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Characteristics of Naturally Occurring Radioactive Materials in Groundwater from Aquifers Composed of Different Geological Settings in Ganghwa Island (강화도의 지질별 지하수 중 자연방사성 물질의 특성)

  • Kim, Ikhyun;Kim, MoonSu;Hamm, Se-Yeong;Kim, Hyunkoo;Kim, Dongsoo;Jo, Seongjin;Lee, Heonmin;Hwang, Jongyeon;Jo, Hunje;Park, Sunhwa;Chung, Hyenmi
    • Economic and Environmental Geology
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    • v.51 no.1
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    • pp.27-38
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    • 2018
  • Groundwaters in different rock types (Mesozoic granite, Precambrian gneiss, and schist) of Ganghwa island, Incheon City were characterized by using naturally occurring radioactive materials (NORM) and hydrogeochemical constituents. For the study, groundwater samples from 69 wells had been collected over eight years. Statistical methods were applied to relate hydrogeochemical components and NORM in the groundwater samples. The groundwater samples belonged to $Ca(Na)-HCO_3$ types. The uranium concentrations in three groundwater samples exceeded 30 ug/L of United States Environmental Protection Agency (US EPA) maximum contaminant level (MCL). The radon concentrations in 28 groundwater samples exceeded 4,000 pCi/L (picocuries per Liter) of US EPA alternative maximum contaminant level (AMCL). Gross-alpha in all the groundwater samples did not exceed 15 pCi/L of US EPA MCL. The average concentrations of uranium and radon in groundwater were the highest in granite area, and then gneiss, schist areas in order. In schist area, the correlation coefficient (R) between radon and $HCO_3$ is -0.40 and R between uranium and $SO_4$ is 0.54. In gneiss area, the R between radon and uranium is 0.55 and the R between uranium and $SO_4$ is 0.41. According to factor analysis, each geological area shows different chemical characteristics. The statistical analysis of whole groundwater resulted in nearly no significant relationship among uranium, radon and chemical constituents. Subsequently, more detailed studies on hydrogeological, geochemical, and geological characteristics related to NORM are required to better understand the behavior and fate of NORM.

The Importance of Monitoring Wells Maintenance in Improving Groundwater Quality (지하수 관측정의 시설개선에 따른 수질변화와 유지관리에 대한 연구)

  • Kim, Jeong-Woo;Seo, Yongkyo;Kim, Rak-Hyeon;Cheon, Jeong-Yong
    • The Journal of Engineering Geology
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    • v.24 no.2
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    • pp.283-295
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    • 2014
  • Groundwater monitoring wells are important to maintain their performance for long term monitoring. The monitoring wells with extensive internal incrustation by clay adsorption were selected for this study. The performance of these monitoring wells was improved by pump washing, tube replacements for dedicated samplers, and well surging. After each improvement, the Mg, Mn, and Zn concentrations were increased. The results show that under these conditions, the monitoring wells must be carefully inspected at least once a year. Even in the case of no abnormal phenomenon like as internal incrustation, the monitoring wells need to be serviced at least once every four to five years to guarantee that they are effectively monitoring groundwater quality.

Effect of Ferro-nickel Slag on Contamination of Soil and Water (페로니켈슬래그(FNS)가 토질 및 수질오염에 미치는 영향)

  • Park, Kyungho;Kim, Daehyeon;Kim, Byungho;Go, Youngjin
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.4
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    • pp.21-33
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    • 2013
  • The purpose of the study is to evaluate engineering properties of Ferro Nickel Slag (FNS) and to investigate the effects of FNS on potential contamination of surrounding soil and water through small and large chamber tests. Soil conditions in the chamber tests were made as closely as possibile to the field conditions. In order to simulate different types of water, we used fresh water, acidic water and seawater. Sand soils were made with relative densities of 40% and 60%, and clay with the degree of compaction of 90%. After flushing water through the FNS in the chambers was completed, the PH test was performed for the water flowing out of the chambers and the soil samples were collected for soil pollution analysis. Based on the results of the chamber tests, although the pollution level was slightly higher in the silt than in the sand, the environmental effect that FNS causes the surrounding soil was found to be very minimal. This indicates that FNS can be used as construction material in place of natural aggregates.

Simultaneous Analysis of Triazines and Phenoxyalkanoic Acids by GC/MS (GC/MS를 이용한 트리아진 및 페녹시산류의 동시 분석)

  • Park, Song-Ja;Kim, Yun Je;Pyo, Hee Soo;Park, Kyung Soo;Park, Jongsei
    • Analytical Science and Technology
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    • v.7 no.1
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    • pp.65-78
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    • 1994
  • The herbicide mixture of 7 triazines and 9 phenoxyalkanoic acid esters was simultaneously separated and determinated with the selected ion monitoring by using gas chromatography/mass spectrometry. The extraction recoveries of those herbicides from the reagent water were studied for the organic solvent extraction(LLE) with methylene chloride. The calibration curves of them showed good linearity over the concentration range of 0.2~0.5ng/ml and the detection limits were 0.2~0.5ng/ml for 100ml of water. This analytical method could be applied to the drinking water and biological sample.

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Spacial-Temporal Characteristics of Dinoflagellate Cyst Distribution in Sediments of Busan Harbor (부산항 퇴적물속 와편모조류 시스트의 시공간적 분포 특성)

  • KIM HYUN-JUNG;MOON CHANG-HO;CHO HYUN-JIN
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.10 no.4
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    • pp.196-203
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    • 2005
  • To describe dinoflagellate cyst distribution from Busan Harbor, eleven surface sediment samples and a vertical sediment sample were collected in 2003. Dinoflagellate cysts were identified 12 genera 22 species, and the total cyst concentrations varied from $210\~869\;cysts/g$. The proportion of heterotrophic dinoflagellate cysts was higher in inner parts than in outer parts of the harbor, which reflects that water quality is worse in inner harborthan that in outer harbor. On the basis of the sedimentation rate of 2.0 mm/yr, total depth of the vertical core reflects marine environment far the past 260 years, where dinoflagellate cysts were identified 9 genera 18 species and the total cyst concentrations were $79\~446\;cysts/g$. The cyst concentrations were low and the proportion of heterotrophic dinoflagellate cysts were incerased in the upper part from $14\~15cm$ depth$(1928\~1933)$, which shows industrialization and urbanization in this study area.

Comparison of the analytical methods for Cd in brown rice (현미중(玄米中) 카드뮴의 분석방법(分析方法)에 관(關)한 비교연구(比較硏究))

  • Kim, Bok-Young;Lee, Min-Hyo
    • Korean Journal of Environmental Agriculture
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    • v.14 no.3
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    • pp.338-344
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    • 1995
  • The wet ash method has been used as an official standard procedure for the analysis of Cd in brown rice in Korea, but this method involves several disadvantages. Thus, four analytical methods were compared in this experiment in order to find a more efficient method for the Cd analysis in brown rice. Evaluation was made based on both the Cd recovery percentages from the Cd-spiked samples and the relationships between Cd contents obtained by the official procedure and other methods. Results showed that ashing 50g brown rice at $600^{\circ}C$(dry ash method) recovered nearly 80% of the spiked Cd. This recovery percentage was a little lower than that of the wet ash method(87%) but higher than those of other methods. The dry ash method had the lowest standard deviations and revealed the highest correlation coefficient($r=0.98^{\ast\ast}$) in Cd contents with the standard wet ash method. These results demonstrated that the dry ash method, ashing 50g brown rice at $600^{\circ}C$, would be as efficient as the wet ash method and could be employed as a recommended procedure for the Cd analysis of brown rice.

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Detection of Waterborne Pathogens in Public Bath Houses by PCR-Reverse Blot Hybridization Assay (PCR-REBA) (분자생물학적 방법인 PCR-REBA를 이용한 대중목욕탕 수질 중 수인성병원성미생물 검출)

  • Song, Woon-Heung;Choi, Seung-Gu;Yang, Byoung-Seon;Lee, Jae-Sang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.8
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    • pp.3517-3522
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    • 2011
  • Contamination of public bath water by waterborne pathogens can cause disease outbreaks and contribute to background rates of disease. The aim of this study is to determine the prevalence of waterborne pathogens in public baths. A total of 30 water samples were collected from 30 different public baths in seoul, Korea. Pathogens in water samples were concentrated by 0.45 ${\mu}m$ nitrocellulose membrane filter, analyzed by both cultivation and polymerase chain reaction-reverse blot hybridization (PCR-REBA) of partial 16S rRNA gene. Various microorganisms including Escherichia coli and Shigella spp. were identified by microbiological cultivation. E. coli, Shigella spp., Salmonella spp., Pseudomonas spp. and Mycobacterium spp. were identified by PCR-REBA. Our results suggest that appropriate hygiene practice and continuous monitoring is needed for reducing health risk associated with public bath houses.

Hydrogeology and Water Chemistry of the Friar Tuck Abandoned Coal Mine Site, Indiana, USA (미국 인디아나주 Friar Tuck 폐탄광의 수리지질 및 수질)

  • Park, Jung-Chan
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.2
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    • pp.70-79
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    • 1996
  • The Friar Tuck Abandoned Coal Mine site is one of the most complexly disturbed areas in the midwestern United States. The deposits of gob and tailings contain high concentrations of pyrite, whose oxidation contributes to the acidification of soil and water and prevents the growth of vegetation. In an effort to quantitatively evaluate the effects of reclamation techniques, detailed monitoring program was performed. Water samples were collected from surface water, groundwater, and pore water from the unsaturated zone during a period of five years. According to the results, The spoil deposits are a relatively minor source of contamination and gob piles are the source of severe contamination to surface water and groundwater. But, loess and till beneath the gob piles effectively prevent the contaminated water migration from the source. Surface layers of the gob piles and the tailing deposits are less toxic than the interior of the deposits as a consequence of weathering over several decades. Acid mine drainage is in a post-peak stage and acid formation potential is probably situated in the unsaturated zone of refuse.

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Hydrogeochemical Characterization of Natural Radionuclides Uranium and Radon in Groundwater, Jeonnam Province (전라남도 일대 지하수 중에서 산출하는 자연방사성물질 우라늄과 라돈의 수리지구화학적 거동특징)

  • Cho, Byong Wook;Kim, Moon Su;Kim, Hyun Gu;Hwang, Jae Hong;Cho, Soo Young;Choo, Chang Oh
    • The Journal of Engineering Geology
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    • v.27 no.4
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    • pp.501-511
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    • 2017
  • Natural radionuclides such as uranium and radon from 170 groundwater wells in Jeonnam Province were investigated, together with hydrogeochemical properties, and concentration maps of uranium and radon were also constructed in this study. Characteristics of their concentrations and occurrence were discussed using hydrogeochemical factors and geostatistical methods based on individual geological units. Though uranium and radon in groundwater show a wide range in the concentration, most of which occur as low levels except a few sites. Based on factor analysis, correlation coefficients between uranium and radon are very low. Such results verify that these radionuclides behave independently, well consistent with most previous results investigated nationwide in groundwater. Besides uranium and radon, most hydrochemical components in groundwater show a close relation to indicate the water-rock interaction taken place actively in aquifer.

Disposable Strip-type Sensors for Detection of Free Chlorine (유리염소 측정을 위한 일회용 스트립 센서)

  • Kim, Seung Ki;Kang, Tae Young;Cha, Geun Sig;Nam, Hakhyun;Shin, Jae Ho
    • Journal of the Korean Electrochemical Society
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    • v.15 no.4
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    • pp.242-248
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    • 2012
  • The measurement of residual chlorine as a disinfectant is very important to ensure the safety against the pathogenic microbes and to suppress injection. The portable free chlorine sensor was fabricated with a disposable strip format by a screen printing method. The strip sensors prepared with a carbon-Ag/AgCl(cathode-anode) combination exhibited less interfering responses towards combined chlorine species(especially $NHCl_2$) and oxygen than the sensors prepared with other metals(i.e., gold and platinum). Free chlorine was determined chronoamperometrically with carbon-based electrodes at an applied potential of -0.3 V(vs. Ag/AgCl). A channel was built on the strip-type electrode for easy sampling, and the resulting strip sensors were employed to determine the concentrations of residual free chlorine.