• Journal of the Korean Chemical Society
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• v.23 no.6
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• pp.374-384
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• 1979

Hydration scheme and hydration energy are determined in ${\alpha}$ cage of zeolite NaA. The selectivity between Na(1) and Na(2) is determined from energy calculation. The waters in ${\alpha}$ cage form a distorted dodecahedral cage. The average binding energies of water(1), water(2) and water(3) are -29.847, -25.344 and -15.888 kcal/mole respectively. The positions of oxygens of hydrated waters are in good agreement with the X-ray data. The heat of immersion curve is also obtained. This result is in good agreement with the differential heat of sorption curve obtained from differential thermal analysis. It is concluded that theoretical method provides considerable uses in the determination and understanding of the hydration and interaction energy of zeolites sorbate binding.

• Journal of the Korean Society of Food Science and Nutrition
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• v.46 no.3
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• pp.374-380
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• 2017

Image analysis and k-mean clustering were conducted to develop a grading system of dried sea cucumber (SC) based on rehydration rate. The SC images were obtained by taking pictures in a box under controlled light conditions. The region of interest was extracted to depict the shape of the SC in a 2D graph, and those 2D shapes were rendered to build a 3D model. The results from the image analysis provided the morphological features of the SC, including length, width, surface area, and volume, to obtain the parameters of the k-mean clustering weight. The k-mean clustering classified the SC samples into three different grades. Each SC sample was rehydrated at $30^{\circ}C$ for 40 h. During rehydration, the flux of each grade was analyzed. Our study demonstrates that the mass transfer rate of SC increased as the surface area increased, and the grade of SC was classified based on rehydration rate. This study suggests that the optimal rehydration process for SC can be achieved by applying a suitable grading system.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.317-328
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• 2016

This research intends to understand the impact of super-absorbent polymer (SAP) as an internal curing agent in Ultra-High Performance Concrete (UHPC). Two different types of SAPs of acrylic acid (SAP_AA) and acrylic acid-co-acrylamide (SAP_AM) were examined with UHPC formulation. Isothermal calorimetry and x-ray diffraction experiments revealed the impact of polymers with the different chemical bonds on cement hydration. To test its feasibility as a shrinkage reducing admixture for UHPC, a series of experiments including flowability, compressive strength, rapid chloride permeability and autogenous shrinkage profile was performed. While both SAPs showed a reduction in autogenous shrinkage, it has been concluded that the SAP size and chemical form significantly affect the performance as an internal curing agent in UHPC by controlling cement hydration and porosity modification. Between the tested SAPs, SAP_AM which absorbs more water in UHPC than SAP_AA, shows better mechanical and durability performance.

• Journal of the Korea Concrete Institute
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• v.14 no.2
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• pp.137-147
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• 2002

Maturity models involving curing temperature and curing ages have been widely used to predict concrete strength, which can accurately estimate concrete strength. However, they may not consider physical quantities such as the characteristics of hydrates and the capillary porosity of microstructures associated with strength development. In order to find out the effects of both factors on a strength increment, the hydration model and the estimation method of the amount of capillary porosity were established, and the compressive strength test of concrete nth various water/cement ratios was carried out considering two test parameters, curing temperature and curing age. In this study, by analyzing the experimental results, a strength estimation model for early-age concrete that can consider the microstructural characteristics such as hydrates and capillary porosity was proposed. Measured compressive strengths were compared with estimated strengths and good agreements were obtained. Consequently, the proposed strength model can estimate compressive strength of concrete with curing age and curing temperature within an acceptable error.

• Horticultural Science & Technology
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• v.28 no.5
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• pp.762-767
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• 2010

This study was conducted to investigate the influence of formulation of fungicides on epicuticular waxes in 'Campbell Early' grapes. Non-bagged and bagged berries were treated with wettable powder, suspension concentrate and emulsifiable concentrate 15 days after full bloom (DAFB) and 48 DAFB (veraison), respectively. Fruit skin was observed by naked eye and scanning electron microscope (SEM) at harvest. Remarkable white blots were observed on the berries treated 48 DAFB in the order of wettable powder, suspension concentrate, and emulsifiable concentrate. The observation by SEM showed all formulations of fungicides damaged the ultra-structure of epicuticular waxes; also, an unknown substance was observed on treatment with wettable powder and suspension concentrate. Moreover epicuticular wax appeared to be melting on the grapes treated with emulsifiable concentrate. Also, non-bagged grapes showed serious contamination of epicuticular wax by some unknown substance, but bagged grapes had only fungicides' traces.

• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.581-586
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• 2005

High-performance concrete (HPC), which is particularly sensitive to self-desiccation, is required to be durable even in severe environmental conditions, i.e. costal area, cold district, etc. However, in recent years, some attention was particularly given to cracking sensitivity of high performance concrete at early age. It has been argued and demonstrated experimentally that such concrete undergoes autogenous shrinkage due to self-desiccation at early age under restrained condition, nd, as a result, internal tensile stress may develop, leading to micro cracking and macro cracking. This shrinkage-introduced crack produces a major serviceability problem for concrete structures. One possible method to reduce cracking due to autogenous shrinkage is the addition of expansive additive. Tests conducted by many researches have shown the beneficial effects of addition of expansive additive for reducing the risk of autogenous shrinkage-introduced cracking. However, the research on hydration model of expansion additive has been hardly researched up to now. This paper presents a study of the hydration model of Ettringite-Gypsum type expansive additive. As a result of comparing forecast values with experiment value, proposed model is shown to expressible of hydration of expansive additive.

• Magazine of the Korea Concrete Institute
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• v.10 no.2
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• pp.99-107
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• 1998

콘크리트는 일반적으로 수회시멘트풀과 골재로 이루어진 이상의 복합체이지만 미시적으로는 수화시멘트풀과 골재, 그리고 천이영역으로 이루어진 삼상의 복합체이다. 수화시멘트풀과 골재 사이에서 형성되는 천이영역은 국부적으로 공극률이 높으므로 콘크리트의 강성과 강도에 많은 영향을 끼친다. 본 논문에서는 이러한 천이영역의 특성을 고려하여 콘크리트의 탄성계수를 추정하기 위해 이원 삼중 내포물 모델을 제안하였다. 제안된 모델에 의한 탄성계수의 추정결과는 실험결과와 비교하여 잘 일치하였으며 제안된 모델은 실험적으로 구하기 힘든 천이영역의 특성을 구하는데 사용될 수 있다.

• Journal of the Korea Concrete Institute
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• v.14 no.1
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• pp.118-125
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• 2002

Hydration is the main reason for the growth of the material properties. An exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development of all material properties and the formation of microstructure should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of W/C ratio on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The tatter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration. In this study, the effects of chemical composition of cement, W/C ratio, temperature, and moisture conditions on the degree of hydration are considered. Parameters that can be used to indicate or approximate the real degree of hydration are liberated heat of hydration, amount of chemically bound water, and chemical shrinkage, etc. Thus, the degree of heat liberation and adiabatic temperature rise could be determined by prediction of degree of hydration.

• Magazine of the Korea Concrete Institute
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• v.7 no.5
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• pp.164-171
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• 1995

Drying shrinkage and hydration heat are important factors on the initiation of the crack in con crete at early age. Therefore, the stress caused by hydration heat and drying shrinkage should be .analyzed to predict whether the crack occurrs or not. And, mechanical properties of early age concrete is also required for the predicting crack formation In this study, non-destructive test method of resonance frequency was used to find the relation between dynamic modulus and mechanical properties of concrete in early age. Test results were compared with existing equations, and a new equation based on test. results in this study and other data was also proposed

• Journal of the Korea Institute of Building Construction
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• v.20 no.1
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• pp.11-18
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• 2020

Carbon nanotubes are used in various industries with their excellent mechanical properties and electrical conductivity. In the construction industry, research is being conducted to give self-sensing capabilities to structures, but the results of experiments vary among researchers, and the analysis is insufficient. Therefore, in this study, the hydration and electrical properties of MWCNT-added cement pastes were measured. The electrical resistance values of hydration heat, porosity, Rietveld quantitative analysis, compressive strength, and distance were measured.. The heat resistance, porosity, Rietvelt quantitative analysis, compressive strength and distance were measured according to electrical resistance. Experimental results showed that the heat of hydration decreased with increasing MWCNT. XRD Rietveld quantitative analysis showed that there was no significant difference in the amount of hydration products with increasing addition rate of MWCNT. As a result of SEM analysis, the MWCNT is agglomerated by van der Waals forces, and this area is considered to be caused by voids and weak areas. The electrical resistance value decreases as the addition rate is increased, and thus may play a role for magnetic sensing in the future.