• Journal of the Korea Institute of Building Construction
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• v.18 no.6
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• pp.551-558
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• 2018

This study evaluate the fluidity and hardening properties of mortar by replacement ratio of ferronickel slag powder to estimate the applicability of ferronickel slag powder for cement replacement materials. Ferronickel slag powder was replaced by 0, 5, 10, 15 and 20% of the cement weight. In addition, blast furnace slag powder and fly ash were also used for comparing with the mixtures using ferronickel slag powder. As the test results, the micro-hydration heat of the mixture containing the ferronickel slag powder was lower than that of the mixtures containing the same amount of blast furnace slag powder and fly ash. The flow of the sample with ferronickel slag powder was relatively higher than the other mixtures. In all ages, the compressive strength of the mixture with ferronickel slag powder and fly ash was similar to that of the mix containing only fly ash. In case of drying shrinkage, the mixture containing ferronickel slag powder exhibited lower drying shrinkage than the mixture using blast furnace slag powder, and similar to the mixture containing fly ash.

• Resources Recycling
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• v.28 no.1
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• pp.32-39
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• 2019

The present study investigated hydration of alkali activated slag incorporating sulfate as a form of anhydrite by employing thermodynamic modeling using the Gibbs free energy minimization approach. Various parameters were evaluated in the thermodynamic calculations, such as presence of sulfide, precipitation/dissolution of AFt/AFm phase, and the effect of oxic condition on the predicted reaction. The calculations suggested no significant difference in the void volume and chemical shrinkage, which might influence the performance of the mixtures, in spite of various changes of the parameters. Although the types of hydration products and their amount varied according to the input conditions, their variations were smaller range than that induced by water-to-binder ratio. Moreover, it did not affect the amount of C-(N-)A-S-H which was the most important hydration product.

• Journal of the Korea Concrete Institute
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• v.16 no.3 s.81
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• pp.369-374
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• 2004

Calcium sulfoalumiante(CSA) was prepared for using natural calcite($CaCO_3$) and industrial by-products and wastes, such as $Al(OH)_3,\;CaSO_4{\cdot}2H_2O$. The mixture of raw materials was fired at 20, 400, 600, $1200^{\circ}C$ for 1h and cooled rapidly in air. The cement replaced by 10 wt% $C_4A_3S$ expansive additives was investigated by the measurement of the hydration products and compressive strength, setting time, expansion at wet curing condition. $C_4A_3S$ was found in x-ray diffraction pattern over the temperature $1200^{\circ}C$. The setting time or the cement pastes added clinkers fired at different temperature was shorter than ordinary portland cement. The compressive strength was higher than the ordinary portland cement about 20~30%. The mainly hydration products were ettringite, and $Ca(OH)_2$. The expansion due to the formation of ettringite during hydration decreased the drying shrinkage of hardened cement rather than the ordinary portland cement.

• Journal of the Korean Society of Marine Environment & Safety
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• v.15 no.2
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• pp.135-142
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• 2009

This study investigates the characteristic properties of strength, flowability, durability and drying shrinkage to control strength and to reduce heat of hydration of high performance concrete using crushed stone fines. According to the experimental results, when crushed stone fines are increased every 10%, $10{\sim}15%$ of compressive strength is decreased and flowability of high performance concrete is effectively improved due to the decrease of modulus of deformation and confined water ratio. When crushed stone fines are replaced every 10%, $4^{\circ}C$ of the highest adiabatic temperature rise is decreased by reducing the unit cement. However, 5% of drying shrinkage is increased in the same condition In the meantime, durability of high performance concrete is excellent, having over 100% of good relative dynamic modulus of elasticity due to fineness of formation mused by the increase of the unit powder content and the improvement of flowability, without regard to the replacement of crushed stone fines. Therefore, It can be said that the usage of crushed stone fines can control the strength of high performance concrete by replacement and reduce heat of hydration.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.413-418
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• 2021

In this study, as a basic study to use recycled limestone powder as a secondary product mixture for concrete, it was found that the compressive and flexural strengths were equal to or slightly improved compared to Plain up to 10% and 20% of the RLP mixing ratio, but the strength was rather decreased at 30% mixing. As a result of the heat of hydration experiment, as the RLP mixing rate increased, the heat of hydration decreased, and the elapsed time of the maximum heat was also delayed. As a result of the drying shrinkage test, as the fine powder RLP filled the internal pores of the cement mortar, the drying shrinkage decreased as the mixing rate increased. The compressive strength, water absorption rate, and compressive strength after freezing and thawing of the concrete block mixed with RLP 20% all satisfied the group standard criteria of the Korea Concrete Industry Cooperative Federation, confirming the possibility of use as a mixed material.

• International Journal of Highway Engineering
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• v.11 no.2
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• pp.185-194
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• 2009

The autogenous shrinkage of high-performance concrete, including very-early strength latex-modified concrete(VES-LMC), is generally bigger than that of normal strength concrete because of the low water/cement ratio, high binder contents, and usage of superplasticizer. Mix. proportion of VES-LMC has low water/cement ratio(0.38), high cement content(390kg/m$^3$), and aid of latex(15% of cement weight). Thus, these factors of VES-LMC, rapid water self-dissipation and evaporation within 3 hours of concrete placement would increase the autogenous shrinkage. The purpose of this study was to evaluate the early-age shrinkage, thermal deformation and autogenous shrinkages of VES-LMC with retarder contents(retarder solids-cement ratio, by weight) using to secure working time in field. The experimental results showed that retarder contents do not affect of the maximum hydration temperature. Early-age expansion of VES-LMC was mostly caused by thermal expansion and partly by autogenous expansion. The autogenous shrinkage is decreased by increasing the retarder contents within this study. On the other hand, the usage of retarder should be decided carefully considering the field conditions because an excessive usage of retarder can cause handful early-age expansion.

• Journal of the Korean Society of Hazard Mitigation
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• v.7 no.3
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• pp.19-31
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• 2007

Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.741-744
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• 2008

Quality control of early age concrete significantly influences the long term performance. Primary factors for early age concrete quality control should include the relative humidity and temperature variation, and these are more important as structures become massive and huge. Temperature raise due to cement hydration causes stress, which can develop to cracking with internal and/or external restraints. Exposure conditions including ambient temperature, humidity and wind also significantly affect the cracking behavior of early age concrete. Among many of studies on the early age concrete behavior, investigation on the variation of temperature and relative humidity internal of concrete is not common. That is in part because the difficulties in measuring the relative humidity and temperature inside the concrete. This study used a digital sensor with an appropriate logger to measure internal temperature and relative humidity. This direct measuring method is expected to provide more reliable and comprehensive data acquisition on the early age behavior of concrete.

• Journal of the Korean Ceramic Society
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• v.40 no.9
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• pp.859-866
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• 2003

When calcium sulfoaluminate-based expansive cement was hydrated, ettringite and monosulfate were mainly formed. The crack of hardened cement was prevented by compensating drying shrinkage due to formation of the above hydrates. In order to study the hydration properties of calcium sulfoaluminate-based expanding cement, 3CaOㆍ3Al$_2$O$_3$ㆍCaSO$_4$(C$_4$A$_3$S) was prepared by chemical synthesis, and then the hydration of $C_4$A$_3$S-Ca(OH)$_2$-CaSO$_4$.$2H_2O$-C$_3$A system_was characterized. Good $C_4$A$_3$S phase was prepared at $1300^{\circ}C$ by chemical synthesis, and the main hydration product of $C_4$A$_3$S-Ca(OH)$_2$-CaSO$_4$.2$H_2O$ system was ettringite. In the case of hydration $C_4$A$_3$S-Ca(OH)$_2$-CaSO$_4$ㆍ 2$H_2O$-C$_3$A system, ettringite was formed in the early period and it was transformed into monosulfate while consumed gypsum.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.3
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• pp.39-47
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• 2015

In this study, the properties of strength and drying shrinkage of alkali-activated slag cement (AASC) with magnesium oxide (MgO) contents between 0 and 16 wt% were investigated. The ground granulated furnace blast slag (GGBFS) was activated by potassium hydroxide (KOH) and dosage of activator was 2M and 4M. The MgO was replaced with 2% to 16% of GGBFS by weight. The water-binder ratio (w/b) was 0.5. In the result, the higher MgO content leads to a slightly higher degree of reaction and thus to a higher compressive strength at all ages. The compressive strength and ultra sonic velocity (UPV) increased with increases MgO contents. The drying shrinkage of AASC was decreased as the contents of MgO increases. The results from SEM confirmed that there were densified reaction product of higher MgO content specimens.