• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.102-109
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• 2024

In order to use limestone powder as a material for concrete, the mechanical and durability characteristics of cement matrices manufactured by varying the substitution rate were evaluated. In general, limestone powder did not contribute to the cement hydration reaction, so as a result of the compressive strength test of cement mortar using it, the compressive strength decreased as the substitution rate increased. However, as a result of evaluating the durability performance of cement mortar using limestone powder, such as chloride ion penetration resistance, carbonation resistance, and chemical attack resistance, small particles of limestone powder showed superior results compared to the unsubstituted control mortar due to the micro-filler effect of filling the fine pores inside the cement matrix. Therefore, limestone powder is expected to be used as an effective method for improving the durability of concrete. In this study, the durability was evaluated by changing the mixing amount of limestone powder to 0 %, 5 %, 10 %, and 15 %, but it is judged that it is necessary to study in more detail the effect on the durability by changing the end and mixing amount of limestone powder to various levels in the future.

• Journal of the Korea Concrete Institute
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• v.23 no.2
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• pp.225-233
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• 2011

The volume change in concrete takes place with changes in temperature and water content immediately after concrete casting. In the early age stage, the thermal and drying shrinkages can cause cracks that are very crucial to the durability of concrete. It was reported that when the cement with lightly-burnt MgO powder was used, the shrinkage of concrete can be reduced. This study investigates fundamental properties of cement composites with lightly burnt MgO powder by performing various experiments. The stability test results verified that MgO powder in cement composites does not cause any abnormal expansion. Also, the hydrate product analysis results obtained from MgO cement paste showed that MgO powder reduces the shrinkage at the longterm ages. In addition, the cement composites containing the proper amount of MgO powder could improve compressive strength. Finally, the shrinkage reduction from using MgO powder can be optimized by increasing MgO replacement level and curing temperature.

• Composites Research
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• v.25 no.4
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• pp.110-116
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• 2012

Recently, the development and field applications of Ternary Blended Cement(TBC), where blast furnace slag and fly ash are recycled in Ordinary Portland Cement(OPC) in order to obtain improvements in the durability and heat of hydration reduction performance in large scale civil structures, have been increasing. Also, there are continuing efforts by construction companies to reduce the construction time with the aim of reducing construction costs. Therefore, there is a need to improve the performance of TBC, which has a relatively slow early strength development. In order to improve the early strength of TBC mortar, the compressive strength, SO3 content, and SEM analysis was determined in this study on mortar with the fineness and content of blast furnace slag and anhydrite regulated. As a result, to secure the early strength of TBC mortar, using blast furnace slag with a fineness of approximately $4,200cm^2/g$, adding 3.5% anhydrite with a fineness of approximately $10,000cm^2/g$, and managing the $SO_3$ content to roughly 3.72% was found to provide the most outstanding early strength properties.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.488-495
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• 2017

In this study, we conducted the kinetic hydration modeling of OPC and the final product according to the substitution ratio of GGBS by using the geochemical code, GEMS, in order to calculate the thermodynamic equilibrium. The thermodynamic data was used by GEMS's 3rd party database, Cemdata18, and the cement hydration model, the Parrot & Killoh model was applied to simulate the hydration process. In OPC modeling, ion concentration of pore solution and hydration products by mass and volume were observed according to time. In the GGBS modeling, as the substitution rate increases, the amount of C-S-H, which contributes the long-term strength, increases, but the amount of Portlandite decreases, which leads to carbonation and steel corrosion. Therefore, it is necessary to establish prevention of some deterioration.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.3
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• pp.240-245
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• 2013

The optimum binder ratio of the low heat mass concrete for LNG tank was evaluated in the present study. Three types of binder such as OPC I, ground granulated blast-furnace slag powder were mixed and were used. Also fine particle cement and activator were used to raise an early age strength development and ground limestone was used to reduce the cost. As a result of the study, mix ratio II (30:30:40) was suitable for Bottom Center and mix ratio III(40:30:30) was suitable for Roof based on compressive strength and semi-adiabatic temperature.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.509-516
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• 2023

The use of sulfur(S) in concrete has been variously studied as a way to improve salt resistance in concrete. However, sulfur is a solid material and is difficult to powder, which has disadvantages in its usability as an admixture or mixture for cement and concrete. For these problem, polymers such as dicyclopentadiene have been used to modify sulfur, but this also exists in a sticky state after modifying and does not improve the fundamental problem. So, reforming sulfur with slaked lime and the effect on cement hydration was examined by reforming sulfur with slaked lime, and the following conclusions were obtained. Depending on the reaction conditions, slaked lime modified bio-sulfur exists in a slurry state containing unreacted sulfur, unreacted slaked lime, calcium-sulfur(Ca-S) compounds and water. When slaked lime modified bio-sulfur is used as a cement mixture, salt resistance of concrete with slaked lime modified bio-sulfur is to be superior to that of plain concrete. This is believed to be because structure of cement hydrates with slaked lime modified bio-sulfur is to be more dense to that of plain cement hydrates by the continued presence of ettringite and can be used as a cement mixture in concrete.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.110-111
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• 2021

The eggshell is a type of bio-waste which is considered hazardous to the environment. In this research, the waste eggshell is utilized as a potential filler in cementitious material. This study has measured by zeta potential to analyze the interaction between the surface of the filler and the calcium ion in the solution. Meanwhile, the effect of eggshell powder on cement hydration process has been determined by isothermal calorimeter. The results show that the surface of eggshell powder have a strong adsorption of Ca2+, and addition of the eggshell powder provides a heterogeneous nucleation site for cement, which promotes the growth of hydration products.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2010.04a
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• pp.758-761
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• 2010

본 연구에서는 원전격납구조물과 같이 고품질의 대형 매스콘크리트의 설계, 시공, 품질예측 및 관리에 필요한 구조물 건전성 평가시스템 구축의 일환으로 수화열 예측 프로그램을 개발하였다. 개발된 수화열 예측 프로그램은 국내에서 생산된 시멘트 및 결합재의 화학조성성분, 분말도와 같은 기초정보 및 배합정보를 입력하여 경시변화에 따른 수화발열량을 계산하는 방식으로서 기존의 연구결과를 바탕으로 개발되었다. 개발된 프로그램은 배합환경조건을 고려하여 초기배합온도 3종류(10, 20, $30^{\circ}C$)로 실험한 단열온도상승 실험 결과와 비교해 보았으며, 좋은 상관성을 나타냄을 확인할 수 있었다.

• Journal of the Korea Institute of Building Construction
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• v.9 no.4
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• pp.139-145
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• 2009

This study presents an estimation of the strength development of concrete considering the equivalent age using fine particle cement (FC), which is manufactured according to the classification process. Contents and W/B were considered as experimental parameters. The strength considering the equivalent age is gradually increased, and the deviation of the strength according to W/C is increased with decrease of W/C in accordance with the replacement of the fine particle cement. For estimating the apparent activation energy (Ea) considering setting time and blame fineness of cement, Ea of the FC based on setting time is calculated with $27.6{\sim}28.9$ KJ/mol, which is somewhat similar to that of OPC, while by applying Ea based on blame fineness, Ea is increased with increase of FC contents, and is calculated with $40{\sim}56$ KJ/mol. Good agreement is obtained by applying Ea based on setting time, while there was remarkable variation between calculated value and measured value when Ea based on blame fineness. Therefore, it is necessary to add influencing factors in existing Ea to enhance the accuracy of the estimation.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.1
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• pp.92-99
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• 2021

CaO-based by-products composed of CaO, SO3, Al2O3, etc. are generally used as raw materials for CaO compounds. When applied to the recovered water of ready-mixed concrete, the hydration reaction of the powder material is accelerated and concrete performance can be improved. In this study, activated sludge was prepared to apply to the recovered water of ready-mixed concrete by mixing CaO-based hot-rolled slag(C12A7) in the recycling water of ready-m ixed concrete. Cem ent paste setting time and mortar compressive strength performance tests confirmed the effect on the hydration reaction. Therefore, the possibility of concrete application using activated sludge was confirmed.