• Journal of the Korea Concrete Institute
• /
• v.27 no.3
• /
• pp.237-244
• /
• 2015

Entering the 20th century since the industrial revolution, the cement has been widely used in the field of construction and civil engineering due to the remarkable development of construction industry. However, result from that development, each kind of industrial by-products and waste and the carbon dioxide generated in the process of cement production cause air pollution and environmental damage so earth is getting sick now slowly. Therefore, we have to recognize importance about this. It means that the time taking specific and long-term measures have come. In this research paper, as substitution of the cement generating environmental pollution, we investigate the hydration reaction of non-Sintered Cement mortar mixed with GBFS, active stimulant of alkaline and sulphate series by using SEM and XRD, mechanical and chemical properties according to the curing method. As a result of this experiment, NSC realized outstanding strength for water curing and steam curing. It means that it has a good possibility as substitution of cement. From now on, it can be used for structure satisfying specific standard. We expect to find a substitution of outstanding cement by progressing continuous research making the best use of pros and cons according to the curing method.

• Journal of the Korean Ceramic Society
• /
• v.40 no.7
• /
• pp.683-689
• /
• 2003

The cylindrical ${\gamma}$-alumina pellets were prepared using amorphous alumina and pore generating agent. Its were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH, Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and HNO$_3$, and Fe(NO$_3$)$_3$.9$H_2O$ and HNO$_3$. The pellets thus were hydrothermally treated at 20$0^{\circ}C$ for 3 h in autoclave, and were investigated morphologies and changes of crystal pore characteristics, $N_2$ adsorption and desorption isotherms, active sites and mechanical strength etc. According to the preparation method, acicular platelet pseudo-boehmite crystals of 0.1~0.3 ${\mu}{\textrm}{m}$ size were transformed into acicular pseudo-boehmite cristals of 0.5~2 ${\mu}{\textrm}{m}$ size having the same crystal structure. When ${\gamma}$-alumina pellets were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and then were hydrothermally treated, pore volume between 100 $\AA$ and 1000 $\AA$ was increased from 0.34 ㏄/g to 0.86 ㏄/g, and the gap of $N_2$ adsorption and desorption hysteresis loop was decreased due to increasement of pore size. New active site that could adsorb the C-H functional group was created on the catalist. Also, mechanical strength of catalyst was increased from 1.06 ㎫ to 1.36 ㎫.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.21 no.4
• /
• pp.132-139
• /
• 2017

In this study, in order to prevent the frost damage of the concrete, the characteristics of the form using heating sheet utilizing the chemical reaction of quicklime and the insulation were evaluated through experiments at low temperature. In the case of form at $-10^{\circ}C$, the form with attached heating sheet showed a temperature history of more than $10^{\circ}C$ higher than that of wood form at the early of concreting due to heat of the quicklime in the heating sheet. In the case of the insulated form, the concrete was kept at a high temperature by preserving the hydration heat. When the heating sheet and the isopink(extruded polystyrene) were attached together on the form, the effect was the same as that of the vacuum insulation. The compressive strength of the form with vacuum insulation and form with isopink, heating sheet as measured about 5 MPa at age 3. The experimental in Mongolia, as with the pervious results, the form with the heating sheet and the insulation showed the highest temperature history over $25^{\circ}C$ for 48 hours. Therefore, it was confirmed that the heating sheet and insulation are attached to the form, which helps the concrete strength development at low temperature by heat generation and the insulation effect.

• The Korean Journal of Pesticide Science
• /
• v.11 no.1
• /
• pp.32-37
• /
• 2007

The study was carried out to establish buffer zone for the protection of the non-target organisms by aerial pesticide application. The two pesticide combination of 3-way tank-mixing of three pesticides for aerial application, ferimzone tricyclazole SC + BPMC EC + validamycin-A SL and hexaconzole EC + isoprothiolane EC+phenthoate EC were selected for the simultaneous control of key pests on paddy rice as blast, sheath blight, brown planthopper and moth. Aquatic organisms including killifish and loach in the paddy field and nearby water reservoirs were not affected by aerial application of the pesticides. However, all the water flea were killed, when they were exposed 10 m from the aerially sprayed site, while the water flea exposed in 30 m away from the site were not affected. Honeybees within 50 m in the wind direction and 20 m in the opposite wind direction showed a mortality of $7{\sim}100%$. Residues concentration of the pesticides in paddy water were not detectable level after six days from aerial application. Drifting distance of aerially sprayed droplet from the target area was within 30 m in the wind direction and 20 m in the opposite direction. Consequently, it was the buffer zones in the aerial pesticides application for the protection of the non-target organisms should be at least 50 m for aquatic organisms and 100 m for honeybees.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.18 no.5
• /
• pp.116-127
• /
• 2014

The studies were carried out to process one cycle for a day to the large section tunnel lining concrete. Climatic characteristics of the tunnel inside are changed, when the temperature of the concrete placement is low, the mold remove time is increased that the heat of hydration speed be delayed because affects the strength development, to compensate for this, after installing the curing sheet on both sides of the steel form and installation of tunnel entrance, when it comes to providing the additional heat source of $28{\pm}2^{\circ}C$ therein, it was to be achieved early strength development control standards (4.5MPa) presented as a crack control scheme or more, thus, It was able to remove after age of 14hr from mold. On the other hand, under the conditions of $10{\pm}1^{\circ}C$ that a natural curing temperature in the tunnel, it was analyzed must ensure the curing time of 36hr or more after concrete placement. Throughout this study, the concrete strength development and the temperature in the early-age concrete, it can find that reverify the curing temperature is greatly affected, even concrete fly ash is mixed 10%, if it is possible to raise the surface temperature for a predetermined time, is not a problem in the early strength development.

• Korean Journal of Agricultural and Forest Meteorology
• /
• v.9 no.4
• /
• pp.247-259
• /
• 2007

In this study, we examined the flux of carbon and water using an eco-hydrological model, Regional Hydro-Ecologic Simulation System (RHESSys). Our purposes were to develop a set of parameters optimized for a well-designed experimental watershed (Gwangneung Research Watershed, GN) and then, to test suitability of the parameters for predicting carbon and water fluxes of other watershed with different regimes of climate, topography, and vegetation structure (i.e Gangseonry Watershed in Mt. Jumbong, GS). Field datasets of stream flow, soil water content (SWC), and wood biomass product (WBP) were utilized for model parameterization and validation. After laborious parameterization processes, RHESSys was validated with the field observations from the GN watershed. The parameter set identified at the GN watershed was then applied to the GS watershed in Mt. Jumbong, which resulted in good agreement for SWC but poor predictability for WBP. Our study showed that RHESSys simulated reliable SWC at the GS by adjusting site-specific porosity only. In contrast, vegetation productivity would require more rigorous site-specific parameterization and hence, further study is necessary to identify primary field ecophysiological variables for enhancing model parameterization and application to multiple watersheds.

• Journal of the Korean Society of Hazard Mitigation
• /
• v.7 no.3
• /
• pp.19-31
• /
• 2007

Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.7 no.3
• /
• pp.77-84
• /
• 2012

It is known that some components of wood obstruct the hydration of cement when wood is mixed with cement. In order to examine the effect of pretreatment of wood chips in hot water, this study conducted the experiments for the setting and compressive strength of mortar by sieving pine wood chips with a 2.4mm sieve, dipping them in waters of different temperatures, and then using them as a part of the fine aggregate. For the experiments, water-cement ratio of the mortar was 0.50 and the amount of the fine aggregate substituted by wood chips was set at 0%, 2%, 4%, 6%, 8%, and 10% of the mass of the fine aggregate. As a result of the test, it was found out that when wood chips were used to substitute fine aggregate for the production of mortar, more usage of wood chips postponed setting more, and the treatment of wood chips with water improved the problem of the delay in setting time. Especially, the final setting time of the mortar which used 2~6% of wood chips treated in $100^{\circ}C$ water for 30 minutes was almost the same as the final setting time of the mortar which used no wood chips. Also, the compressive strength of the mortar which used the wood chips treated with water was compared to that of the mortar which used the wood chips not treated with water. The result showed that the strength improved for age of 7 days and 28 days, while there was little change in strength for age of 3 days.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.31 no.5
• /
• pp.251-258
• /
• 2018

In construction site, conventional methods such as jackhammer or explosive methods(dynamite) have been often used for the demolition of structures. Use of those methods are more carefully treated in environmentally and historically sensitive area. For those reasons, use of Soundless Chemical Demolition Agent(SCDA) is getting the spotlight. The SCDA is a powder which has expansive strength when it is mixed with water. In these Characteristics, SCDA can destroy the concrete or rock as it is poured into boreholes of the concrete or rock structures. However, there is no industrial standard for the use of SCDA effectively yet. In this study, experimental study to measure the expansive pressure was conducted depending on various boundary conditions such as waterproof, length of the steel pipe, submerged of steel pipe. Furthermore, computational analysis using damage plasticity model to predict the minimum required pressure of the SCDA for the concrete demolition depending on spacing between holes(k-factor) and compressive strength of the concrete was conducted. Obtained results indicates that water heat dissipation with submerged steel pipe shows the stable pressure for measuring the SCDA and hole distance(k-factor) is the most important factor for crack initiation of concrete.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.20 no.2
• /
• pp.94-101
• /
• 2016

This paper presents an investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(0, 30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0) and initial curing temperatures($23^{\circ}C$ and $70^{\circ}C$). The tests involved immersions for a period of 6 months into 10% solutions of sodium sulfate and magnesium sulfate. The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, as higher GGBFS replace ratio or Ms shown higher compressive strengths on 28 days. In case of immersed in 10% sodium sulfate solution, the samples shows increase in long-term strength. However, for samples immersed in magnesium sulfate solutions, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$); the gypsum increased up to 6 months continuously.