO_2$ by 2050, which is 19% of the total $CO_2$ reduction amount. To make pure oxygen combustion feasible, a regenerative system is required to enhance the efficiency of pure oxygen combustion system. However, an existing air combustion technology is not directly applicable due to the absence of nitrogen that occupies the 78% of air. This study, therefore, investigates the heat and fluid flow in a regenerative system for pure oxygen combustion by using commercial CFD software, FLUENT. Our regenerative system is composed of aluminium packed spheres. The effect of the amount of packed spheres in regenerator and the effect of presence or absence of a bypass of exhaust gas are investigated. The more thermal mass in regenerator makes the steady-state time longer and temperature variation between heating and regenerating cycle smaller. In the case of absence of bypass, the regenerator saturates because of enthalpy imbalance between exhaust gas and oxygen. We find that 40% of exhaust gas is to be bypassed to prevent the saturation of regenerator.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.479-486
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• 2016

The efficient steam drum should be required to reduce carbon oxide emissions and heat recovery in oxygen converter hood system. However, steam generation is limited to the time of the oxygen blowing period, which is intermittent or cyclical in operation of steel-making process. Thus, steam drum should be optimized for an effective steam generation during the oxygen blowing portion of the converter cycle. In this study, a three-dimensional computational fluid dynamics (CFD) model has been developed to describe the impacts of changing various operating conditions and geometric shape on thermo-fluid characteristics and performance of the steam drum. This model encompasses not only fluid flow and heat transfer but also evaporation and condensation at the interfacial surface in the steam drum by using VOF (Volume of Fluid) method. To validate the prediction performance of this model, comparison of the steam flow rate between numerical and experimental result has been performed, resulting in the accuracy of the relative error by less than 3.2%.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.41 no.5
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• pp.493-504
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• 2021

The target site, Goejeongcheon flows through downtown of Saha-gu, Busan and it connects to the Nakdong-gang estuary. But non-point pollutants and sewage sludge are partially flowing into the stream and deposited. As a result, dissolved oxygen concentrations of the stream were observed close to the anaerobic condition. Multistage Vortex Aerator was applied for restoring this urban stream. It dissolves oxygen by repeatedly causing collisions between water and oxygen by vortex flow. The changes in water quality and odor were monitored for 2 months while circulating 1 m³/min of water with 22 ppm dissolved oxygen. As a result of the operation, the dissolved oxygen was improved from slightly Bad (4)~Bad (5) to Good (1b)~Normal (3) grade, and the total phosphorus concentration was decreased by 76 % on average. In the case of complex odor, a maximum reduction of 84.5 % was observed on the day the entire river was anaerobic. Through this study, we evaluated the feasibility of applying pure oxygen and Vortex Aerator for the the stream restoration. It is expected that the results of this study can be used for full-scale design.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.904-909
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• 2012

Acid sulfate soil (ASS) and potential acid sulfate soil (PASS) are distribution in worldwide and originate from sedimentary process, volcanic activity, or metamorphism and are problematic in agriculture and environmental due to their present and potential acidity developed by the oxidation. The PASS was defined as soil materials that had sulfidic layer more than 20 cm thick within 4 m of the soil profile and contained more than 0.15% of total-sulfur (T-S). A tentative interpretative soil classification system was proposed weak potential acid sulfate (T-S, 0.15-0.5%), moderate potential acid sulfate (T-S, 0.5-0.75%) and strong potential acid sulfate (T-S, more than 0.75%). PASS due to excess of pyrite over soil neutralizing capacity are formed. It provides no information on the kinetic rates of acid generation or neutralization; therefore, the test procedures used in acid base account (ABA) are referred to as static procedures. The net acid generation (NAG) test is a direct method to measure the ability of the sample to produce acid through sulfide oxidation and also provides and indication. The NAG test can evaluated easily whether the soils is PASS. The samples are mixed sandy loam and the PAS from the hydrothermal altered andesite (1:3, 1:8, 1:16, 1:20, 1:40, 1:80 and 1:200 ratios) in this study. We could find out that the NAG pH of the soil containing 0.75% of T-S was 2.5, and that of the soil has 0.15% of T-S was 3.8. NAG pH test can be proposed as soil classification criteria for the potential acid sulfate soils. The strong type has NAG pH of 2.5, the moderate one has NAG pH of 3.0, and the weak one has NAG pH of 3.5.

• Clean Technology
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• v.24 no.3
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• pp.212-220
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• 2018

Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.255-260
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• 2003

Characteristics of methane jet diffusion flames using pure oxygen with recirculating $CO_{2}$ as an oxidizer were investigated experimentally. A coflow burner was considered, and the diameter of confinement was larger than that of the coflow. No stabilized flame could be observed over 75% of $CO_{2}$ volume percent. A comparison between air and $O_{2}/CO_{2}$ mixture was made in terms of liftoff velocity, flame liftoff height, and blowout conditions. As results, more stable flame could be observed with $O_{2}/CO_{2}$ mixture for the case of having similar flame temperature.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.229-234
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• 2006

The oxy-fuel combustion heating characteristics is investigated experimentally by measuring furnace and steel temperature variations for batch type furnace simulator with a specially designed low NOx oxy-fuel burner. Economics of using oxy-fuel combustion is confirmed and, the furnace and steel temperature variations for different heating conditions are compared to deduce optimal heating control pattern for energy savings and rapid uniform heating. High $CO_2$ concentration (> 80-90%), low NOx (< 40ppm) and CO (< 10ppm) are measured in the flue gas. Temperature differences (< $30^{circ}C$) inside the furnace and steel are reduced relatively by increasing the burner jet momentum.

• Journal of Korean Society of Water and Wastewater
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• v.13 no.4
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• pp.27-34
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• 1999

An experimental study on improvement of the paper-mill wastewater treatment using the pure oxygen activated sludge process was conducted. The effects of hydraulic retention time(HRT) and BOD loading on organic removal efficiency were investigated. The BOD removal efficiencies were above 90% under all examined HRTs except for HRT of 3 hours. The increase of HRT from 3 hours to 6 hours, and to 12 hours significantly improved BOD and COD removal efficiencies, respectively. However, additional increase of HRT did not affect organic removal efficiency. F/M ratio change at fixed HRT did not affect organic removal efficiency. However, F/M ratio investigated in this study(0.11~1.98kgBOD/kgMLVSS/day) was 5 times greater in maximum than that of conventional activated sludge process, which implies that pure oxygen activated sludge process can treat wastewater with high organic strength. Under the same HRT, the volumetric BOD loading change cause no effect on organic removal efficiency also.