• Title/Summary/Keyword: 수착 성질

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A Study on the Sorption and Physical Properties of the BTCA Finished Cotton Fabrics (BTCA로 방추가공한 면직물의 수착 성질 및 물리적 성질의 연구)

  • 최연주;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.4
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    • pp.535-542
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    • 1998
  • Cotton fabrics were treated with BTCA, which is used to improve the wrinkle recovery property of cotton fabrics. BTCA, with varying its concentrations, was treated on cotton fabrics by pad dry-cure technique. BTCA contents in treated cotton fabrics were determined by the weight gain and the FT-lR spectrometer. The effects on the sorption and physical properties of BTCA treated fabrics were investigated. IR spectra showed that ester-crosslinks were produced in BTCA treated cotton fabrics. And as increasing the concentration of BTCA, ester-crosslinks are increased in amorphous regions of fabrics. Moisture regain and water imbibition of treated fabrics were reduced. But, they were increased over a certain concentration. Dye sorptions also were reduced, but they were similar over 6% BTCA. When BTCA was treated on cotton fabrics, DP rating and wrinkle recovery angle were improved. On the other hand, strength retentions of treated fabrics were lower than untreated fabrics. Stiffness was increased.

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Phosphate Sorption on Boehmite with Eu(III): P K-edge EXAFS Fingerprinting (뵈마이트 표면의 인산염 및 Eu(III) 수착: 인(P) X-선 흡수분석(EXAFS)에 의한 연구)

  • Yoon, Soh-Joung;Bleam, William F.
    • Economic and Environmental Geology
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    • v.42 no.5
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    • pp.495-500
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    • 2009
  • Actinide sorption to the geological materials can reduce the mobility and bioavailability of radionuclides released to the environment through the development of nuclear weapons and nuclear energy. Under circumneutral pH conditions, actinide sorption can be enhanced by phosphate anions sorbed on oxide mineral surfaces as indicated by the sorption of trivalent lanthanide ions ($Ln^{3+}$), the chemical analog for trivalent actinide ions ($Ac^{3+}$). In this paper, we examined a ternary sorption system of trivalent europium ions ($Eu^{3+}$) sorbed onto boehmite (${\gamma}$-AlOOH) surfaces pre-sorbed with phosphate anions (${PO_4}^{3-}$), using extended X-ray absorption fine structure (EXAFS) spectroscopy. In the Eu-$PO_4$-boehmite ternary sorption system, $EuPO_4$ surface precipitates were formed as implicated by Eu $L_{III}$-edge EXAFS spectroscopy. Phosphorus K-edge EXAFS fingerprinting indicated a bidentate mononuclear surface complex formation of phosphate sorbed on boehmite surfaces as well as $EuPO_4$ surface precipitate formation.

Simultaneous Removal of Nitrate and Trichloroethylene by Zero Valent Iron and Peat (영가철과 피트를 이용한 질산성질소와 트리클로로에틸렌의 제거)

  • Min, Jee-Eun;Kim, Mee-Jeong;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1074-1081
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    • 2006
  • As common pollutants in surface and groundwater, nitrate nitrogen($NO_3-N$) and trichloroethylene(TCE) can be chemically and biologically reduced by zero valent iron(ZVI) and peat soil. In batch microcosm experiments, chemical reduction of TCE and nitrate was supported by hydrogen from ZVI. For biological degradation of TCE and denitrification peat soil was introduced. ZVI reduced TCE, while peat provided TCE sorption site and microbes performing biological degradation. Nitrate reduction was also achieved by hydrogen from ZVI. In addition, indirect evidence of denitrification was observed. More reduction of TCE and nitrate was achieved by ZVI+peat treatment however nitrated reduction was hindered in the presence of TCE in the system due to the competition for hydrogen. TCE reduction mechanism was more dependent on ZVI, while nitrate was peat-dependent. Hydrogen and methane concentration showed that peat had various anaerobic denitryfing and halorespiring bacteria.

Enrichment of Oxygen and process engineering aspects using polysulfone hollowfiber membrane (폴리수폰 중공사막에 의한 산소농축 및 공정변수의 영향)

  • 조정식;김종수;이광래
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.65-66
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    • 1997
  • 1. 서론 : 현재의 막분리 기술로는 단 단계 분리공정(single-stage separation)으로 약 40%의 산소농축공기(oxygen-enriched air)를 얻을 수 밖에 없지만 심냉법(cryogenic techniques)보다는 에너지 소비율이 적으며, 공정이 비교적 간단하기 때문에 용도에 따라 순 산소를 꼭 필요로 하지 않는 제철소, 발전소 등의 연소분야, 호흡기 환자를 위한 의료분야, 생물공학이나 항공기 분야 등에 편리하게 이용될 수 있다. 이와 같이 용도가 다양한 산소를 분리막을 이용하여 보다 편리하고 값싸게 얻기 위해서는 산소와 질소의 막투과에 대한 새로운 지식을 얻고 막투과가 기체의 어떤 성질에 지배되고 있는가를 조사할 필요가 있다. 본 연구에서는 고무상 고분자막(rubbery polymer membrane)에 대한 산소/질소의 수착특성과 순수한 기체의 투과율(permeation rate)을 기초로 하여 혼합기체의 투과율, 분리인자(separation factor), 막분리 공정변수에 의한 중공사 분리막에서의 기체분리특성에 대하여 연구하였다.

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Microstructure and Mechanical Properties of Alumina/Zirconia Layered Composites (알루미나/지르코니아 층상 복합체의 미세구조 및 기계적 성질)

  • Lyu, Seung-Woo;Park, Young-Min;Yang, Tae-Young;Ryu, Su-Chak;Kim, Young-Woo;Yoon, Seog-Young;Park, Hong-Chae
    • Journal of the Korean Ceramic Society
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    • v.43 no.3 s.286
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    • pp.193-197
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    • 2006
  • Symmetric three-layer $Al_2O_3/ZrO_2$ composite has been prepared by freeze casting and pressureless sintering at $1400-1600^{\circ}C$ in air. The layered material sintered at $1600^{\circ}C$ showed the maximum fracture strength (410 MPa), measured by a four-point bending test. Contact damage strength was superior in three-layer composite compared with corresponding mono-layered material, possibly due to the development of relatively large compressive stress. The grain growth of $ZrO_2$ particles was mainly governed by coalescence mechanism.