• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.769-774
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• 2005

Fluosilicic acid(H2SiF6) is recovered as an aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded H3PO4 or HF. Generally, fluosilicates are the salts produced by the reaction of H2SiF6 and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. This study was performed to know mechanical properties and watertightness using fluosilicates based composite made from fluosilicates and other compounds. Mix proportions for experiments were modulated at 0.45 of water to cement ratio and $0.0-2.0\%$ of adding ratio of fluosilicates based composite. Evaluation for mechanical properties of concrete was conducted to know fresh state of concrete, hardening state of concrete, and watertightness. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. In addition. Scanning Electron Microscopy(SEM) and Energy Dispersive X-Ray(EDX) used for investigating micro-structure and atomic component distributed in hardened concrete. It is ascertained that characteristics of mechanical properties and watertightness was more improved than non-added because of packing role of fluosilicates based composite and pozzolanic reaction of soluble $SiO_2$. Also, concrete added fluosilicates based composite had a tendency to delay setting time and only $0.5\%$ addition of fluosilicates based composite delayed 150 minutes compared with non-added.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.6
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• pp.83-90
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• 2017

Concrete structure for nuclear power plant is mass concrete structure with large wall depth and easily permits cracking in early age due to hydration heat and drying shrinkage. It always needs cooling water so that usually located near to sea shore. The crack on concrete surface permits rapid chloride intrusion and also causes more rapid corrosion in the steel. In the study, the effect of age and crack width on chloride diffusion is evaluated for the concrete for nuclear power plant with 6000 psi strength. For the work, various crack widths with 0.0~1.4 mm are induced and accelerated diffusion test is performed for concrete with 56 days, 180days, and 365 days. With increasing crack width over 1.0mm, diffusion coefficient is enlarged to 2.7~3.1 times and significant reduction of diffusion is evaluated due to age effect. Furthermore, apparent diffusion coefficient and surface chloride content are evaluated for the concrete with various crack width exposed to atmospheric zone with salt spraying at the age of 180 days. The results are also analyzed with those from accelerated diffusion test.

• Korean Journal of Agricultural Science
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• v.2 no.2
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• pp.381-398
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• 1975

Present work was executed to evaluate effects of adjuvants. stabilizers. moisture. pH and heavy metals on the stability of Fenitrothion in the emulsifiable concentrate. In addition, susceptibility ' of Fenitrothion in various formulations, to UV-irradiation has been also examined. The results are summarized as follows; 1. Xylene and benzene were found to be satisfactory solvents for Fenitrothion emulsifiable concentrate. As expected, polar sol vents such as aliphatic alcohols considerably reduced stability of the pesticides. 2. Of the two non-ionic emulsifiers, an alkyl aryl type Sorpol-1200, in contrast to sorbitan type Tweens, substantially reduced decomposition of Fenitrothion in the emulsifiable concentrates. Moisture and pH of emulsifiers. in the ranges studied. affected little if any. on the stabi ity of the Fenitrothion during the experiment periods. 3. Maleic anhydride, p-toluene sulfonic acid, sulfosalicylic acid, maleic anhydride-sulfosalicylic acid reduced decomposition of Fenitrothion in the emulsifiable concentrate. Addition of organic acids, however, increased liability of Fenitrothion in the emulsifiable concentrate. 4. Presence of either zinc or copper metals in the emulsifiable concentrate containing Tween-80 as a emulsifier, reduced stability of the Fenitrothion. 5. UV-irradiation, as expected, brought decomposition of Fenitrothion. The liability of Fenitrothion formulations decreased in the order, wettable powder ${\gg}$ dust > emulsifiable concentrate.

• International Journal of Highway Engineering
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• v.11 no.2
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• pp.185-194
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• 2009

The autogenous shrinkage of high-performance concrete, including very-early strength latex-modified concrete(VES-LMC), is generally bigger than that of normal strength concrete because of the low water/cement ratio, high binder contents, and usage of superplasticizer. Mix. proportion of VES-LMC has low water/cement ratio(0.38), high cement content(390kg/m$^3$), and aid of latex(15% of cement weight). Thus, these factors of VES-LMC, rapid water self-dissipation and evaporation within 3 hours of concrete placement would increase the autogenous shrinkage. The purpose of this study was to evaluate the early-age shrinkage, thermal deformation and autogenous shrinkages of VES-LMC with retarder contents(retarder solids-cement ratio, by weight) using to secure working time in field. The experimental results showed that retarder contents do not affect of the maximum hydration temperature. Early-age expansion of VES-LMC was mostly caused by thermal expansion and partly by autogenous expansion. The autogenous shrinkage is decreased by increasing the retarder contents within this study. On the other hand, the usage of retarder should be decided carefully considering the field conditions because an excessive usage of retarder can cause handful early-age expansion.

• Journal of the Korean Ceramic Society
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• v.40 no.7
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• pp.683-689
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• 2003

The cylindrical ${\gamma}$-alumina pellets were prepared using amorphous alumina and pore generating agent. Its were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH, Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and HNO$_3$, and Fe(NO$_3$)$_3$.9$H_2O$ and HNO$_3$. The pellets thus were hydrothermally treated at 20$0^{\circ}C$ for 3 h in autoclave, and were investigated morphologies and changes of crystal pore characteristics, $N_2$ adsorption and desorption isotherms, active sites and mechanical strength etc. According to the preparation method, acicular platelet pseudo-boehmite crystals of 0.1~0.3 ${\mu}{\textrm}{m}$ size were transformed into acicular pseudo-boehmite cristals of 0.5~2 ${\mu}{\textrm}{m}$ size having the same crystal structure. When ${\gamma}$-alumina pellets were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and then were hydrothermally treated, pore volume between 100 $\AA$ and 1000 $\AA$ was increased from 0.34 ㏄/g to 0.86 ㏄/g, and the gap of $N_2$ adsorption and desorption hysteresis loop was decreased due to increasement of pore size. New active site that could adsorb the C-H functional group was created on the catalist. Also, mechanical strength of catalyst was increased from 1.06 ㎫ to 1.36 ㎫.

• Journal of the Korean Society of Hazard Mitigation
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• v.7 no.3
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• pp.19-31
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• 2007

Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

• Economic and Environmental Geology
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• v.42 no.5
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• pp.509-512
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• 2009

Powder diffraction patterns of the zeolite mesolite ($Na_{5.33}Ca_{5.33}Al_{16}Si_{24}O_{80}{\cdot}21.33H_2O$), with a natrolite framework topology were measured as a function of pressure up to 5.0 GPa using a diamond-anvil cell and a $200{\mu}m$-focused monochromatic synchrotron X-ray. Under the hydrostatic conditions mediated by pore-penetrating alcohol and water mixture, the elastic behavior of mesolite is characterized by continuous volume expansion between ca. 0.5 and 1.5 GPa, which results from expansion in the ab-plane and contraction along the c-axis. Subsequent to this anomalous behavior, changes in the powder diffraction patterns suggest possible reentrant order-disorder transition. The ordered layers of sodium- and calcium-containing channels in a 1:2 ratio along the b-axis attribute to the $3b_{natrolite}$ cell below 1.5 GPa. When the volume expansion is completed above 1.5 GPa, such characteristic ordering reflections disappear and the $b_{natrolite}$ cell persists with marginal volume contraction up to ca. 2.5 GPa. Further increase in pressure leads to progressive volume contraction and appears to generate another set of superlattice reflections in the $3c_{natrolite}$ cell. This suggests that mesolite in the pressure-induced hydration state experiences order-disorder-order transition involving the motions of sodium and calcium cations either through cross-channel diffusion or within the respective channels.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.677-680
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• 2008

The autogenous shrinkage of HPC is important in that it can lead the early cracks in concrete structures. The purpose of the present study is to explore the autogenous shrinkage of HPC with cellulose fiber and expansive additive and to derive a realistic equation to estimate the autogenous shrinkage model of that. For this purpose, comprehensive experimental program has been set up to observe the autogenous shrinkage for various test series. Major test variables were the quantity of expansive additive and cellulose fiber. Water-cement ratio is fixed with 13%. The autogenous shrinkage of HPC is found to decrease with increasing expansive additive and cellulose fiber. A prediction equation to estimate the autogenous shrinkage of HPC was derived and proposed in this study. The proposed equation shows reasonably good correlation with test data on autogenous shrinkage of HPC.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.499-506
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• 2005

지반오염조사에 대한 유전상수 측정기법의 적용성을 평가하기 위하여 중금속 오염도에 따른 흙의 유전특성 변화를 분석하였다. 유전상수의 실수부와 허수부 모두 체적함수비에 따른 증가경향을 나타내었으며, 특히 MHz 범위에서 유전상수 실수부는 쌍극자모멘트에 비례하기 때문에 흙의 유전상수는 체적함수비에 따른 선형적인 증가경향을 나타내었다. 중금속 용액은 50kHz 이하의 저주파영역에서 전극 분극효과에 의해 농도 증가에 따라 유전상수 실수부가 증가하는 경향을 나타내었으나, 고주파 영역에서는 이온의 수화작용에 의한 물분자의 배향분극 발현 감소로 인하여 유전상수 실수부가 감소하였다. 유전상수 허수부의 경우에는 모든 주파수 영역에서 중금속 농도 증가에 따른 전도손실에 의하여 증가하는 경향을 나타내었다. 흙과 중금속 혼합시료의 경우 함수비가 큰 시료에서는 중금속 용액 자체의 유전특성이 그대로 발현되었으나, 함수비가 작은 시료에서는 공간전하분극의 영향이 우세하여 유전상수 실수부가 10-20%정도 증가하는 경향을 나타내었다. 유전상수 허수부의 경우에는 중금속 농도 증가에 따른 뚜렷한 증가경향을 확인할 수 있었다. 본 연구의 결과에 의하면 중금속의 오염감지에 대해서는 유전상수 실수부보다는 허수부의 적용성이 높은 것으로 나타났으며, 현장에서의 정확한 오염도 평가를 위해서는 함수비에 대한 평가가 선행되어야 할 것으로 판단된다.

• Applied Biological Chemistry
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• v.35 no.4
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• pp.219-226
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• 1992

The effect of freezing on cooking times, tastes and microstructures of beans were examined. Freezing was effective in shortening of cooking time and improving of the taste: while the cooking time was reduced to one-half by freezing, textures, flavors and overall acceptabilities of black bean and soybean were improved by freezing. A high correlation was found between sensory texture and Instron puncture force, and sensory texture was predictable from puncture force using equation. The microstructure of cotyledonary cells of soybean was characterized with thick cell wall and no difference was observed between frozen and non-frozen soybean. But the spherosome enclosing the protein body was destructed by freezing.